• 제목/요약/키워드: SF-1

검색결과 1,183건 처리시간 0.029초

sII $SF_6+H_2$ 하이드레이트의 분자 거동 (Molecular Behavior of $SF_6+H_2$ Structure II Hydrates)

  • 박다혜;이보람;사정훈;;이건홍
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
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    • pp.122.2-122.2
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    • 2011
  • Sulfur hexafluoride ($SF_6$), one of the most potent greenhouse gases, is known as a hydrate former and has been studied at the high pressure up to 1.3 GPa with gas mixtures and with aqueous surfactant. Since we regard $SF_6$ as a potential promoter molecule that can stabilize hydrate structure more effectively compare to the other promoters, further investigation is required to verify the stabilizing ability of $SF_6$ in the hydrate structure. However, the insoluble nature of $SF_6$ in water or gases hinders fine scale analyses. This work discusses the data obtained by using molecular dynamics simulations of structure II (sII) clathrate hydrates containing $SF_6$ and $H_2$. The simulations were performed using the TIP4P/Ice model for water molecule and a previously reported $SF_6$ molecular model (optimized at the pure $SF_6$ single phase system (Olivet and Vega, 2007)), and a $H_2$ molecular model (adapted from the THF+$H_2$ hydrate system (Alavi et al., 2006)). The simulations are performed to observe the stability of $SF_6$ and $H_2$ in the sII clathrate hydrate system with varying temperature and pressure conditions and occupancies of $SF_6$ and $H_2$, which cannot be easily tuned experimentally. We observe that stability of H2 enclathrated in the hydrate structure more affected by the occupancy of $SF_6$ molecules and temperature than pressure, which ranges from 1 to 100 bar.

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뇌임펄스전압에 대한 SF6와 dry-air의 절연특성 (Dielectric Characteristics of SF6 and Dry-Air Gases under Lightning Impulse Voltage)

  • 이봉;유양우;김동규;이복희
    • 조명전기설비학회논문지
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    • 제24권8호
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    • pp.142-149
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    • 2010
  • 본 논문은 준평등전계에서 뇌임펄스전압에 대한 $SF_6$와 dry-air의 절연파괴 특성에 대하여 기술하였다. 준평등전계로 사용된 구-평판전극계의 전계이용률은 71[%]이다. $SF_6$는 0.1~0.2[MPa] 범위에서, dry-air는 0.2~0.6[MPa]에서 $SF_6$와 dry-air의 절연파괴전압을 임펄스전압의 극성과 가스압력에 따라 측정 분석하였다. 그 결과 뇌임펄스전압에 대한 두 가스의 절연파괴전압은 정극성이 부극성보다 높았으며, $SF_6$의 절연파괴전압이 dry-air의 절연파괴전압보다 약 2.67배정도 높았다. 본 연구결과는 뇌서지에 대하여 우수한 성능을 가지는 배전기기에서 $SF_6$의 대체가스 성능 평가에 유용한 정보가 될 것이다.

SF6-N2 혼합가스 중 돌출 결함의 부분방전 특성 (Partial Discharge Characteristics on Protrusion Defects in SF6-N2 Mixture Gases)

  • 조향은;왕국명;김선재;박경수;길경석
    • 한국전기전자재료학회논문지
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    • 제29권1호
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    • pp.44-49
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    • 2016
  • Studies on a $SF_6$-mixture and -alternative gas has been in progress to reduce the use of $SF_6$ gas as an insulation material of GIS (gas insulated switchgears). In this paper, we dealt with PD (partial discharge) characteristics in pure $SF_6$ and $N_2$, and their mixtures on aspects of insulation design and risk assessment for GIS. A POC (protrusion on conductor) and a POE (protrusion on enclosure) as the major defects were fabricated to simulate PD. We analyzed the DIV (discharge inception voltage), DEV (discharge extinction voltage), pulse magnitude, counts and phase distribution of PD pulse in $SF_6-N_2$ mixtures ($SF_6$ 100%, $SF_6$ 80%-$N_2$ 20%, $SF_6$ 50%-$N_2$ 50%, $SF_6$ 20%-$N_2$ 80%, and $N_2$ 100%) according to the IEC60270. The DIV, DEV as well as magnitude of PD pulse decreased on the POC as increase of $N_2$ ratio. For the POE, the DIV and DEV in $N_2$ ratio below 50% were the same voltages as those in $SF_6$ 100%. In this experiment, $SF_6$ 80%-$N_2$ 20% mixture could be considered with the equivalent insulation performance to a GIS.

