• Korean Journal of Soil Science and Fertilizer
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• v.30 no.3
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• pp.234-241
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• 1997

The effects of bulk densities(${\rho}_b$) on saturated hydraulic conductivity (Ksat) and solute elution patterns were investigated from five different bulk densities ranging from $1.1Mg/m^3$ to $1.5Mg/m^3$ with each increment of $0.1Mg/m^3$. The hydraulic conductivities observed were divided into two stages: (1) a linearly decrease with increase in bulk density up to $1.4Mg/m^3$, (2) a steady state where the bulk density is greater than $1.4Mg/m^3$. Using the saturated hydraulic conductivity at the steady state, we figured out the equation describing the correlation between bulk densities(${\rho}_b$) and saturated hydraulic conductivity(Ksat) as follows: $Ksat=-19.2({\rho}_b{^2})+6{\rho}_b+15.5$, (r=0.985). Electrical conductivity(EC) measured from the leachate of the soil column showed that EC at the same pore volume were decreased with an increase in the bulk density from $1.2g/cm^3$, $1.5g/cm^3$, as shown in the time taken to collect the same pore volume at each respective bulk density. The maximum relative concentrations (C/Co=1) from the breakthrough curves for the anions of $Cl^-$, $NO_3{^-}$ and $SO_4{^{2-}}$, which are weakly adsorbed on the soil particles, moved to the right of the graph, while a distinctive retardation occurs at the bulk density between $1.3Mg/m^3$ and $1.4Mg/m^3$. The time taken to recover about 90% of indigenous sulphate was approximately twice as those of chloride and nitrate, resulting in slightly stronger adsorption characteristics for sorption sites on the soil surface. Thus, we can conclude that the salt accumulation in green house soil might be significantly influenced by it's bulk density at the soil depth, as well as the adsorption capacity of ions for the sorption sites in soils.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.1
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• pp.33-42
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• 2000

Adsorption onto the surfaces of solid particles is a well known phenomenon that causes the retardation effect of heavy metals in soils. For adequate remediation of soil and groundwater contamination, it is important to investigate the mobility of heavy metals that largely depends on pH conditions in the soil water since adsorption of heavy metals is pH-dependent. In this study, we investigated the transport of Zn ion under various pH conditions in a sandy soil by conducting batch and column tests. The batch test was performed using the standard procedure of equilibrating fine fractions collected from the soil with eleven different initial $ZnCl_2$ concentrations, and analysis of Zn ion in the equilibrated solutions using ICP-AES. The column test consisted of monitoring the concentrations of soil solutions exiting the soil column with time known as a breakthrough curve (BTC). We injected respectively $ZnCl_2$ and KCl solutions with the concentration of 10 g/L as a tracer in a square pulse type under three different pH conditions (7.7, 5.8, 4.1) and monitored the flux concentration at the exit boundary using an EC meter and ICP-AES. The resident concentration was also monitored at the 10cm-depth by Time Domain Reflectometry (TDR). The results of batch test showed that ion exchange process between Zn and other cations (Ca, Mg) was predominant. The retardation coefficients obtained from adsorption isotherms (Linear, Freundlich, Langmuir) resulted in the various values ranging from 1.2 to 614.1. No retardation effect but ion exchange was found for the BTCs under all pH conditions. This can be explained by the absence of other cations to desorb Zn ion from soil exchange sites under the conditions of ETC experiment imposing blank water as leachate in steady-state flow. As pH decreased, the peak concentration of Zn increased due to the competition of Zn with hydrogen ions ($H^+$) and the concentrations of other cations decreased. The peak concentration of Zn was increased by 12.7 times as pH decreased from 7.7 to 4.1.

