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Preparation and Characterization of Nylon 6,5 Copolymers from ε-Caprolactam and 2-Piperidone (ε-Caprolactam과 2-Piperidone으로부터 나일론 6,5 공중합체 제조 및 특성평가)

  • Kim, Hye Young;Goh, Jin-Seon;Ryu, Mi Hee;Kim, Dae Su;Song, Bong-Keun;Lee, Seung Hwan;Park, Si-Jae;Jegal, Jonggeon
    • Polymer(Korea)
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    • v.38 no.1
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    • pp.31-37
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    • 2014
  • To prepare biomass based nylon 6,5 copolymers, ${\varepsilon}$-caprolactam and 2-piperidone, the monomers of nylon 6,5 copolymers, were synthesized respectively from lysine and 5-aminovaleric acid which were produced from glucose by the fermentation process. The copolymers were then polymerized by the anionic ring opening polymerization of them at $40^{\circ}C$, using potassium tert-butoxide as a catalyst and acetyl-2-caprolactam and carbon dioxide as initiators. The prepared copolymers were characterized with various analytical methods: their viscosity molecular weight ($M_{\eta}$) was as high as 30000 g/mol and polymerization yield was over 50%, and it was found that they were semi-crystalline polymers having melting point at $165^{\circ}C$ which was much lower than its thermal degradation point, $250^{\circ}C$. These polymers were expected to have good thermal processability and application fields.

Fabrication and optical characteristics of 50 ㎓ narrow band pass filter for fiber optical communication using dual ion beam sputtering technique (이중 이온빔 스퍼터링 방식을 사용한 채널 간격 50 ㎓ 광통신용 협대역 투과 필터의 제작 및 특성)

  • 김회경;김명진
    • Korean Journal of Optics and Photonics
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    • v.14 no.3
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    • pp.331-337
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    • 2003
  • This paper represents 50 ㎓ narrow band pass filters for fiber optical communication fabricated by dual ion beam sputtering method. We have analyzed the characteristics of the TA$_2$ $O_{5}$ and $SiO_2$ single layers in order to optimize the process conditions for the 50 ㎓ narrow band pass filters, and controlled the film thickness uniformity to less than 0.1 nm deviation by dual peak spike filter pre-deposition. We designed and fabricated 50 ㎓ narrow band pass filters that consist of 216 layers including 4 cavities based on quarter wave optical thickness. Class substrates with high thermal expansion coefficients were used to reduce the film stress. Anti-reflection coating at the rear side of the substrate was also needed to reduce the optical thickness errors of the Optical Monitoring System caused by multiple beam interference between the front side and the rear side of substrate. The optical characteristics of this 50 ㎓ narrow band pass filters are insertion loss of 0.40 ㏈, pass band ripple of 0.20 ㏈, and pass bandwidth at -0.5 ㏈ of 0.20 nm. and isolation bandwidth at -25 ㏈ of 0.6 nm, which satisfy specifications of dense WDM system in fiber optical communications.tions.

A Study of Algal Succession and Community Structure on Artificial Reef at Yangyang-gun and Pohang-si, Korea (양양군과 포항 해역에 시설한 인공어초에서 진행된 해조천이와 군집에 관한 연구)

  • Lee, Hyeon Jin;Choi, Chang Geun
    • Journal of Marine Life Science
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    • v.4 no.2
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    • pp.81-85
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    • 2019
  • This study was carried out to observe the changes of seaweed community in artificial reefs installed in September, 2016 in Namae-ri, Yangyang-gun, and Seokbyeong-ri, Pohangsi, Korea. Field surveys were conducted by SCUBA diving once a season in February, May, August, and November of 2017, and quantitative survey and qualitative survey were carried out in parallel. In this study, a total of 94 species, including 11 green algae, 15 brown algae and 68 red algae were appeared. 66 species (8 green algae, 9 brown algae, 49 red algae) and 65 species (7 green algae, 9 brown algae, 49 red algae) were collected and identified in Yangyang and Pohang. In dominant species, Yangyang was dominant species of Saccharina japonica and subdominant species of Ulva australis. Pohang dominated in order of Colpomenia sinuosa and Gelidium elegans. In both coastal areas, Ulva spp., Colpomenia sinuosa were grown at the early stage of reforestation, and perennial seaweeds such as Saccharina japonica, Ecklonia cava and Gelidium elegans were grown. In order to clarify the clustering relation through flora change, it is necessary to monitor the transition process until the seaweed community is stabilized by observing the long-term change through continuous monitoring.

