• Title/Summary/Keyword: SO

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The Effect of SO2 in Flue Gas on the SCR Activity of V/TiO2 (배가스 중 SO2가 V/TiO2 SCR활성에 미치는 영향)

  • Hong, Sung-Chang
    • Applied Chemistry for Engineering
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    • v.17 no.5
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    • pp.490-497
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    • 2006
  • $V_{2}O_{5}$/$TiO_{2}$ catalyst can be deactivated by ammonium salts formed by $SO_{2}$ oxidation and unreacted ammonium in presence of $SO_{2}$ in flue gas. The deactivation of catalyst by $SO_{2}$ depends on the $SO_{2}$ oxidation to $SO_{3}$. The oxidation of $SO_{2}$ is weakly affected by oxygen concentration, and strongly by the amount of vanadium loaded onto titania supports. Because unreacted ammonia is one of elements to form the ammonium salts, it is important to control the mole ratio of $NH_{3}/NOx$ in SCR. Thus the experiments about $NH_{3}/NOx$ were carried out. The reason of low activity of catalyst deactivated by ammonium salts is the change of pore volume. And TPD (Temperature Programmed Decomposition) was performed to find the decomposition of ammonium bisulfate on deactivated catalyst.

A Study on the Li$^+$ Ion Conducting Solid Electrolytes (Li$^+$ 이온성 고체전해질에 관한 연구)

  • Park Sung Ho;Lee Doo-Weon;Kim Keu Hong;Choi Jae Shi
    • Journal of the Korean Chemical Society
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    • v.35 no.4
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    • pp.324-328
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    • 1991
  • The Li$_2SO_4$ system containing various mol${\%}$ of CaSO$_4$ were synthesized. The structure and the electrical conduction of these system were studied at the temperature from 20 to 700$^{\circ}C$. In the region of CaSO$_4$ mol ratio higher than 0.05, it could be confirmed that Li$_2SO_4-CaSO_4$ system does not form solid solution. Due to the substituted Ca$^{2+}$, the transition temperature (monoclinic to cubic) is shifted to the low temperature. The ionic conduction of monoclinic Li$_2SO_4-CaSO_4$ increased with increasing lithium vacancy which was produced by substituted Ca$^{2+}$, but that fcc Li$_2SO_4-CaSO_4$ was not influenced by the substituted Ca$^{2+}$ ion.

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A Study on Synthesis of Potassium Sulfate used Sodium Sulfate and Potassium Chloride (황산나트륨과 염화칼륨을 사용한 황산칼륨 제조 연구)

  • Kim, Nam-Il;Kim, Tae-Yeon;Chu, Yong-Sik
    • Resources Recycling
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    • v.30 no.1
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    • pp.35-43
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    • 2021
  • In this study, Na2SO4 and KCl reagents were used to synthesize K2SO4 as a basic study for recycling byproducts generated during the manufacture of steel and cement. The mole ratio of Na2SO4 to KCl, the saturation of the solution, and the stirring temperature were controlled to derive the optimal manufacturing conditions. The microstructure and crystallinity of the materials prepared were evaluated using scanning electron microscopy and X-ray diffraction analysis. Pure K2SO4 was obtained when the mole ratio of Na2SO4 to KCl was 1:6-18, the saturation of the solution was less than 160%, and the stirring temperature was 20℃, 50℃. The optimal manufacturing conditions to maximize the crystallinity and yield of K2SO4 while minimizing the energy consumption were 1:6 mole ratio of Na2SO4 to KCl, 140% saturation of the solution, and 20℃ stirring temperature.

