• Title/Summary/Keyword: SGR

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Characterization of Synthesized Carbonate and Sulfate Green Rusts: Formation Mechanisms and Physicochemical Properties (합성된 탄산염 및 황산염 그린 러스트의 형성 메커니즘과 이화학적 특성 규명)

  • Lee, Seon Yong;Choi, Su-Yeon;Chang, Bongsu;Lee, Young Jae
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.2
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    • pp.111-123
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    • 2022
  • Carbonate green rust (CGR) and sulfate green rust (SGR) commonly occur in nature. In this study, CGR and SGR were synthesized through co-precipitation, and their formation mechanisms and physicochemical properties were investigated. X-ray diffraction (XRD) and Rietveld refinement showed both CGR and SGR with layered double hydroxide structure were successfully synthesized without any secondary phases under each synthetic condition. Refined structural parameters (unit cell) for two green rusts were a (=b) = 3.17 Å and c = 22.52 Å for CGR and a (=b) = 5.50 Å and c = 10.97 Å for SGR with the crystallite size 57.8 nm in diameter from (003) reflection and 40.1 nm from (001) reflections, respectively. Scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDS) results showed that both CGR and SGR had typical hexagonal plate-like crystal morphologies but their chemical composition is different in the content of C and S. In addition, Fourier transform infrared (FT-IR) spectroscopy analysis revealed that carbonate (CO32-) and sulfate (SO42-) molecules were occupied as interlayer anions of CGR and SGR, respectively. These SEM/EDS and FT-IR results were in good agreement with XRD results. Changes in the solution chemistry (i.e., pH, Eh and residual iron concentrations (Fe(II):Fe(III)) of the mixed solution) were observed as a function of the injection time of hydroxyl ion (OH-) into the iron solution. Three different stages were observed in the formation of both CGR and SGR; precursor, intermediator, and green rust in the formation of both CGR and SGR. This study provides co-precipitation methods for CGR and SGR in a way of the stable synthesis. In addition, our findings for the formation mechanisms of the two green rusts and their physicochemical properties will provide crucial information with researches and industrials in utilizing green rust.

A Study on the Durability and Environmentally Friendly of Inorganic Grouting Material (무기질계 지반주입재의 내구성 및 친환경적 특성에 관한 연구)

  • Chun, Byungsik;Park, Dukhyum;Kang, Hyoungnam;Do, Jongnam
    • Journal of the Korean GEO-environmental Society
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    • v.9 no.5
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    • pp.37-43
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    • 2008
  • Inorganic injection material, which is one of the ground improvement materials, consists of cement accelerator and inorganic micro particle. The inorganic injection material is known to overcome the major limitations of water glass type improvement materials, which are leaching and accompanying strength loss. The inorganic injection material is superior in durability and strength, and environmentally friendly since leaching is prevented. In this study, the effectiveness and environment-friendliness of the MIS(Micro Injection-process System) using the inorganic injection material is compared to SGR, which uses the water glass. The performed tests were unconfined compression test, chemical resistance test, and fish poison test. The unconfined compression tests showed that the MIS results in 1.7 times higher 28 day strength compared to the SGR. In addition, the strength continually increased with time for the MIS, while it decreased for the SGR. The chemical resistance tests indicated that the rate of change in length using the MIS is 10~25 times smaller than when using the SGR. The fish poison test proved that MIS was more environmentally friendly. The analysis of chemical ingredients of leached showed that the amount of $Cr^{6+}$, Pb and Si leached from the MIS is less compared to the SGR. Accordingly, the MIS grout is more high-strength than existing SGR grout. It is excellent in shortening of construction period, structural stability of foundation and environmentally friendly. So, it is considered that it has not little the problem about groundwater pollution.

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The Durability of Environmentally Friendly Inorganic Grouting Material(NDS) (친환경적인 무기질계 주입재(NDS)의 내구성에 관한 연구)

  • Lee, Hyejin;Lee, Jonghwi;Jung, kyoungsik;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.7
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    • pp.49-56
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    • 2011
  • Recently, the ground injection method using water glass as one of the components of the main resources and the products of the construction has some basic problems for permanent reinforcement of foundation and stopping leakage of water because it has some serious problems such as durability reduction, compression strength reduction and eluviation. This study was to evaluate the environmental impact and durability of the developed friendliness of Natural and Durable Stabilizer(NDS) of inorganic injection and Space Grouting Roket(SGR) with typical water glass type material. Two materials, NDS and SGR, were compared with each other by unconfined compressive strength test, fish poison test, durability test and triaxial permeability test. The results of the durability test indicated that the 28-day strength of the NDS was 1.5 times higher than that of the SGR. The fish poison test proved that the survival rate in the SGR and NDS is 50~70%, and 100%, respectively. Therefore, the NDS has higher survival rate than that of the existing SGR. The NDS will be considered by an environmentally friendly product and moreover it has a few problems for soil and groundwater pollution.

