• Title/Summary/Keyword: SN ratio

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HYDROGEN PLASMA DURABILITY OF $SnO_2$:F FILMS (불소 도핑 이산화주석 박막의 수소플라즈마 내구성)

  • Yoon, Kyung-Hoon;Song, Jin-Soo;kang, Kee-Hwan
    • Proceedings of the KIEE Conference
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    • 1992.07b
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    • pp.847-849
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    • 1992
  • Fluorine-doped ($SnO_2$:F) thin films obtained by pyrosol deposition method have been exposed to R.F. excited pure hydrogen plasma under the following conditions; substrate temperature of 200$^{\circ}C$, $H_2$ pressure of 1 Torr, R.F. input power of 50 mW/$\textrm{cm}^{2}$, $H_2$ flow rate of 30cc/min and exposure time of 15-600 seconds. It is found that the sheet resistance of the films remains unchanged or rather slightly reduces for initial exposure time of 30-60 seconds, but increases sharply with further increasing the exposure time. The optical transmittance of $SnO_2$:F films slows a rapid fall with increasing exposure time except for a film obtained with a solution having $CH_3OH/H_2O$ mol ratio of 2.65, its degradations at the exposure time of 30-60 seconds are about 7-15%. In addition, the exposure of the films to hydrogen plasma atmosphere leads to remarkable changes in the microstructure and chemical composition, which should be attributed to the reduction of $SnO_2$ to SnO and to elemental Sn.

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Study on Indium-free and Indium-reduced thin film solar absorber materials for photovoltaic application

  • Wibowo, Rachmat Adhi;Kim, Gyu-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.270-273
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    • 2007
  • In this report, Indium-free and Indium-reduced thin film materials for solar absorber were studied in order to search alternative materials for thin film solar cell. The films of $Cu_2ZnSnSe_4$ and $Cu_2ZnSnSe_2$ were deposited using mixed binary chalcogenides powders. From the film bulk analysis result, it is observed that Cu concentration is a function of substrate temperature as well as CuSe mole ratio in the target. Under optimized conditions, $Cu_2ZnSnSe_4$ and $Cu_2ZnSnSe_2$ thin films grow with strong (112), (220/204) and (312/116) reflections. Films are found to exhibit a high absorption coefficient of $10^4$ $cm^{-1}$. $Cu_2ZnSnSe_4$ film shows a 1.5 eV band gap. On the other side, an increasing of optical band gap from 1.0 eV to 1.25 eV ($CuInSnSe_2$) is found to be proportional with an increasing of Zn concentration. All films have a p-type semiconductor characteristic with a carrier concentration in the order of $10^{14}$ $cm^{-3}$, a mobility about $10^1$ $cm^{2{\cdot}-1.}S^{-1}$ and a resistivity at the range of $10^2-10^6$ ${\Omega}{\cdot}m$.

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CHANGE OF LATERAL SOFT TISSUE PROFILE AFTER SURGICAL CORRECTION OF MANDIBULAR PROGNATHISM (하악전돌증의 악교정수술후 연조직 변화에 관한 연구)

  • Lee, Sang-Chull;Kim, Yeo-Gab;Ryu, Dong-Mok;Lee, Wan-Kee
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.14 no.3
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    • pp.217-227
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    • 1992
  • The purpose of this paper is to investigate changes in soft tissue in 22 patients treated by vertical ramus osteotomy and sagittal split ramus osteotomy for the correction of mandibular prognathism. 22 individuals, 12 males and 10 females, were selected from the patients with mandibular prognathism at the Department of Oral and Maxillofacial Surgery, Colledge of Dentistry, Kyung Hee University. Patient were analyzed with cephalogram taken 1 week before and at least 6 weeks after surgery under the same condition. Measurements were made constructed hard tissue and sop tissue points located on each before-and-after film tracing. Comparision were made of these figures to estimate the amount that the soft tissue followed the hard tissue structures in each surgical procedure : ratio of sop and hard tissue changes were formulated. The results were as follows. 1. The horizontal changes of Pogs and Bs as a ratio of the horizontal changes of Pog and B point were 1.02 and 1.16 respectively. 2. One millimeter of posterior changes at Pog resulted in 0.86mm of posterior change at Li and 0.09mm of posterior change at Ls. The greatest amount of sop tissue change occurred at Pogs, with substantially less posterior displacement at Bs, even less at Li and at least at Ls. 3. The ratio of LI to Li was 1:0.81 and the ratio of LI to Ls was not significant.(1 : 0.17) 4. The ULA(Cm-Sn-Ls) and the relative lower lip projection (LLP) was incnease4 but the relative upper lip projection (ULP) was slightly decreased 5. The angular change of the upper lip inclined angle (Ls-Sn/ANS-PNS) and lower lip inclined angle(Li-Pogs/Me-Go) expressed as a ratio of the posterior change of Pog were 0.57 and 0.20 respectively. 6. The ratio of the lower anterior facial height change of the soft tissue(Sn-Mes) to the hard tissue(ANS-Gn) were 0.78 and and the ratio of vertical height changes of the hard tissue and sop tissue to the posterior change of the Pog were 0.18 and 0.19 respectively. 7. The sop tissue angular change of facial convexity(G-Sn-Pogs) expressed as a ratio of the angular change of the hard tissue angle of facial convexity(N-A-Pog) was 1.24.

