Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Microwave Syntheses of Subphthalocyanine Derivatives and Their Properties

서브프탈로시아닌 유도체의 마이크로파 합성 및 이의 특성

  • Kim, Jae Hwan (Division of Applied Chemical Engineering, Pukyong National University) ;
  • Heo, Jin (Division of Applied Chemical Engineering, Pukyong National University) ;
  • Kang, Boo Min (Division of Applied Chemical Engineering, Pukyong National University) ;
  • Son, Dae-Hee (Division of Applied Chemical Engineering, Pukyong National University) ;
  • Lee, Geun-Dae (Division of Applied Chemical Engineering, Pukyong National University) ;
  • Hong, Seong-Soo (Division of Applied Chemical Engineering, Pukyong National University) ;
  • Park, Seong-Soo (Division of Applied Chemical Engineering, Pukyong National University)
  • 김재환 (부경대학교 공과대학 응용화학공학부) ;
  • 허진 (부경대학교 공과대학 응용화학공학부) ;
  • 강부민 (부경대학교 공과대학 응용화학공학부) ;
  • 손대희 (부경대학교 공과대학 응용화학공학부) ;
  • 이근대 (부경대학교 공과대학 응용화학공학부) ;
  • 홍성수 (부경대학교 공과대학 응용화학공학부) ;
  • 박성수 (부경대학교 공과대학 응용화학공학부)
  • Received : 2008.12.08
  • Accepted : 2009.02.02
  • Published : 2009.04.10
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Abstract

Subphthalocyanine (SubPc) derivatives with different kind of substitute groups were synthesized successfully from various precursors using conventional and microwave heating sources. The chemical structure of precursor and product was determined by $^{1}H-NMR$ and FT-IR spectrometer. Also, spectroscopic property was measured by UV-Vis spectrometer. Compared to the conventional synthesis, it was found that SubPc derivatives were synthesized for a shorter reaction time with a higher synthetic yield in the microwave synthesis.

본 연구에서는 마이크로파와 재래식 열원으로부터 여러 종류의 전구체를 사용하여 치환기의 종류가 상이한 subphthalocyanine (SubPc) 유도체들을 성공적으로 합성하였다. 최종 생성물의 화학적 구조는 핵자기 공명 분광기 및 푸레어 변환 적외선 분광기를 이용하여 확인하였다. 또한 분광학적 특성은 자외선-가시광 분광기를 이용하여 측정 분석하였다. 재래식 합성에 비하여 마이크로파 합성에서 SubPc 유도체들이 짧은 반응시간에 높은 합성수율로 합성되는 것을 확인하였다.

Keywords

Acknowledgement

Supported by : 부경대학교

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