SgrA* 22GHz KaVA(+TAK) observation and its Amplitude Calibration

  • CHO, ILJE;JUNG, TAEHYUN;ZHAO, GUANG-YAO;KINO, MOTOKI;SOHN, BONGWON
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.2
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    • pp.52.2-52.2
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    • 2015
  • SgrA* located in the center of the Milky Way is of great interest to understand the physics of supermassive black hole(SMBH) and the interaction of the G2 cloud around SgrA* with the accretion flow which was expected since 2013. In order to seize this rare opportunity, KVN and VERA Array (so called, KaVA) has started an intensive monitoring program of SgrA* at 22/43 GHz where scatter broadening is reduced compared to lower frequency VLBI observations. We present the results of KaVA SgrA* observation together with Takahagi (32m) and Yamaguchi (32m) telescopes at 22 GHz on March 24, 2013. We have tested both a standard amplitude calibration methods using the Tsys and antenna gain information and a template amplitude calibration method which uses a peak of H2O maser line of nearby maser source (SgrB2), and found that the latter method is useful when an accuracy of Tsys measurement or antenna gain of a telescope is poor. In our comparison, the difference between the two methods is around 20% (~5% for the KVN and ~15% for the VERA when the elevation is above $20^{\circ}$). We also imaged SgrA* with a total flux of ~0.7 Jy at 22GHz, and fitted an elliptical Gaussian model which has a size of ~2.5mas for major axis and ~1.7mas for minor axis, respectively.

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Effect of Heat Processed Ginseng on Anti-Fatigue (가공 인상의 항피로효과)

  • Shin, Y.W.;Choi, H.J.;Kim, D.H.;Park, J.H.;Kim, N.J.
    • Korean Journal of Pharmacognosy
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    • v.37 no.4 s.147
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    • pp.246-252
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    • 2006
  • Processing of traditional herbal medicine is one of the pharmaceutical technique in oriental medicine. Most frequently used processing method in oriental medicine are roasting and steaming. In this studies, to elucidate the pharmacological transformation of traditional herbal medicine by means of processing them, Ginseng Radix (root of Panax ginseng, Araliaceae) was used as a sample. Processed ginseng radix (SGR, Sun Ginseng) was prepared by steaming of roots of white ginseng (GR) for 3 hours at $120^{\circ}C$. The biological activities of methanol extract of GR and SGR were investigated. According to DPPH radical scavenging effects, and inhibitory effects of xanthine oxidase and AAPH induced hemolysis, PGR exhibited more effective than those of GR in vitro. And, the antifatigue effect of GR and SGR were investigated using a weight-loading forced swimming test by monitoring swimming times and prolonged intensity exercise model rats by measuring blood biochemical parameters. GR and SGR were significantly prolonged swimming times in 8% body weight ratio loaded mice. Also, they had the inhibitory effects on the decrease of blood glucose levels, the elevation of serum creatinine, lactic acid and free fatty acid, and lactic dehydrogenase activities in forces swimming rats with 1% of the body weight attached to the neck for 3 hours. SGR was more excellent than GR on these effect. Also, these effects were transformed to the n-butanol fraction of methanol extract of SGR. From these results, it can be considered that SGR has antifatigue effect.

Predictive mathematical model for the growth kinetics of Listeria monocytogenes on smoked salmon (온도와 시간을 주요 변수로한 훈제연어에서의 Listeria monocytogenes 성장예측모델)

  • Cho, Joon-Il;Lee, Soon-Ho;Lim, Ji-Su;Kwak, Hyo-Sun;Hwang, In-Gyun
    • Journal of Food Hygiene and Safety
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    • v.26 no.2
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    • pp.120-124
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    • 2011
  • Predictive mathematical models were developed for predicting the kinetics of growth of Listeria monocytogenes in smoked salmon, which is the popular ready-to-eat foods in the world, as a function of temperature (4, 10, 20 and $30^{\circ}C$). At these storage temperature, the primary growth curve fit well ($r^2$=0.989~0.996) to a Gompertz equation to obtain specific growth rate (SGR) and lag time (LT). The Polynomial model for natural logarithm transformation of the SGR and LT as a function of temperature was obtained by nonlinear regression (Prism, version 4.0, GraphPad Software). Results indicate L. monocytogenes growth was affected by temperature mainly, and SGR model equation is $365.3-31.94^*Temperature+0.6661^*Temperature^{\wedge^2}$ and LT model equation is $0.1162-0.01674^*Temperature+0.0009303^*Temperature{\wedge^2}$. As storage temperature decreased $30^{\circ}C$ to $4^{\circ}C$, SGR decreased and LT increased respectively. Polynomial model was identified as appropriate secondary model for SGR and LT on the basis of most statistical indices such as bias factor (1.01 by SGR, 1.55 by LT) and accuracy factor (1.03 by SGR, 1.58 by LT).

