• Korean Journal of Environmental Agriculture
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• v.12 no.1
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• pp.9-17
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• 1993

The leaching behavior of $^{14}C-carbofuran$, $^{14}C-bentazon$, and $^{14}C-3,3,4,4'-tetrachloroazobenzene(TCAB)$ in the forms of freshly treated, 3-month-aged, and 6-month-aged residues, respectively, was investigated in a loamy soil column system. The degradation and mobility of pesticides in soil and the possibility of the contamination of groundwater were followed by this approach: The ambient temperature of $15{\pm}2^{\circ}C$, irrigation by the constant-head method on soil columns, and leaching with 1332 ml of simulated precipitation during 90 days. While the fresh residues of $^{14}C-carbofuran$ and $^{14}C-bentazon$ were very mobile, the aged ones were remarkably reduced in their mobility. Fresh and aged residues of $^{14}C-TCAB$ were very immobile, instead. 3-Keto carbofuran phenol(2,3-dihydro-2,2-dimethyl-3-oxo-7-benzofuranol) was the major degradation product present in the leachate from the soil column containing freshly treated $^{14}C-carbofuran$, while no metabolites could be detected in the leachates from the columns containing $^{14}C-bentazon$ or $^{14}C-TCAB$.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 1997.04a
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• pp.88-89
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• 1997

• Journal of Korea Soil Environment Society
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• v.2 no.3
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• pp.39-47
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• 1997

Geochemical study was carried out to find out the distribution of metals and cyanide in soil in the vicinity of the abandoned Daduck mine and the reason for acid mine drainage occurrence in the tailings impoundment. Chemical analysis showed that content of As in soil around tailings exceeded 15mg/kg, Korean standard of soil contamination in the farm land. That means the contamination of soil by As is due to input of tailings. According to total decomposition of tailings, As, Cd, Cu, Pb, Zn and S were highly concentrated in tailings. However the water in tailings impoundment was changed to acidic and contaminated by metals and sulfate because the tailings in the top of the tailings impoundment had been oxidized. Acid mine drainage contaminated the water course in the vicinity of the paddy soils. The proper measures are required to prevent contamination of the soil and water in the vicinity of the Daduck mine.

• Journal of Environmental Impact Assessment
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• v.8 no.2
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• pp.9-20
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• 1999

Until 1993, Nanji landfill has been the main solid waste treatment facility for Seoul, which is the capital of Korea. Since the landfill has not been properly lined, soil and ground water around the landfill has been contaminated. Due to the proximity, it has been speculated that the water quality of the Han River would have been also influenced by the leachate. In order to illuminate this, HELP model to estimate the quantity of the leachate from Nanji landfill and RMA model to simulate the change of water quality in Han River were applied in this research. The result indicates that the quantity of leachate from Nanji landfill has been overestimated by previous works and it was due to the failure to consider the water storage capacity of the landfill. The effect from Nanji landfill leachate on the water quality, in terms of COD input, proves to be smaller than those from other tributaries and influents to the River and the effect is larger when the flow of the River is reversed due to the tide.

• Journal of the Korean Geotechnical Society
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• v.15 no.6
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• pp.99-109
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• 1999

In the case of domestic general waste landfills, cumulated leachate level is often formed in the landfill due to the waste of high moisture content and it becomes important to characterize the hydraulic properties of the disposed waste. Although many hydrologic studies have been peformed for leachate barriers and pheriperal subsurface environments, few studies have been done to investigate the hydraulic property of the disposed waste and cover soils and to analyse the leachate flow behavior within landfills. In this paper, the geotechnical properties of the waste and buried cover soils are identified through the field experiment including pumping and slug tests. The results of various tests show that the field density of the cover soils is somewhat higher than the maximum laboratory density of cover soils and the vertical flow of leachate and gas in the landfill is prevented by the buried cover soils. The hydraulic conductivities of field pumping test and slug tests are well matched and stayed in the range of hydraulic conductivities of well compacted wastes in the literature.

• Journal of the Korean Society of Groundwater Environment
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• v.1 no.1
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• pp.1-5
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• 1994

The contaminant migration through the subsurface of Nanjido landfill is studied using a 2-D finite element model of contaminant transport. The leachate mounding caused by the installation of partial slurry wall around the pheriperal area of the Landfill is analysed using the finite difference model of groundwater flow. Model parameters were validated using in-situ concentration data and the behavior of the transport next 30 years is predicted. The sensitivities of chloride concentration by the change of model parameters, e.g. leachate mounding in the Landfill and the dispersivity are analysed. The results of the analyses show that the maximum chloride concentration level near Han River caused by the leachate of Nanjido Landfill would be 1488mg/1 and comes 17 years after the landfill closure. Increase of the leachate concentration is caused by the increase of both the leachate mounding and the dispersivity. However, the rate of concentration increase becomes higher with the rise of leachate mounding level, while it tends to converge a certain concentration with the increase of the dispersivity.