High Voltage β-Ga2O3 Power Metal-Oxide-Semiconductor Field-Effect Transistors (고전압 β-산화갈륨(β-Ga2O3) 전력 MOSFETs)

  • Mun, Jae-Kyoung;Cho, Kyujun;Chang, Woojin;Lee, Hyungseok;Bae, Sungbum;Kim, Jeongjin;Sung, Hokun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.3
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    • pp.201-206
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    • 2019
  • This report constitutes the first demonstration in Korea of single-crystal lateral gallium oxide ($Ga_2O_3$) as a metal-oxide-semiconductor field-effect-transistor (MOSFET), with a breakdown voltage in excess of 480 V. A Si-doped channel layer was grown on a Fe-doped semi-insulating ${\beta}-Ga_2O_3$ (010) substrate by molecular beam epitaxy. The single-crystal substrate was grown by the edge-defined film-fed growth method and wafered to a size of $10{\times}15mm^2$. Although we fabricated several types of power devices using the same process, we only report the characterization of a finger-type MOSFET with a gate length ($L_g$) of $2{\mu}m$ and a gate-drain spacing ($L_{gd}$) of $5{\mu}m$. The MOSFET showed a favorable drain current modulation according to the gate voltage swing. A complete drain current pinch-off feature was also obtained for $V_{gs}<-6V$, and the three-terminal off-state breakdown voltage was over 482 V in a $L_{gd}=5{\mu}m$ device measured in Fluorinert ambient at $V_{gs}=-10V$. A low drain leakage current of 4.7 nA at the off-state led to a high on/off drain current ratio of approximately $5.3{\times}10^5$. These device characteristics indicate the promising potential of $Ga_2O_3$-based electrical devices for next-generation high-power device applications, such as electrical autonomous vehicles, railroads, photovoltaics, renewable energy, and industry.

Study on the Scan Field of Modified Octupole and Quadrupole Deflector in a Microcolumn (마이크로칼럼에서 변형된 4중극 디플렉터와 8중극 디플렉터의 스캔 영역 비교)

  • Kim, Young Chul;Kim, Ho-Seob;Ahn, Seong Joon;Oh, Tae-Sik;Kim, Dae-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.11
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    • pp.1-7
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    • 2018
  • In a microcolumn, a miniaturized electrostatic deflector is often adopted to scan an electron beam. Usually, a double octupole deflector is used because it can avoid excessive spherical aberrations by controlling the electron beam path close to the optical axis of the objective lens and has a wide scan field. Studies on microcolumns have been performed to improve the low throughput of an electron column through multiple column applications. On the other hand, as the number of microcolumns increases, the number of wires connected to the components of the microcolumn increases. This will result in practical problems during the process of connecting the wires to electronic controllers outside of the vacuum chamber. To reduce this problem, modified quadrupole and octupole deflectors were examined through simulation analysis by selecting an ultraminiaturized microcolumn with the Einzel lens eliminated. The modified deflectors were designed changing the size of each electrode of the conventional Si octupole deflector. The variations of the scan field and electric field strength were studied by changing the size of active electrodes to which the deflection voltage was to be applied. The scan field increased linearly with increasing deflection voltage. The scan field of the quadrupole deflector and the electric field strength at the center were calculated to be approximately 1.3 ~ 2.0 times larger than those of the octupole deflector depending on the electrode size.