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CO Sensing Properties in Layer structure of SnO2-ZnO System prepared by Thick film Process (SnO2-ZnO계 후막센서 구조에 따른 CO 감지 특성)

  • Park, Bo-Seok;Hong, Kwang-Joon;Kim, Ho-Gi;Park, Jin-Seoung
    • Journal of Sensor Science and Technology
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    • v.11 no.3
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    • pp.155-162
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    • 2002
  • The sensing properties of carbon monooxide were investigated as a function of mixing ratio and the lamination structure of 3mol% ZnO-doped $SnO_2$ and 3mol% $SnO_2$-doped ZnO. The lamination structures were fabricared monolayer, double layer, and hetero layer of $SnO_2$, Zno, and theirs mixture composition using thick film process. There was no second phase by the reaction of $SnO_2$ and ZnO. The conductance was decreased by the addition of ZnO in $SnO_2$, but it was increased with the addition of $SnO_2$ in ZnO. The conductance was increased with temperature and the inlet of CO. There was no improvement of sensitivity in the structure of mono- and double-layer. The hetero-layer structure, however, of $SnO_2$ 3ZnO-ZnO $3SnO_2$ showed the higher resistivity and the highest sensitivity. Ohmic characteristics was confirmed by the linear properties for I-V measurements.

Study on the Silicone Contact Lens Using AA and BMA (AA(Acrylic acid)와 BMA(Butyl methacrylate)를 이용한 실리콘 콘택트렌즈에 관한 연구)

  • Kim, Tae-Hun;Yae, Ki-Hun;Kweon, Young-Seok;Sung, A-Young
    • Journal of Korean Ophthalmic Optics Society
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    • v.11 no.3
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    • pp.259-265
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    • 2006
  • We polymerized material of AA(Acrylic acid) and BMA(butyl methacrylate) to make up for the weak points of hydrogel contact lens. The synthesis process of silicone synthesis is as follows. Acrylate-PDMS(Polydimethylsiloxane)-Urethane prepolymer was composed after Diisocynate reacted with HEMA(2-hydroxyethylmethacrylate) under the catalyst and it reacted again with bis(hydroxyalkyl) terminated poly(dimethylsiloxane) with high oxygen transmissibility characteristics. HEMA(2-hydroxyethylmethacrylate) was used to make prepolymer that can be polymerized and the urethane was used to improve elasticity and oxygen transmissibility, copolymerization was performed with conventional hydrogel contact lens materials to make silicone hydrogel contact lens with higher oxygen transmissibility. For manufacturing of contact lens, We added BMA(Butyl methacrylate) with better elasticity and flexibility, and AA(Acrylic acid) with higher moisturizing to used contact lens materials. AIBN (Azobis2-methylpropionitrile) as initiator and EGDMA(Ethylene Glycol Dimethacrylat) as crosslinking agent were used and the lens with higher oxygen transmissibility and better moisturizing were manufactured complying with basic contact lens properties, which have several combination trial of each monomer characteristics. Compounding SN which included SILICONE, HEMA, NVP and EGDMA etc was showed by swelling ratio of 9.38% and water content of 23.7%. SN was showed by swelling ratio of 9.38%, water content of 23.7% and a visible ray transmissibility of 89%. SB which added BMA in the SN was showed by swelling ratio of 12.50%, water content of 18.56% and a visible ray transmissibility of 88%. SAB which added both AA and BMA in the SN was showed by swelling ratio of 8.33%, water content of 12.93% and a visible ray transmissibility of 88%.

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Cephalometric study of the effect of cervical pull headgear based on facial growth patterns (안모의 성장유형에 따른 경부견인 헤드기어의 효과에 대한 두부방사선계측학적 연구)

  • Kang, Eun-Ha;Chang, Chongon
    • The korean journal of orthodontics
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    • v.29 no.4 s.75
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    • pp.503-510
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    • 1999
  • The purpose of this study is to investigate the negative effects of cervical pull headgear and to compare the differences between the two groups of growers-vertical grower and horizontal grower group-which are classified by the posterior-anterior facial height ratio. Initial and final lateral cephalograms were taken for 26 patients including 15 vertical growers and 11 horizontal growers ; also, 3 angular measurements and 4 linear measurements were evaluated. The following results were found. 1. The palatal plane was tipped anteroinferiorly in the vertical grower group. 2. The posterior facial height/anterior facial height ratio was increased in the horizontal grower group. 3. The Mandibular plane angle remained stable on both groups. 4. There was no significant difference between the two groups in the amount of maxillary molar extrusion.

