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Reaction of lithiated pyridine with $Me_2RSiCl$ and its identification with NMR spectroscopic methods(R=Me, $^tBuCH_2CHSiMe_3$) (리튬화된 Pyridine과 $ME_2RSiCl$의 반응생성물의 NMR 분광학적 연구 (R=Me, $^tBuCH_2CHSiMe_3$))

  • Kim, Duk-Mook;Son, Byung-Yung
    • Analytical Science and Technology
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    • v.7 no.2
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    • pp.187-191
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    • 1994
  • A reactive intermediate 1,2-dihydropyridine derivative 2 has been prepared and isolated from the reaction of pyridine with $^tBuLi$ and trimethylchlorosilane in nonpolar condition at low temperature 2 has characterized by $^1H-NMR$ fine structure analysis with SPINX3. The mechanistic information of formation of 2 was obtained from synthesized 2,5-disubstituted pyridine derivatives 3 and 4.

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An Experimental Study on the Anchorage Capacity by Diameter and Anchor Type of Re-bar (콘크리트 구조체 매입 철근의 직경 및 유형별 앵커력 측정실험 연구)

  • Cho, Seong-Yeol;Son, Ki-Sang
    • Journal of the Korean Society of Safety
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    • v.29 no.5
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    • pp.67-73
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    • 2014
  • Construction equipment such as tower crane should be installed in a field without appropriate anchorage to cause a collapse of crane. The anchorage capacity can be varied with Anchor length, concrete strength, anchor diameter, hooked or non hooked these variables will be made and tested in the study. It is shown what anchorage capacity will be more effective case by case. Hooked and non-hooked rebar anchor concrete weight with dia 22mm rebar are shown with initial displacement at 170~220KN of hooked case and 200~210KN of non-hooked one which are linearly increased, without any ductility behavior with almost brittleness. Three(3) same test pieces are almost similarly behaviored without relation to hooked or non-hooked cases. It is found out that the bigger diameter of rebar becomes, the more resistant capacity could be made, but conversely ductility against sudden collapse similar to brittleness becomes the more insufficient. It is also found out that dia 16mm rebar could be more effectively applied to heavy support weight at construction sites.

Fatigue life prediction of multiple site damage based on probabilistic equivalent initial flaw model

  • Kim, JungHoon;Zi, Goangseup;Van, Son-Nguyen;Jeong, MinChul;Kong, JungSik;Kim, Minsung
    • Structural Engineering and Mechanics
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    • v.38 no.4
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    • pp.443-457
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    • 2011
  • The loss of strength in a structure as a result of cyclic loads over a period of life time is an important phenomenon for the life-cycle analysis. Service loads are accentuated at the areas of stress concentration, mainly at the connection of components. Structural components unavoidably are affected by defects such as surface scratches, surface roughness and weld defects of random sizes, which usually occur during the manufacturing and handling process. These defects are shown to have an important effect on the fatigue life of the structural components by promoting crack initiation sites. The value of equivalent initial flaw size (EIFS) is calculated by using the back extrapolation technique and the Paris law of fatigue crack growth from results of fatigue tests. We try to analyze the effect of EIFS distribution in a multiple site damage (MSD) specimen by using the extended finite element method (XFEM). For the analysis, fatigue tests were conducted on the centrally-cracked specimens and MSD specimens.

Application of tube-type ceramic microfiltration membrane for post-treatment of effluent from biological wastewater treatment process using phase separation