A Systematic Review of Moxibustion for Frozen Shoulder (동결견에 대한 뜸치료 효과의 체계적 문헌고찰)

  • Han, Si-Hoon;Lee, Gi-Eon;Byun, Da-Young;Kim, Young-Ik;Kim, Min-Kyun;Min, Boo-Ki;Lim, Han-Bit;Jeong, Yun-Jae;Oh, Min-Seok
    • Journal of Korean Medicine Rehabilitation
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    • v.29 no.3
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    • pp.35-49
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    • 2019
  • Objectives The purpose of this research is to evaluate the effectiveness of moxibustion theraphy for frozen shoulder through systematic review and meta-analysis. Methods The effect of moxibustion for frozen shoulder was constructed as a key question to search randomized controlled trials (RCTs) in 16 databases without type of publication restriction. Results A total of 790 studies were searched and 22 RCTs were finally selected through primary and secondary selection/exclusion process. In most of the evaluation indexes used in each study, moxibustion treatment for shoulder pain was statistically significant compared with other treatments. A meta-analysis of effective rate in 10 studies comparing moxibustion with acupuncture and acupuncture showed a statistically significant effect of moxibustion treatment. And there was a significant effect on the improvement of the shoulder mobility, but the effect size of shoulder pain was no significant effect for shoulder pain reduction. In addition in the result of meta-analysis of 4 studies' effective rate comparing moxibustion with electronic acupuncture, the effect of moxibustion was significantly higher than that of electronic acupuncture in frozen shoulder. Conclusions Moxibustion therapy was effective in symptoms in patients with frozen shoulder. However because of the high risk of bias in the quality of the included studies, the applicability of this study seems to be limited. It is thought that future randomized controlled trials will need to be designed and performed by reviewing ways to minimize bias.

A Study of Maintenance Method by Monitoring and Evaluation of Water Friendly Facilitiesin Urban Streams - A Case Study of Jeonjucheon in Jeonju-si - (하천친수시설의 모니터링과 평가를 통한 유지관리방안 연구 - 전주천을 중심으로 -)

  • Lim, Hyunjeong;Jeong, Moonsun
    • Journal of Environmental Impact Assessment
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    • v.28 no.3
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    • pp.263-274
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    • 2019
  • The purpose of this study is to examine a monitoring method, management zones, and maintenance strategies for water friendly facilities in urban streams after the completion of ecological restoration projects. Maintenance monitoring items are composed of 'use space& facilities', 'trails& bike roads', 'access', and 'boards'. The evaluation standards of water friendly facilities are 'maintenance conditions', 'safety', and 'usage level' which are rated as 'good', 'moderate', and 'poor'. Through a field survey and evaluation of 15 stream sections in Jeonjucheon,the management levels of each water friendly facility are determined as 'priority maintenance', 'general maintenance', 'maintain/remove', and 'remove'. Based on the evaluation results, management zones and maintenance strategies are proposed for each stream section. As a results, the stream sections of J2, J3, J4, and J9 which have 5 to 9 facilities with 'priority maintenance' are determined as 'intensive management zone'. The stream sections of J5, J6, J7, J8, J11, and J14 which have 1 to 3 facilities with 'priority maintenance' are determined as 'regular management zone'. The stream sections of J1, J10, J12, J13, and J15 which have no facilities with 'priority maintenance' are determined as 'minimum management zone'. The process of monitoring & evaluation system and determining management zones can be applied to establish a systematic maintenance plan for water friendly facilities by participation of governance in the future.