• Journal of the Korea Organic Resources Recycling Association
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• v.31 no.3
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• pp.55-64
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• 2023

This batch experiment was conducted to investigate the patterns of major plant nutrients in the leachates from the soil that was incorporated with rice hull biochar adjusted pH with dry fish powder utilizing rice hull biochar for loading the soil microorganisms. The rice hull biochar adjusted pH between 6.0 and 7.0, and the mixture ratio of rice hull biochar and dry fish powder was 4:6. The treatments consisted of three; the soil incorporated with rice hull biochar non-adjusted pH with dry fish powder as control (RB + DF), the soil incorporated with rice hull biochar adjusted pH by pyroligneous acid solution and dry fish powder (RBP+DF), and the soil incorporated with rice hull biochar adjusted pH by citric acid solution and dry fish powder (RBC+DF). NH₄-N, NO₃-N, PO₄-P, and K concentrations in the leachates were analyzed during incubation. The accumulated NH₄-N and PO₄-P concentrations in the leachates from the RBC+DF treatment were the highest during leaching periods. The highest accumulated NO₃-N and K concentrations in the leachates from the RBP+DF treatment were observed. It observed that NH₄-N and PO₄-P were more released in the adjusted citric acid solution, but NO₃-N and K were less released than those in the pyroligneous acid solution due to their low absorption capacity. Furthermore, it is necessary to investigate crop growth responses to the soil incorporated with adjusted pH rice hull biochar and dry fish powder for loading soil microorganisms.

• Applied Biological Chemistry
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• v.44 no.2
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• pp.97-102
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• 2001

Cheju island depends on a hydrogeologically vulnerable aquifer system as its principle source of drinking water. Most of golf courses are located in the area which is important for the ground water recharge, and pesticides are applied to golf courses often at relatively high rates. Therefore, turf pesticides in golf course should be applied without adversely impacting ground water. In this experiment, downward movement of pesticides was monitored in model greens of golf course, where different adsorbents were layered in 3-cm thickness at 35-cm depth, and effect of the adsorption layer on the leaching loss of pesticides was investigated. Major leachings were observed in the periods of heavy rain and very limited leaching was observed under artificial irrigation. Fenitrothion and triadimefon, which have relatively short persistence and high adsorption coefficient, were found in the leachate in low concentrations only at the first rainfall event, around 20 days after the pesticide application. However, diniconazole, which has a relatively long half-life (97 days), was detected in the leachate during the whole period of experiment and concentration was much higher than those of the other pesticides. Maximum leachate concentrations were 1.9, 10.3, and 84.5 ${\mu}l^{-1}$ for fenitrothion, triadimefon, and diniconazole, respectively. Therefore, in golf course green which allows rapid water percolation and has extremely low adsorption capacity, persistence in soil could be more important factor in determination of leaching potential of pesticides. Total quantity of pesticides leached from the model green was <0.2% for fenitrothion and triadimefon and 1.8% for diniconazole. Adsorption layers significantly reduced pesticide leaching, and active carbon and Orpar were more effective than zeolite. In the model green having adsorption layer of active carbon or Orpar, leaching loss of pesticides was reduced below 0.01% of the initial application.

• Journal of the Korean Society of Groundwater Environment
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• v.2 no.2
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• pp.58-63
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• 1995

Cokriging was applied for the estimation of the water levels of the basal leachate and the surrounding groundwater at the Nanjido waste landfill area. When the groundwater level is estimated at the high relief area, it makes a good result to use the data of groundwater level and elevation simultaneously because groundwater level is correlated with topography. This study determined the best semivariogram model of 87 groundwater levels and 144 elevations through cross validation test, and produced the contour maps of groundwater levels using ordinary kriging and universal kiging. Two contour maps don't make big difference at the waste site because this area has a large number of groundwater level data. However, they show big difference at the upper left part of the study area because this area has high relief and a small number of sample data. Their difference is also found at the south area near the Han river. When the topography is considered for the both areas, the contour map of cokriging is thought to be closer to the real groundwater distribution than that of kriging.

• Journal of the Korean Society of Groundwater Environment
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• v.7 no.1
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• pp.1-7
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• 2000

In order to reduce the groundwater contamination around the Kimpo landfill in Korea by the leakage of the leachate within it, The method establishing 5 sets of Radial Collector Well Laterals(RCWLs) within the landfill, the method utilizing the wells dewatering the condensed water, the method establishing an interception wall to the 2nd layer at the circumference of the landfill and 22 sets of RCWLs within it, and the method establishing an interception wall to the 3rd layer and 40 sets of RCWLs were studied. Hydraulic parameters were measured for this study and then the groundwater flow and contaminant transport systems around the Kimpo landfill were analyzed with the MODFLOW and MT3D models. Conclusively, the method establishing an interception wall to the 2nd layer and 22 sets of RCWLs was evaluated as the most stable and economical option to reduce groundwater contamination concentration below drinking water standards.