  • Son, Dong-Jin;Kim, Woo-Yeol;Yun, Chan-Young;Kim, Dae-Gun;Chang, Duk;Sunwoo, Young;Hong, Ki-Ho
    • Environmental Engineering Research
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    • v.22 no.4
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    • pp.377-383
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    • 2017
  • A tube-type ceramic membrane for microfiltration was developed, and the membrane module comprised of three membranes was also applied to biological carbon and nitrogen removal processes for post-treatment. Manufacturing the microfiltration membrane was successful with the structure and boundary of the coated and support layers within the membrane module clearly observable. Total kjeldahl nitrogen removal from effluent was additionally achieved through the elimination of solids containing organic nitrogen by use of the ceramic membrane module. Removal of suspended solids and colloidal substances were noticeably improved after membrane filtration, and the filtration function of the ceramic membrane could also easily be recovered by physical cleaning. By using the ceramic membrane module, the system showed average removals of organics, nitrogen, and solids up to 98%, 80% and 99.9%, respectively. Thus, this microfiltration system appears to be an alternative and flexible option for existing biological nutrient removal processes suffering from poor settling performance due to the use of a clarifier.

The Coefficients of Variation Characteristic of Stress Distribution in Silty Sand by Probabilistic Load (확률론적 하중에 따른 실트질 모래지반 내 지중응력의 변동계수 특성)

  • Bong, Tae-Ho;Son, Young-Hwan;Kim, Seong-Pil;Heo, Joon
    • Journal of The Korean Society of Agricultural Engineers
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    • v.54 no.6
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    • pp.77-87
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    • 2012
  • Recently, Load and Resistance Factor Design (LRFD) based on reliability analysis has become a global trend for economical and rational design. In order to implement the LRFD, quantification of uncertainty for load and resistance should be done. The reliability of result relies on input variable, and therefore, it is important to obtain exact uncertainty properties of load and resistance. Since soil stress is the main reason causing the settlement or deformation of ground and load on the underground structure, it is essential to clarify the uncertainty of soil stress distribution for accurately predict the uncertainty of load in LRFD. In this study, laboratory model test on silty sand bed under probabilistic load is performed to observe propagation of upper load uncertainty. The results show that the coefficient of variation (COV) of soil stress are varied depending on location due to non-linear relationship between upper load increment and soil pressure increment. In addition, when the load uncertainty is transmitted through ground, COV is decreased by damping effect.

Development of Thin and Parallel XYθ Alignment Stage (박형 병렬구조 XYθ 정렬 스테이지 개발)

  • Kang, Dong-Bae;Ahn, Jung-Hwan;Son, Seong-Min
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.1
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    • pp.74-79
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    • 2011
  • Alignment systems with multi-axis motions are applied to determine vertical arrangement of multilayer assembly such as LCD, PDP, and MLCC. This study reports the development of XY${\theta}$ alignment stage which is designed as thin-type structure and parallel actuations. The thin-type parallel XY${\theta}$ alignment stage is maintained below $1{\mu}m$ in repeatability error. The squareness and straightness also allow precise motion for the alignment by the developed stage. The measured error is ${\pm}6.25{\mu}m$ in the alignment experiment by the vision system on the parallel XY${\theta}$ alignment stage.

Minimum Expected Cost based Design of Vertical Drain Systems (최소기대비용에 의한 연직배수시설의 설계)

  • Kim, Seong-Pil;Son, Young-Hwan;Chang, Pyung-Wook
    • Journal of The Korean Society of Agricultural Engineers
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    • v.49 no.6
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    • pp.93-101
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    • 2007
  • In general, geotechnical properties have many uncertain aspects, thus probabilistic analysis have been used to consider these aspects. It is, however, quite difficult to select an appropriate target probability for a certain structure or construction process. In this study, minimum expected cost design method based on probabilistic analysis is suggested for design of vertical drains generally used to accelerate consolidation in soft clayey soils. A sensitivity analysis is performed to select the most important uncertain parameters for the design of vertical drains. Monte Carlo simulation is used in sensitivity analysis and probabilistic analysis. Total expected cost, defined as the sum of initial cost and expected additive cost, varies widely with variation of input parameters used in design of vertical drain systems. And probability of failure to get the minimum total expected cost varies under the different design conditions. A minimum value of total expected cost is suggested as a design value in this study. The proposed design concept is applicable to unit construction process because this approach is to consider the uncertainties using probabilistic analysis and uncertainties of geotechnical properties.