UX Design Evaluation and its Approach to Mobile Applications for Smart Appliances (스마트 애플리케이션 UX 디자인 평가 접근 방법)

  • You, Si Cheon;Choi, Jinyoung;Sim, Mihee
    • Smart Media Journal
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    • v.8 no.3
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    • pp.70-79
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    • 2019
  • Implementing UX design that meets user expectations has become an important variable that determines the prominence of smart home appliances. This study addresses the UX design evaluation issues in mobile application development of smart home appliances. As an experimental research subject, the UX design evaluation contents were set up for the mobile application of , the demand of which is surging recently. The purpose of the research is to explore the significance of the UX design user evaluation method in smart home applications, and to suggest how to achieve the mixing of quantitative and qualitative evaluation methods. The main findings are as follows. First, we found that user evaluation can positively impact the direction of UX design. Secondly, we found that the mixing of 'quantitative' and 'qualitative' methods works complementarily to UX design evaluation. Research implications are as follows. The UX design evaluation process can be performed efficiently as long as we distinguish between the roles of quantitative evaluation and qualitative evaluation. For example, through qualitative evaluation such as 'Honeycomb model', can be identified in terms of 'exploratory', and through qualitative evaluation such as 'in-depth user interview', can be identified in terms of 'assessment' and 'validation'.

Application of Standardized North American Marsh Bird Monitoring Protocols to Survey Inconspicuous Marsh Birds in Korea (은둔형 습지 조류의 효과적인 조사 방법 탐색을 위한 국외 프로토콜의 시범 적용)

  • Lee, Sang-Yeon;Sung, Ha-Cheol
    • Korean Journal of Ecology and Environment
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    • v.52 no.2
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    • pp.143-150
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    • 2019
  • Although inconspicuous marsh birds are an indicator of marsh health, there is little understanding of their status and population trends due to their behavioral characteristics and lack of reliable survey methods in Korea. We applied the Standardized North American Marsh Bird Monitoring Protocols(SNAMBMP) already validated in North America for effective survey of the marsh birds. We selected 29 sites with emergent marshes, rice fields and riparian forests in Seocheon-gun, Buyeo-gun and Gunsan-si. We conducted the survey with a combination of passive 5 minute point-count and vocal survey method (30 seconds call-broadcasting+30 seconds silence) that was targeted eight species 2~7 times/site from March to July 2017. Four species, Brown-cheeked Rail(Rallus indicus), Ruddy-breasted Crake (Porzana fusca), Watercock (Gallicrex cinerea) and Greater Painted-snipe (Rostatula benghalensis), were detected at one site respectively (naïve occupancy rate=0.035). Vocal survey method with conspecific call-broadcasting provided better on Brown-cheeked Rail and Watercock than the others. We suggest a combination of passive point-count and vocal survey method like SNAMBMP to monitor inconspicuous marsh birds at nationwide scale and collection of sound files through recording of the entire process during the survey.

The Effect of Acetonitrile on the Texture Properties of Sodium Silicate Based Silica Aerogels (아세토니트릴 첨가가 물유리 기반 실리카 에어로겔의 기공구조에 미치는 영향)

  • Kim, Younghun;Kim, Taehee;Shim, Jong Gil;Park, Hyung-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.25 no.4
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    • pp.143-148
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    • 2018
  • Sodium silicate based silica aerogels are lower in cost than silica alkoxide based silica aerogels, but the demand is decreasing as their physical properties are lowered. In this research, acetonitrile as a drying control chemical additive (DCCA) is added in the sol state to improve the pore-structural properties of sodium silicate based silica aerogel by preventing the agglomeration of particles and cross-linked bond. The sodium silicate based silica aerogel by ambient pressure drying were prepared by sol-gel process. Acetonitrile/$Na_2SiO_3$ molar ratio of 0, 0.05, 0.1, 0.15, and 0.2 was added to the sol state. The physical properties of the final product were analyzed using Fourier transform infrared, contact angle measurement, Brunauer-Emmett-Teller and Barrett-Joyner-Halenda measurements and field emission scanning electron microscopy. It was confirmed that the sample with adding 0.15 molar ratio of acetonitrile and sodium silicate showed a high specific surface area ($577m^2/g$), a high pore volume (3.29 cc/g), and a high porosity (93%) comparable to the pore-structural properties of silica alkoxide based silica aerogels.