Hot Issue-세계 SoC 시장 전망

  • IT-SoC Association
    • IT SoC Magazine
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    • s.5
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    • pp.30-34
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    • 2005
  • 전체 반도체 시장이 연평균 10.7% 성장할 것으로 예측되고 있는 중, DRAM과 Flash가 메모리반도체 시장을 주도적으로 끌어나갈 것으로 예상되며 SoC 분야에서는 Digital Signal Processor (DSP), General Purpose Logic, Standard Linear가 시장을 주도적으로 이끌어 나갈 것으로 점쳐진다. 특히 General Purpose Logic은 SoC 전체에서 가장 높은 13.6%의 성장을 기록하면서 전체 반도체 시장에서 차지하는 비중도 5.9%에서 6.9%로 1% 상승하여 빠른 성장을 보이면서 시장 내의 비중이 제고될 것으로 예상된다

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Reactivity of SO2 Catalytic Reduction over Sn-Zr Based Catalyst under High Pressure Condition (고압조건에서 Sn-Zr계 촉매상에서 SO2 촉매환원 반응특성)

  • Park, Jung Yun;Park, No-Kuk;Lee, Tae Jin;Baek, Jeom-In;Ryu, Chong Kul
    • Korean Chemical Engineering Research
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    • v.48 no.3
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    • pp.316-321
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    • 2010
  • The $SO_2$ catalytic reduction was carried out under the condition of high pressure in this study. Sn-Zr based oxide and CO were used as the catalyst and reducing agent for the reduction of $SO_2$ to element sulfur, respectively. In order to compare the reactivity with the pressure on the catalytic process, the reactivity tests were performed under the conditions of atmospheric pressure and 20 atm. $SO_2$ conversion, the element sulfur yield and COS selectivity were also compared with changing the reaction temperature, $CO/SO_2$ mole ratio and the space velocity(GHSV). $SO_2$ conversion increased with increasing temperature and $CO/SO_2$ mole ratio under the condition of atmospheric pressure and element sulfur yield decreased due to the production of COS by the series reaction of CO and the produced sulfur. However, high $SO_2$ conversion and high element sulfur were obtained under the condition of 20 atm. It was concluded that COS decreased due to the condensation of the produced element sulfur under the condition of high pressure. Therefore, the high sulfur yield for $SO_2$ catalytic reduction could be profitably obtained under the condition of high pressure.

Pre-Irradiation Grafting of Acrylic Acid onto Polyethylene Film (전조사법에 의한 아크릴산의 폴리에틸렌 필름에 대한 그라프트 반응)

  • Nho, Young Chang;Jin, Joon-Ha;Lee, Myun Zu
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.75-82
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    • 1996
  • Acrylic acid was graft-copolymerized on polyethylene film in the presence of additives such as acid and $FeSO_4(NH_4)_2SO_4{\cdot}6H_2O$ using peroxide grafting technique by ${\gamma}$-ray and electron beam, and the effect of $FeSO_4(NH_4)_2SO_4{\cdot}6H_2O$ and acid on the grafting yield was evaluated. The grafting mechanism and the physical property of grafted films were also examined. The results showed that the inclusion of $FeSO_4(NH_4)_2SO_4{\cdot}6H_2O$ in acidified acrylic acid grafting solution was extremely beneficial and led to a most unusual enhancement effect in the radiation grafting. In the other hand, inclusion of mineral acid in the grafting solution in the absence of $FeSO_4(NH_4)_2SO_4{\cdot}6H_2O$ could not lead to he suitable grafting reaction by the severe homopolymerization of acrylic acid. The addition of $H_2SO_4$, and HCl led to much higher grafting yield than $HNO_3$and $CH_3COOH$. It was shown that grafting yield of ${\gamma}$-ray irradiated-polyethylene was higher than that of electron beam irradiated polyethylene.

