• 대한안전경영과학회지
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• 제14권1호
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• pp.43-51
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• 2012

This study was carried out to observe the impacts of a mouse's inhalation of toxic gas SO2 generated from combustion on its organs by different concentrations. As for research methods: First, after concentrations of SO2 generation from combustion had been set to three: low (10.4 ppm), middle (24.9 ppm) and high (122 ppm) through Gas Toxicity Testing Method (KS F 2271) and SO2 combustion gas was exposed to eight mice in each concentration. Five mice that were able to move based on LD50, a criterion, which sets the down time of a mouse's average behaviors to over 9 minutes, were randomly selected in each concentration, and they were set up as the subjects of the study on toxicity bio-markers. Second, tissues were taken from heart, liver, lungs, spleen and the thymus gland of the mice selected in each concentration and a pathological examination of them was carried out. As a result, microvascular congestion appeared in the heart, and cell necrosis, cortex congestion and tubule medulla congestion, etc. in each concentration were observed in addition to vascular congestion in liver, lungs, spleen and the thymus gland. Also, it was found that the higher the concentrations of SO2 exposure is, the greater, the changes in the organs get. Through this study, SO2 of various toxic gases generated from fire turned out to affect the tissues of each organ of a mouse, it is expected that the toxic gases may greatly affect human body in case of actual fire, and this study is evaluated as having a significance as a basic data on inhalation toxicity assessment of toxic substances generated in combustion.

• 한국화재소방학회논문지
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• 제29권4호
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• pp.57-60
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• 2015

화재 시 발생하는 독성 가스인 CO, HCl, HCN, $SO_2$를 방독면에 의해 제거하는 효율은 화재로 인한 인명구조의 핵심 요소이다. 머리와 목끈이 없는 탄력있는 방독면은 전방을 주시할 수 있는 창, 탄력후드, 가스정화기와 공기 환풍구로 되어 있어서 화재 시 빠르고 쉽게 착용할 수 있다. 이 연구에서는 이러한 방독면의 CO, HCl, HCN, $SO_2$ 제거 효율에 대한 연구를 진행하였다. 실험결과 CO 제거 효율은 최초 농도가 2505.0 ppm인 경우 3.5분 후에 99.99%였고, 8.5분 후에는 99.98%로 나타났다. 8.5분 후에는 CO 농도가 급격히 증가하는 특성을 보였다. HCl, HCN, $SO_2$에 대해서는 최초 농도가 각각 1003.0, 399.0, 100.3 ppm인 경우 20분 동안 제거 효율이 100%로 나타났다.

• 한국표면공학회지
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• 제54권2호
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• pp.43-52
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• 2021

The Ni-based superalloy, Inconel 740, was corroded between 800 and 1100℃ for up to 100 hr in air and Ar-0.2%SO₂ gas in order to study its corrosion behavior in air and sulfur/oxygen environment. It displayed relatively good corrosion resistance in both environment, because its corrosion was primarily dominated by not sulfidation but oxidation especially in Ar-0.2%SO₂ gas. Such was attributed to the thermodynamic stability of oxides of alloying elements when compared to corresponding sulfides. The scales consisted primarily of Cr₂O₃, together with some NiAl₂O₄, MnCr₂O₄, NiCrMnO₄, and rutile-TiO₂. Sulfur from SO₂ gas made scales prone to spallation, and thicker. It also widened the internal corrosion zone when compared to air. The corrosion resistance of IN740 was mainly indebted to the formation of protective Cr₂O₃-rich oxides, and suppression of the sulfide formation.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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• pp.43-45
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• 2012

The effect of limestone characteristics on in-furnace desulfurization was experimentally investigated at hot gas combustion condition in a drop tube furnace (DTF). Flue gas was measured by Gas analyzer in order to figure out $SO_2$ content. The experiments were performed under excess sulfur 3000ppm condition to examine the effect of operating variables such as reaction temperatures, Ca/S ratios on the $SO_2$ removal efficiencies. The results show that the $SO_2$ removal efficiency increased with reaction temperature and Ca/S ratio increase. When considering the economics, $1200^{\circ}C$ and Ca/S ratio 2 condition is optimized to reduce $SO_2$ emission.

• 센서학회지
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• 제32권3호
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• pp.147-153
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• 2023

Metal-organic frameworks (MOFs) of cobalt gallate were synthesized and deposited on gold electrodes using self-assembly monolayers (SAMs) and hydrothermal processing. These MOF films exhibit strong adsorption capabilities for gaseous particulates, and the use of SAMs allows the synthesis and deposition processes to be completed in a single step. When cobalt gallate is mixed with SAMs, a coordination bond is formed between the cobalt ion and the carboxylate or hydroxyl groups of the SAMs, particularly under hydrothermal conditions. Additionally, the quartz crystal microbalance (QCM) gas sensor accurately measures the number of particulates adsorbed on the MOF films in real-time. Thus, the QCM gas sensor is a valuable tool for quantitatively measuring gases, such as SO₂, NO₂, and CO₂. Furthermore, the QCM MOF film gas sensor was more effective for gas adsorption than the MOF particles alone and allowed the accurate modeling of gas adsorption. Moreover, the QCM MOF films accurately detect the adsorption-desorption mechanisms of SO₂ and NO₂, which exist as gaseous particulate matter, at specific gas concentrations.

