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P3HT:PCBM-based on Polymer Photovoltaic Cells with PEDOT:PSS-pentacene as a Hole Conducting Layer

  • Kim, Hyun-Soo;Hwang, Jong-Won;Park, Su-Jin;Chae, Hyun-Hee;Choe, Young-Son
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.313-313
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    • 2010
  • The performance of polymer photovoltaic cells based on blends of poly(3-hexylyhiophene) (P3HT) and phenyl-C61-butyric acid methyl ester (PCBM) is strongly influenced by blend composition and thickness. Polymer photovoltaic cells based on bulk-heterojunction have been fabricated with a structure of ITO/poly(3, 4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS)-pentacene/poly (3-hexylthiophene) (P3HT):phenyl-C61-butyric acid methyl ester (PCBM)/Al. We have prepared PEDOT:PSS by dissolving pentacene in N-methylpyrrolidine (NMP) and mixing with PEDOT:PSS. Pentacene was added a maximum concentration of approximately 5.5mg to the PEDOT:PSS solution and sonicated for 10 min. Active layer (P3HT:PCBM) (1:1) was strongly influenced by PEDOT:PSS-pentacene. We have investigated the performance of photovoltaic device with different concentration of P3HT:PCBM (1:1) 2.0wt%, 2.2wt%, 2.4wt% and 2.6wt%, respectively. The photocurrent and power conversion efficiency (PCE) showed a maximum between 2.0wt% and 2.2wt% concentration of P3HT:PCBM. This implied that both morphology and electron transport properties of the layer influenced the performance of the present photovoltaic cells. As the concentration of P3HT:PCBM blends as an active layer was increased, the power conversion efficiency was decreased. P3HT:PCBM layer and PEDOT:PSS-pentacene layer were characterized by work function, UV-visible absorption, atomic force microscopy (AFM), X-ray diffraction (XRD) and scanning electron microscope (SEM).

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Thed Optimum Optical Geometry for Recording a Full Color Transmission type Holographic Screen of Larged Size

  • Kim, Jai-Soon;Bobrinev, V.I.;Son, Jung-Young;Choi, Yong-Jin;Shin, Sang-Hun
    • Journal of the Optical Society of Korea
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    • v.4 no.1
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    • pp.66-70
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    • 2000
  • The main problem of image projection on a transmission type holographic screen is color sepa-ration. And it can be overcome by using a long narrow slit type diffuser as a source of the object beam when we record the screen. But that screen is not optimized and so needs changing several conditions. To set up the system many complicate things should be taken into accounted so it is very important to analyze the basic structure by simple concepts and calculations. We designed the system so that recording and projection axis coincide in one line and showed that the analysis of the system is very simple. We did it by a 1st order paraxial approximation calculation and it was good enough to describe the system. The photo-emulsion layer shrinks after processing of the hologram. It induced unsatisfactory color matching at the viewing zone. To overcome this effect, we pre-checked the shrinkage rate of an emulsion layer by experiments and modified the recording set up to compensate for the amount of shrinkage.

A Study on the Back Pressure Characteristics and Engine Performance of Muffler with Exhaust Variable Valve (배기 가변 밸브를 적용한 소음기의 배압특성 및 엔진 성능에 관한 연구)

  • Park Kyoung-Suk;Park Se-Jong;Suh Ho-Chul;Son Sung-Man
    • Journal of the Korean Society for Precision Engineering
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    • v.23 no.7 s.184
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    • pp.108-113
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    • 2006
  • Recently, Automobile manufactures have developing automotive exhaust system under consideration for improvement in engine performance. It thus develop many exhaust components. For example active muffler, semi-active muffler, electronic muffler etc. In this components consider enhanced back pressure and reduction noise. Especially, In recent years it develop the study of semi-active muffler. Semi-active muffler is simple structure and excel performance. Recently many forms semi-active muffler was developed and adopted to the actual use in consideration of cost and technical side for noise and vibration. This study had main objects about the recently developed the semi-active muffler. It was to show its combustion performance as well as its enhanced back pressure characteristics in design. Therefore if the precise analysis of the combustion pressure according to the back pressure transmission was carried out, it was understood that this study would be utilized in the design of the exhaust system such as the semi-active muffler.