Influence of Combustor Pressure on Combustion Characteristics and Local Flame Reaction in the Partially Premixed Flames with $CH_4$, $C_2H_4$ and $C_3H_8$ (부분 예혼합 화염의 연소실 압력이 연료별(메탄, 에틸렌, 프로판) 연소특성과 국소 화염 반응에 미치는 영향)

  • Kim, Jong-Ryul;Son, Je-Ha;Noh, Young-Gu;Kim, Yun-Dong;Choi, Gyung-Min;Kim, Duck-Jool
    • Journal of the Korean Society of Combustion
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    • v.15 no.4
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    • pp.29-36
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    • 2010
  • An experimental study was conducted for three different fuels($CH_4$, $C_2H_4$ and $C_3H_8$) to investigate the combustion characteristics and the local reaction intensity with combustor pressure(-30kpa~30kpa). Regardless of fuel composition, EINOx decreased with reducing pressure decreased. Structure and combustion characteristics were also largely affected by the combustor pressure. In addition, reaction intensity in terms of the changing combustor pressure and equivalence ratio was investigated. Combustion reaction in higher than atmospheric pressure was very active than the lower combustor pressure. When the combustor pressure is lower than the atmospheric pressure, the overall reactivity is noticeably enhanced due to the elevated diffusion process of unburned mixture. It was found that the combustion characteristics of the methane and propane flames are considerably influenced by the pressure while those of ethylene flame are less sensitive to the combustor pressure.

Optimized Synthesis Conditions of Polyethersulfone Support Layer for Enhanced Water Flux for Thin Film Composite Membrane

  • Son, Moon;Choi, Hyeongyu;Liu, Lei;Park, Hosik;Choi, Heechul
    • Environmental Engineering Research
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    • v.19 no.4
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    • pp.339-344
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    • 2014
  • Different types of polyethersulfone (PES) support layer for a thin film composite (TFC) membrane were synthesized under various synthesis conditions using the phase inversion method to study the combined effects of substrate, adhesive, and pore former. The permeability, selectivity, pore structure, and morphology of the prepared membranes were analyzed to evaluate the membrane performance. The combined use of substrate, adhesive, and pore former produced a thinner dense top layer, with more straight finger-like pores. The pure water permeation (PWP) of the optimized PES membrane was $27.42L/m^2hr$ (LMH), whereas that of bare PES membrane was 3.24 LMH. Moreover, membrane selectivity, represented as divalent ion ($CaSO_4$) rejection, was not sacrificed under the synthesis conditions, which produced the dramatically enhanced PWP. The high permeability and selectivity of the PES membrane produced under the optimized synthesis conditions suggest that it can be utilized as a potential support layer for TFC membranes.

Design and Development of a Broadband Ultrasonic Transducer Operating over the Frequency Range of 40 to 75 kHz (40-75 kHz의 주파수 범위에서 동작하는 광대역 초음파 변환기의 설계 및 개발)

  • Lee, Dae-Jae;Kwak, Min Son;Kang, Hee-Young
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.47 no.3
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    • pp.292-301
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    • 2014
  • The objective of this study was to design and develop a broadband ultrasonic transducer that has both wide bandwidth and high sensitivity to measure broadband echoes related to identifying fish species. A broadband ultrasonic transducer providing a nearly flat transmitting response band of 40.2-75.5 kHz with a -12 dB bandwidth of 35.3 kHz was achieved by integrating 12 tonpilz transducer elements operating at different resonance frequencies. The average transmitting voltage response, receiving sensitivity, and figure of merit values in this frequency band were 168.4 dB (re $1{\mu}Pa/V$ at 1 m), -196.8 dB (re $1V/{\mu}Pa$), and -28.4 dB, respectively. The results suggest that bandwidth and sensitivity can be widened and improved by adjusting the array pattern and the structure of tonpilz transducer elements.