• 멤브레인
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• 제2권2호
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• pp.135-143
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• 1992

여러가지 고분자막을 이용하여 $N_2-SO_2$ 혼합기체를 분리하는 데 있어서 압력, 온도 등을 조작변수로 하여 투과계수와 분리인자를 계산하고 이에 따른 기체투과 특성을 규명하고 분리성능을 측정하였다. 실험한 압력의 범위는 0.1~1.0 MPa이었으며, 온도범위는 283~303 K이었다. 압력이 커질수록 투과계수와 분리인자가 증가하였으나, 온도증가에 따라 투과계수와 분리인자는 감소하였다. 본 실험에서 사용된 막 중 Film-Tech사의 FT-30이 $N_2-SO_2$ 혼합기체의 분리능력이 가장 뛰어난 것으로 나타났다.

• 대한환경공학회지
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• 제29권1호
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• pp.62-67
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• 2007

본 연구의 목적은 액상 균일질 촉매를 이용하여 연소가스 중에 포함되어 있는 $SO_2/NO$의 동시제거 기술 개발에 있다. 연구는 bench scale/소규모 pilot scale에서 이루어졌으며 연구 결과는 다음과 같다. 1) $SO_2$는 실험조건에 상관없이 높은 제거효율을 가지는 것으로 확인되었다. 그러나 NO의 경우 충진층 높이가 증가할수록, 농도가 낮을수록, 촉매 분사량이 증가할수록 제거효율이 증가하는 것으로 나타났다. 2) Fe(II)-EDTA를 이용한 $SO_2/NO$ 동시처리 기술 개발을 위한 최적의 설계 인자는 충진 높이 =0.5 m, 액체-기체비 = 20 $L/m^3$, 반응기 단수=3단, 반응기 단면적 = 0.025 $m^2$로 결정하였다. 3) 연구 결과를 기초로 $SO_2/NO$의 동시처리 효율을 실험한 결과 각각 95%, 81% 이상 제거가 가능했다. 4) 높은 HTU는 NO의 제거에 있어 유리하지만 과도한 HTU는 스크러버의 운전효율을 감소시키므로 최적의 HTU를 결정하는 것이 필요하다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 봄 학술발표회 논문집
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• pp.261-266
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• 2003

This study is to investigate the heating value and noxious gases generation such as CO, NO and $SO_2$ known as dangerous gas for human from specimen made of cement and lightweight aggregate. The most quanity of CO gas is generated in EPS(Expanded Poly Styrene), core of commercial sandwich panel. Although specimens mainly composed of cement discharged the relatively less CO gas than organic core such as EPS, specimens which SBR was added discharged the very much amount of CO gas similar to EPS and especially, specimens including foaming agent, gas foaming agent or redipersible powder of VA/VeoVa showed the good properties in the generation of CO gas. From the standpoint of the generation of NO and $SO_2$ gas, both the core of commercial sandwich panel such as EPS, Glass wool and specimens made with polymer dispersion such as St/BA and SBR discharge the very much amount of NO and $SO_2$ gas in comparison of the other specimens. From this study, it was confirmed that organic materials such as core of commercial sandwich panel dischared much more noxious gas than specimens composed of cement and inorganic lightweight aggregate.

• Corrosion Science and Technology
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• 제18권6호
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• pp.285-291
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• 2019

In this study, the corrosion characteristics of T22 and T92 steel were investigated in 6O₂ + 16CO₂ + 2SO₂ gas environment at 650 ℃. Corrosion characteristics were characterized by weight gain, oxide layer thickness, scanning electron microscope, optical microscope, energy dispersive X-ray spectroscopy, and X-ray diffraction. T22 and T92 steel tended to stagnate oxide layer growth over time. Oxidation kinetics were analyzed using the data of oxide layer thickness, and a regression model was presented. The regression model was significantly acceptable. The corrosion rate between the two steels through the regression model showed significant difference. The T92 steel was approximately twice as large as the time exponent and showed very good corrosion resistance compared to the T22 steel. In both steels, the oxide layer mainly formed a Fe-rich oxide layer composed of hematite (Fe₂O₃), magnetite (Fe₃O₄), and spinel (FeCr₂O₄). Sulfide segregation occurred in the oxide layer due to SO₂ gas. However, the locations of segregation for the T22 and T92 steel were different.

• 한국응용과학기술학회지
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• 제28권4호
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• pp.455-463
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• 2011

The average sulfur content of crude oil is 2.2%. Coal is about 0.3 to 4.0 percent of the sulfur gases or particles being discharged into the atmosphere through the chimney as 1 to 2% $SO_3$(Sulfur trioxide) and about 95% of the $SO_2$ is reported. $SO_3$ gas, which has many different causes of, as the combustion of sulfur containing fuel during the air due to the excess $SO_2$ gas is oxidized to $SO_3$ gas. Sulfur trioxide emitted from high sulfur heavy oil fired boiler caused white plume in stack and high temperature and cold end corrosion of facilities. So, in order to control sulfur trioxide concentration of Fuel gas in boiler, various of additives are used in other foreign. They are injected to Fuel Oil and consumed in boiler and reduce ash and the conversion rate of sulfur trioxide. In domestic, MgO compounds are used as additives but the total volume of them are made from other foreign company. In this study, MgO compounds were developed with liquid MgO compounds and field application was accomplished. The effect of newly developed chemicals and process were nearly equal to foreign products. In Consequent, the chemicals and process produced by newly developed technology can be substituted for foreign products and reduce the cost of plant operation.