GERI-BP001 Compounds, New Inhibitors of Acyl-CoA: Cholesterol Acyltransferase from Aspergillus fumigatus F37

  • Jeong, Tae-Sook;Kim, Sung-Uk;Son, Kwang-Hee;Kwon, Byoung-Mog;Kim, Young-Kook;Bok, Song-Hae
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1995.04a
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    • pp.67-67
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    • 1995
  • Acyl-CoA:cholesterol acyltransferase (ACAT, EC 2.3.1.26) plays an important role in the control of intracellular free cholesterol content via its cholesterol esterifying activity. ACAT inhibitors are expected to be effective for treatment of atherosclerosis and hypercholesterolemia. In the course of a screening program for ACAT inhibitors from microbial sources, GERI-BP001 M, A, and B were isolated from the fermentation broth of a fungal strain. GERI-BP001 compounds were isolated from a culture broth of Aspergillus fumigatus F37 by acetone extraction, EtOAc extraction, SiO$_2$ column chromatography, and reverse phase HPLC. The structure of GERI-BP001 coumpounds were determined by $^1$H-NMR, $\^$l3/C-NMR, 2D-NMR, NOESY, and long range C-H COSY experiments. GERI-BP001 M, A, and B inhibit ACAT activity in an enzyme assay system using rat liver microsomes by 50% at concentrations of 75, 147, and 71 ${\mu}$M, respectively.

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Spatial Distribution of Benthic Macroinvertebrate Community by Altitude in Streams Located in Both Facing Slopes of the Mt. Seorak, Korea (설악산 양사면 하천에서의 고도차에 따른 저서성 대형무척추동물 군집의 공간 분포)

  • Choi, Ah Reum;Kim, Ah Reum;Son, Se-Hwan;Yang, Hee Jung;Kong, Dongsoo
    • Journal of Korean Society on Water Environment
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    • v.30 no.1
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    • pp.68-79
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    • 2014
  • There are marked differences in climate condition between east-facing slopes and west-facing slopes in Mt. Seorak (1,708 m). This study was conducted to find out the differences of benthic macroinvertebrate communities between both slopes of Mt. Seorak. Quantitative (Surber net; $30cm{\times}30cm$, mesh: 1mm) and qualitative (Hand net; mesh: 1mm) samplings ware carried out seasonally in each site which had 100-meter-high difference from November 2010 to November 2011. Most of the survey sites showed sound environmental conditions because they were located in the protection area of the national park. The benthic macroinvertebrates collected from all survey sites were composed of 158 species, 62 families, 17 orders, 7 classes and 5 phyla. DCA (Detrended Correspondence Analysis) ordination based on the abundance of benthic mactoinvertebrates showed that altitude was a major factor governing the structure of benthic macroinvertebrate community. There was no significant difference of the communities between both slopes.

Prediction of Wind Farm Noise with Atmospheric Stability (대기 안정 상태에 따른 풍력 단지 소음 전파 예측)

  • Son, Eunkuk;Lee, Seunghoon;Jeon, Minu;Lee, Soogab
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.42.2-42.2
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    • 2011
  • Noise generated from wind turbines has been predicted by numerical methods. Sound pressure level(SPL) on the turbines is predicted after aerodynamic analysis is carried out by Wind Turbine Flow, Aeroacoustics and Structure analysis (WINFAS) code. The level of each panel of acoustic sphere is determined by the sum of tonal, turbulence ingestion and airfoil self noise. With the noise source database, the acoustic sphere, SPL on the ground is calculated using the model based on acoustic ray theory. The model has been designed to consider the effects on the condition of terrain and atmosphere. The variations of SPL on the ground occur not only because of the different source level but also because of the nonuniform distributions of the sound speed along the height. Hence, the profile of an effective sound speed which is the sum of the contribution of sound speed to a temperature gradient and a wind speed variation is used by the theory based on atmospheric stability. With the integrated numerical method, the prediction of sound propagation on the wind farm is carried out with the states of the atmospheric stability.