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An Experimental Study on the Difference of Blood Constituent in Four Types of Physical Constitution (체질(體質)에 따른 혈중(血中) 성분(成分)의 차이(差異)에 관(關)한 실험적(實驗的) 고찰(考察))

  • Choi, Moon-Kyu
    • The Journal of Internal Korean Medicine
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    • v.13 no.2
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    • pp.48-56
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    • 1992
  • Comparative blook analysis was carried out to investigate the difference of blood constituent in four types of physical constitution. Isoleucine(Ile), Alanine(Ala), Cysteine(Cys), Tyrosine(Tyr), Methionine(Met) were measured. And the following results were obtained: 1. The value of Isoleucine(Ile) on the constitution didn't shown significant difference, but between the value of SO-YANG-IN and SO-EUM-IN showed significant difference. 2. The value of Alanine(Ala) on the constitution didn't shown significant difference. 3. The value of Cysteine(Cys) on the constitution didn't shown significant difference, but between the value of SO-YANG-IN and SO-EUM-IN showed significant difference. 4. Between the value of control group and SO-YANG-IN showed significant difference, and between the value of SO-YANG-IN and TAE-EUM-IN, SO-YANG-IN and SO-EUM-IN showed significant difference. 5. Between the value of control group and SO-YANG-IN showed significant difference.

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A comparative study on the reading process of So Myong-so (만옹 서명서의 독서단계론 비교연구)

  • 김상호
    • Journal of Korean Library and Information Science Society
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    • v.22
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    • pp.277-297
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    • 1995
  • Historical study on the reading in Choson has been mostly focussed on few scholar's viewpoint of reading. This research has revealed the reading process of So Myong-So, and has compared it with the reading process of other scholars. As a result of the research the following have been clarified. a. So Myong-so reorganized the reading process of Yuk Se-ui, divided it into the five steps, and made the systematic reading program. b. So Myong-so made the list of selected books which included not only confucian literature, but also taoist, buddhist, and practical. c. So's reading process and selected booklist were different in system and scale from other's : Im Sang-dok, Hwang Dok-gil, and Kang P'il-hyo.

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On the Characteristics of the SO$_2$ Concentration Variation in Pusan, Korea (부산 지역의 SO$_2$ 농도 변화 특성에 관한 고찰)

  • 전병일;김유근;이화운
    • Journal of Korean Society for Atmospheric Environment
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    • v.10 no.4
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    • pp.245-251
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    • 1994
  • We considered that characteristics of SO$_2$, concentration level and relations of the meteorological parameters and high pollution concentration from the data measured 7 air quality continuous monitoring stations during 4 years, from 1990 to 1993 in Pusan. The SO$_2$ concentration level showed decreasing trend yearly, it was maximum in Winter, minimum in Summer. The time of SO$_2$ peak concentration lagged from seashore to land because of break-down of the nocturnal inversion layer and seabreeze. Ihe correlations of daily SO$_2$, value between various air quality continuous monitoring stations were highest between Beomcheondong and Meongryundong, lowest between Daeyeondong and Sinpyeongdong because of difference of air Pollution emission sources characteristic. The meteorological parameters affecting SO$_2$ concentration level were minimum temperature, relative humidity, wind speed and air pressure. The SO$_2$ high pollution($\geq$95ppb) occurred almost in Winter, particulaly in such day showing lower wind speed and higher air pressure. Elementary SO$_2$ high Pollution Predictor were high pressure system and stability of lower atmosphere.

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Low Power SoC Design Trends Using EDA Tools (설계툴을 사용한 저전력 SoC 설계 동향)

  • Park, Nam Jin;Joo, Yu Sang;Na, Jung-Chan
    • Electronics and Telecommunications Trends
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    • v.35 no.2
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    • pp.69-78
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    • 2020
  • Small portable devices such as mobile phones and laptops currently display a trend of high power consumption owing to their characteristics of high speed and multifunctionality. Low-power SoC design is one of the important factors that must be considered to increase portable time at limited battery capacities. Popular low power SoC design techniques include clock gating, multi-threshold voltage, power gating, and multi-voltage design. With a decreasing semiconductor process technology size, leakage power can surpass dynamic power in total power consumption; therefore, appropriate low-power SoC design techniques must be combined to reduce power consumption to meet the power specifications. This study examines several low-power SoC design trends that reduce semiconductor SoC dynamic and static power using EDA tools. Low-power SoC design technology can be a competitive advantage, especially in the IoT and AI edge environments, where power usage is typically limited.