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Optimization of Lipase-Catalyzed Interesterification for Production of Human Milk Fat Substitutes by Response Surface Methodology (반응표면분석에 의한 모유대체지의 효소적 합성조건 최적화)

  • Son, Jeoung-Mae;Lee, Jeung-Hee;Xue, Cheng-Lian;Hong, Soon-Taek;Lee, Ki-Teak
    • Korean Journal of Food Science and Technology
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    • v.43 no.6
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    • pp.689-695
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    • 2011
  • 1,3-Dioleoyl-2-palmitoylglycerol (OPO)-rich human milk fat substitute (HMFS) was synthesized from tripalmitin (PPP)-rich fraction and oleic ethyl ester by a lipase-catalyzed interesterification. Response surface methodology (RSM) was employed to optimize the presence of palmitic acid at sn-2 position ($Y_1$, %) and of oleic acid at sn-1,3 ($Y_2$, %), with the reaction factors as substrate molar ratio of PPP-rich fraction to oleic ethyl ester ($X_1$, 1:4, 1:5 and 1:6), reaction temperature ($X_2$, 50, 55 and $60^{\circ}C$), and time ($X_3$, 3, 7.5 and 12 h). The optimal conditions for HMFS synthesis were predicted at the reaction combination of $55^{\circ}C$, 3 h and 1:6 substrate ratio. HMFS re-synthesized under the same conditions displayed 70.70% palmitic acid at the sn-2 position and 69.58% oleic acid at the sn-1,3 position. Reaction product was predominantly (90.35%) triacylglycerol (TAG) was observed in which the major TAG species, OPO, comprised 31.24%.

A Optimization Procedure for Robust Design (로버스트 설계에 대한 최적화 방안)

  • Kwon, Yong-Man;Hong, Yeon-Woong
    • Proceedings of the Korean Society for Quality Management Conference
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    • 1998.11a
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    • pp.556-567
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    • 1998
  • Robust design in industry is an approach to reducing performance variation of quality characteristic value in products and processes. Taguchi has used the signal-to-noise ratio(SN) to achieve the appropriate set of operating conditions where variability around target is low in the Taguchi parameter design. Taguchi has dealt with having constraints on both the mean and variability of a characteristic (the dual response problem) by combining information on both mean and variability into an SN. Many Statisticians criticize the Taguchi techniques of analysis, particularly those based on the SN. In this paper we propose a substantially simpler optimization procedure for robust design to solve the dual response problems without resorting to SN. Two examples illustrate this procedure. in the two different experimental design(product array, combined array) approaches.

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Role of Different Oxide to Fuel Ratios in Solution Combustion Synthesis of SnO2 Nanoparticles

  • Chavan, Archana U.;Kim, Ji-Hye;Im, Ha-Ni;Song, Sun-Ju
    • Journal of the Korean Ceramic Society
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    • v.53 no.1
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    • pp.122-127
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    • 2016
  • Tin oxide ($SnO_2$) nanoparticles have been synthesized by solution combustion method using citric acid as a fuel. The oxide to fuel ratio has been varied to obtain ultrafine nanoparticles with better surface area; such particles will be useful in many applications. With this synthesis method, spherical particles are formed having a particle size in the range of 11-30 nm and BET surface area of ~ $24m^2/g$. The degree of agglomeration of $SnO_2$ nanoparticles has been calculated.

High Molecular Weight Poly(L-lactide) Synthesized in Supercritical Fluids

  • Kim, Soo-Hyun
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.210-211
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    • 2006
  • A series of L-LA polymerizations initiated by $Sn(Oct)_{2}\;([LA]_{0}/[Sn]_{0}=200)$ were carried out in scR22 at $130^{\circ}C$ and 300 bar, where $[LA]_{0}$ is the initial L-lactide concentration and $[Sn]_{0}$ is the initial $Sn(Oct)_{2}$ concentration. The reaction time dependences of monomer conversion and PLLA MW improved. The monomer conversion and PLLA MW increased with increasing reaction time. The effect of temperature on monomer conversion and PLLA MW was investigated in a series of polymerizations conducted at temperatures ranging from 90 to $150^{\circ}C$ and at a constant pressure of 200 bar. In all of these experiments, the ratio of monomer to R22 concentration was held constant at 12.4 wt.-%. Increasing the reaction temperature from 90 to $130^{\circ}C$ resulted in increased monomer conversion from 11.5 to 72.2 %.

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