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Microwave Syntheses of Subphthalocyanine Derivatives and Their Properties (서브프탈로시아닌 유도체의 마이크로파 합성 및 이의 특성)

  • Kim, Jae Hwan;Heo, Jin;Kang, Boo Min;Son, Dae-Hee;Lee, Geun-Dae;Hong, Seong-Soo;Park, Seong-Soo
    • Applied Chemistry for Engineering
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    • v.20 no.2
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    • pp.154-158
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    • 2009
  • Subphthalocyanine (SubPc) derivatives with different kind of substitute groups were synthesized successfully from various precursors using conventional and microwave heating sources. The chemical structure of precursor and product was determined by $^{1}H-NMR$ and FT-IR spectrometer. Also, spectroscopic property was measured by UV-Vis spectrometer. Compared to the conventional synthesis, it was found that SubPc derivatives were synthesized for a shorter reaction time with a higher synthetic yield in the microwave synthesis.

InP/ZnS Core/shell as Emitting Layer for Quantum Dot LED

  • Kwon, Byoung-Wook;Son, Dong-Ick;Lee, Bum-Hee;Park, Dong-Hee;Lim, Ki-Pil;Woo, Kyoung-Ja;Choi, Heon-Jin;Choi, Won-Kook
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.451-451
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    • 2012
  • Instead of a highly toxic CdSe and ZnScore-shell,InP/ZnSecore-shell quantum dots [1,2] were investigated as an active material for quantum dot light emitting diode (QD-LED). In this paper, aquantum dot light-emitting diode (QDLED), consisting of a InP/ZnS core-shell type materials, with the device structure of glass/indium-tin-oxide (ITO)/PEDOT:PSS/Poly-TPD/InP-ZnS core-shell quantum dot/Cesium carbonate(CsCO3)/Al was fabricated through a simple spin coating technique. The resulting InP/ZnS core-shell QDs, emitting near blue green wavelength, were more efficient than the above CdSe QDs, and their luminescent properties were comparable to those of CdSe QDs.Thebrightness ofInP/ZnS QDLED was maximumof 179cd/m2.

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Annealing Effect on the Structural and Optical Properties of In2S3 Thin Films

  • Hwang, Dong-Hyeon;An, Jeong-Hun;Son, Yeong-Guk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.589-589
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    • 2012
  • Indium sulfide thin films have been grown onto glass substrates using radio frequency magnetron sputtering at room temperature. The as-deposited film were annealed in nitrogen atmosphere at different temperatures of 100, 200, 300, 400 and $500^{\circ}C$ with an 1 h annealing time. The effect of annealing temperature on composition, structure, morphology and optical properties of the as-grown In2S3 films has been studied. The XRD results indicate that the as-deposited films are composed by a mixture of both cubic ${\alpha}$ and ${\beta}$ crystalline phases, with some fraction of tetragonal phase. The thermal annealing on the films produces the conversion of the cubic crystalline phases to the tetragonal ${\beta}$ one and a crystalline reorientation of the latter phase. The surface morphological analysis reveals that the films grown at $300^{\circ}C$ have an average grain size of ~ 58 nm. These films show a S/In ratio of 0.99. The optical band gap is found to be direct and the films grown at $300^{\circ}C$ shows a higher optical transmittance of 80% and an energy band gap of 2.52 eV.

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Structure of Ni and NiO Nanoparticles Observed by X-ray Coherent Diffraction Imaging

  • Kim, Chan;Kim, Yoon-Hee;Hamh, Sun-Young;Son, Jun-Gon;Khakurel, Krishna Prasad;Iqbal, Mazhar;Noh, Do-Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.542-543
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    • 2012
  • Coherent diffraction imaging (CDI) method using hard x-ray at 5.46 keV was applied to study assembly of Ni and Ni oxide nano structures formed on a Si3N4 membrane. Density distribution of Ni nano-particles was obtained quantitatively with about 15 nm lateral resolution by reconstructing images from the speckle diffraction pattern. In addition, reconstructed images of nickel oxide particles indicated that Ni atoms diffuse out during the oxidation process leaving pores inside the nickel oxide crust. Furthermore, we recognize that really weak phase object, less than 5 nm thickness of Ni residues, can be reconstructed due to the reference particles. We achieved quantitative information of nanometer sized materials and demonstrate the effect of reference particles by using hard x-ray coherent diffractive imaging method.

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