• Journal of the Korean Society of Groundwater Environment
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• v.3 no.2
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• pp.51-59
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• 1996

In case waste disposal site is to be constructed close to the underground facilities such as LPG storage cavern which is completely maintained by groundwater pressure, it is generally requested that the possibility on leachate contamination of cavern area be reviewed and the countermeasure, if it is estimated cavern area is severely affected by leachate, be taken into consideration. Prediction was performed and leachate control plan was made using by analytical and the numerical analysis on the leachate migration which is likely to happen at the area between the proposed waste disposal site and the underground LPG storage cavern located at the U petrochemical complex. Analytical solutions were obtained by the conservative mass advection-diffusion equation and the effect of advection and dispersion factor on the leachate migration was reviewed through peclet number calculation and the functional relationship between the factors and leachate transport velocity was established, which leads to enable us to predict the leachate transport velocity without difficulties when different parameters (factors) are used for analytical solution. Numerical solutions were obtained by FEM using AQUA2D which is for the simulation of groundwater flow and contaminant transport. 3-D discrete fracture models were simulated and fracture flow analysis was performed and feasibility study on the water-curtain system was conducted through the fracture connectivity analysis in rock mass. As results of those analyses, it was interpreted that the leachate would trespass on the LPG storage cavern area in 30 years from the proposed wate disposal site and the vertical water-curtain system was effective mathod for the prevention of leachate's migration further into the cavern area.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.10a
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• pp.122-122
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• 2005

The remediation for contaminated soil and groundwater in contaminated site and waste site has to be compact and economic in maintaining and operating the system. In this study, the atomized slag was tested if they are an effective reactive material in permeable reactive barrier This novel reactive system technology was applied to the treatment of leachate from unplanned waste landfill. The system was optimized and developed to be commercialized.

• Journal of the Korean earth science society
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• v.24 no.4
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• pp.290-302
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• 2003

This study was carried out to evaluate geochemical properties for stream sediments, surrounding soils, sludge collected in the drainage pipe of leachate and waters (stream water, groundwater, leachate) around the Pungam Landfill in Gwangju city. The stream sediments don't show any systematic trend of contents from upstream to downstream. The most enriched major element in the stream sediments is Fe (up to 7.08wt.% in GJ-23). Though stream sediment GJ-23 and GJ-34 were enriched by some heavy metals (eg. As, Cu, Zn), they do not constitute serious problems for environment consideration. The concentration of Fe (35.lwt.%) and As (38ppm) are significantly high in the GJ-8, which is soil specimen adjacent to leachate reservoir. The sludge (GJ-7) shows very high concentrations of As, Mn, Cr, Pb. In particular, the Cr content is 45.6 ppm, which exceeds the permitted level. The leachate is characterized by high TDS (2210-2470mg/L) and high electric conductivity (468, 530ms/cm), and enriched in both cation (Na, K) and anion (HCO$_3$). The leachate(PK-3) had a relatively high concentration of Cl, and is plotted in Na-Cl type on the Piper's diagram. The NO$_3$-N of the groundwater and stream water exceeded the permitted levels for drinking water.

• Proceedings of the Korean Geotechical Society Conference
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• 2003.03a
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• pp.821-826
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• 2003

Laboratory experiments were peformed to understand physical properties of soil-cement column under the influence of acidic flow including metal contaminants and its retaining capacity against metal migration. The contaminant used in this study was nitric acid with Cu and Cd. The Permeability of soil-cement column decreased when pH of the column began to drop below 12. Decreases in pH led to significant reduction of compressive strength of clayey soil-cement specimen, while relatively marginal reduction for sandy soil-cement specimen. The metal contaminants did not leachate from soil-cement column until pH of soil-cement dropped below 7∼8 for Cu and 9∼10 for Cd. Metal contaminants were precipitated and trapped inside the soil-cement column at pHs higher than those mentioned as verified with metal analysis and visual inspection. This indicated that soil-cement column not only performs well as a cut-off wall, but also helps alleviating the level of contamination of the surrounding environment.