• Journal of the Korean Society of Groundwater Environment
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• v.4 no.4
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• pp.175-184
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• 1997

The Seokdae Waste Landfill is a middle-sized site used from June, 1987 to May, 1993. Many joints and faults are developed in andesitic rocks and rhyolitic rocks distributed at the landfill. The chemical analyses of leachates, streams and groundwaters sampled in July, 1996 and June, 1997 show that the concentrations of leachates and streams were decreased, and that the groundwater qualities became worse. The groundwater contamination is deeply extended to not only shallow groundwater but also bedrock-groundwater around the Seokdae Waste Landfill Area. The range of groundwater contamination by the leachates is about 500 m to the west and about 1 km to the south from the boundaries of the waste landfill. The development of monitoring wells and pumping wells, the construction of a leachate-treatment facilities, and the adjustment of the existing grout curtains are necessary for the control of water pollution at the Seokdae Waste Landfill Area.

• 한국지구물리탐사학회:학술대회논문집
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• 2001.09a
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• pp.104-121
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• 2001

Recently, the pollution of soil and groundwater becomes a serious social problem, and geophysical exploration methods have been introduced as a remedial investigation method of subsurface. Digital technologies such as personal computer have revolutionized our ability to acquire large volume of data in a short term, and to produce more reliable results for subsurface image. Also, color graphics easily visualizes the survey results in a more understandable manner, and it is widely used for not only characterizing the contaminated subsurface but also monitoring contaminant and remedial process. In this paper, electrical resistivity and electromagnetic (EM) surveys were carried out in order to understand characteristics of waste landfills, and the applicability of geophysical prospecting to site assessment of waste landfill was also tested. According to the result, electrical resistivity and electromagnetic (EM) surveys were effective in estimating distribution of the leachate plume.

• Journal of the Korean Society of Groundwater Environment
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• v.6 no.3
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• pp.107-110
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• 1999

18 boreholes with nitrate contaminated were selected. Samples were collected 4 times between both 1995 and 1996. Stable nitrogen isotope ratio for them all was measured and the contribution to contamination from several sources like fertilizer, sewage, cropland. and landfill was analysed. Nitrogen source for 11 sampling sites of T-3, L-1. O-1∼O-4, F-2∼F-5, and G-2 considered to come from chemical fertilizer and its contribution was around 60% or more. T-4. T-5 were located downward the downtown, which were influenced bydomestic sewage and its contribution were 70.7% and 54.7%. Nitrate concentration of G-2 was 17.7 mg/L, among which 60.7% was estimated to come from landfill leachate. T-1 and T-2 were located in the small village, in which 42.2 and 43.4% of nitrogen was to come from domestic sewage but 52.8% and 56.0% were from fertilizer sprayed in the cropland. L-2 was near livestock by which it was estimated to be influenced, in which 59.9% of nitrogen was from cropland. F-1 was in the cropland, by which 50.0% was influenced and 49.5% was estimated from organic matter of animals.

• Geophysics and Geophysical Exploration
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• v.21 no.4
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• pp.244-254
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• 2018

The first geophysical technique applied to the agricultural sector in Korea was electrical resistivity sounding and conducted in purpose of groundwater exploitation in the 1970s. According to the diversity of agricultural activities since the 1990s, various geophysical methods including electrical resistivity, electromagnetic induction, and self-potential method were applied to several agricultural fields such as soil characterization with saline concentration in vast reclaimed area, delineation of seawater intrusion regions in costal aquifer, safety inspection of embankment dikes with leakage problem, detection of ground subsidence from overpumping and tracing of groundwater aquifer contamination by leachate from livestock mortality burial or waste burial site. This paper introduces representative geophysical techniques that have been utilized in various agricultural fields and suggests several ways to develop the geophysical methods required for the precision agriculture field in the near future based on the past achievements.