OBSERVATIONS OF THERMAL TRANSITIONS OF SiO TOWARD THE SGR A MOLECULAR CLOUD (Sgr A 분자운의 열적 SiO 천이선 관측연구)

  • MINH Y. C.;ROH D.-G.;KIM S. J.;OHISHI M.
    • Publications of The Korean Astronomical Society
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    • v.16 no.1
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    • pp.15-20
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    • 2001
  • We observed the thermal transitions of SiO (J=I-0, 2-1) and $^{29}SiO$ (J=l-O) toward the Sgr A molecular clouds. The distribution and the velocity structure of SiO are very similar to previous results for 'quiet' interstellar molecules. We think· that the SiO has been well mixed with other molecules such as $H_2$ which may indicate that the formation of Sgr A molecular clouds was affected by the activities, such as shock waves or energetic photons, from the Galactic center in large scales. The total column density of SiO is about $4.1\times10^{14} cm^{-2}$ and the fractional abundance $SiO/H_2$ appears to be about 10 times larger than those of other clouds in the central region of our galaxy. The derived values are thought to be lower limits since the optical depths of the observed SiO lines are not very thin. The formation of SiO has been known to be critically related to shocks, and our results provide informative data on the environment of our Galactic center.

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Antisense expression of a staygreen gene (SGR) delays leaf senescence in creeping bentgrass

  • Hwang, Ok-Jin;Han, Yun-Jeong;Paek, Nam-Chon;Kim, Jeong-Il
    • Rapid Communication in Photoscience
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    • v.3 no.2
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    • pp.28-31
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    • 2014
  • Loss of chlorophyll is the visible symptom of leaf senescence and staygreen refers to the delayed leaf senescence in plants. The staygreen gene (SGR) in rice (Oryza sativa L.) has been identified as its mutation maintains greenness during leaf senescence, and encodes a chloroplast protein required for the initiation of chlorophyll breakdown in plants. In this study, we isolated a rice SGR-homologous gene in creeping bentgrass (Agrostis stolonifera L.), and transgenic creeping bentgrass plants were obtained by introducing pCAMBIA3301 vector harboring antisense SGR gene under control of the senescence-specific SAG12 promoter. Transgenic plants were selected by herbicide resistance assays and genomic integration of the transgenes was confirmed by PCR analysis. Subsequent analyses demonstrated the staygreen phenotype of the transgenic creeping bentgrass plants with decreased chlorophyll loss during leaf senescence. These results suggest that the antisense SGR expression in creeping bentgrass delays leaf senescence, which provides a way to develop genetically engineered turfgrass varieties with the commercially useful staygreen trait.

siRNA Interference with a Proliferation-Inducing Ligand Gene in the Sgr-7901 Gastric Carcinoma Cell Line

  • Ni, Shao-Zhong;Cao, Hong-Yong;Chen, Zheng;Zhu, Yi;Xu, Ze-Kuan
    • Asian Pacific Journal of Cancer Prevention
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    • v.13 no.4
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    • pp.1511-1514
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    • 2012
  • Objective: The present study aimed to investigate the influence of siRNA interference with a proliferation-inducing ligand (APRIL) gene on gastric carcinoma sgr-7901 cell apoptosis. Correlations between APRIL silencing and tyrosine kinase (trka) expression were also explored. Methods: Two APRIL-silencing siRNA vectors were constructed, and transfected into human gastric carcinoma sgr-7901 cells, expression before and after transfection being detected using RT-PCR and western blot analyses. The expression of 15 trka genes was detected using RT-PCR and apoptotic rates of sgr-7901 were assessed by flow cytometry. Results: The expression levels of receptor trka genes were significantly decreased, and the apoptotic rate of sgr-7901 was significantly increased after transfection (P < 0.05). Conclusion: APRIL gene silencing can increase the apoptotic rate of gastric carcinoma cells, and inhibit the expression of receptor trka genes. There is a correlation between the signaling pathways of APRIL and trka.

KaVA and EAVN large program on two Supermassive Black Holes, Sgr A∗ and M87

  • Sohn, Bong Won;Kino, Motoki
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.52.1-52.1
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    • 2019
  • Exploring the vicinity of super-massive black holes (SMBHs) is one of the frontiers in astrophysics. KaVA AGN Science WG has launched its Large Program in 2014 focusing on two SMBHs, Sgr A∗ and M87. They are selected based on their large apparent size. Sgr A∗ is the excellent laboratory for studying gas accretion process onto SMBH and M87 is well known as the best case for investigating plasma outflow ultimately driven by SMBH. For Sgr A∗, KaVA and EAVN provides superb UV-coverage on its emitting region and its scattering medium. In the case of M87, we have conducted high cadence dual-frequency (22and 43GHz )VLBI monitoring to clarify the global profile of the M87 jet velocity field and the spectral index map, which should reflect global structure of magnetic fields in the jet. From 2017, the AGN LP is recognized as multi-wavelength EHT project, conducting quasi-simultaneous coherent observations of M87 and Sgr A∗ with the Event Horizon Telescope (EHT) during its campaign observation periods. AGN WG is reviewing and revising its LP to convert it to EAVN LP. We will briefly report our scientific results and future plan which includes even broader international collaboration, namely East-Asia to Italy Nearly Global (EATING) VLBI to reach higher angular resolution.

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