콩식이섬유를 첨가한 식빵의 이화학적 및 품질 특성 (The Physicochemical and Quality Properties of the Bread Added with Soy Fiber Powder)

  • 이명호;변종범;김선경;최영심
    • 한국조리학회지
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    • 제18권1호
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    • pp.1-14
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    • 2012
  • 본 연구는 여러 가지 생리활성 물질을 가지고 있는 콩식이섬유의 섭취를 증가시키기 위하여 콩식이섬유 SF-1450과 SF-1260을 각각 강력분에 0~12% 첨가하여 식빵을 제조하였다. 콩식이섬유 복합분의 식이섬유 함량은 SF-1450, SF-1260 각각 72.0%, 67.8%이었다. Mixograph 특성은 midline peak height, width at peak, width at 8.00 에서는 콩식이섬유 첨가량이 증가할수록 증가하는 경향을 보였다. 식빵의 비용적은 콩식이섬유 첨가량이 증가할수록 대조구보다 유의적으로 감소하는 경향을 보였다. Crust 색도변화는 콩식이섬유의 첨가량이 증가할수록 각각 L값은 4~12% 첨가구에서 대조구보다 유의적으로 증가하였고 a값은 SF-1450은 6~12% 첨가구, SF-1260은 8~12% 첨가구에서 대조구보다 유의적으로 감소하였으며 crumb 색도변화는 b 값의 경우 대조부보다 유의적으로 증가하였다.(p<0.05). Texture의 특성인 경도의 경우 SF-1450은 10~12% 첨가구에서, SF-1260은 6~12% 첨가구에서 대조구보다 유의적으로 증가하였다. 이상에서 살펴본 바와 같이 콩식이섬유 첨가식빵의 관능특성은 첨가량이 증가함에 따라 대조구보다 품질이 떨어지는 현상을 보였고, 이화학적 분석과 전체적인 기호도를 종합해보면 SF-1450의 경우는 2~4%, SF-1260의 경우는 2% 첨가구의 경우가 우수하게 평가되었다.

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The Effect of Molecular Weight on the Gelation Behavior of Regenerated Silk Solutions

  • Cho, Hee-Jung;Um, In-Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • 제23권1호
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    • pp.183-186
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    • 2011
  • The various molecular weight (MW) regenerated silk fibroins were prepared with different dissolution condition and the effect of MW on the gelation behavior of regenerated aqueous silk fibroin (SF) solution was investigated. The result of gelation time measurement indicated that the gelation of SF aqueous solution was accelerated by the increase of MW and SF concentration. When formic acid was added in SF aqueous solution, the gelation time of SFL and SFC30 aqueous solution showed a significant decreaseat 0.03% formic acid addition. In case of the lowest MW sample, SFC180, SF molecules became aggregated and precipitated without gelation after 28 days storage time. These findings indicate that MW control of SF can be utilized to control the gelation time of SF aqueous solution.

Gelation of silk fibroin solution via β-sheet formation promoted by riboflavin-mediated photo-crosslinking

  • Choi, Jaeho;Ki, Chang Seok
    • International Journal of Industrial Entomology and Biomaterials
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    • 제45권1호
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    • pp.12-16
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    • 2022
  • Di-tyrosine photo-crosslinking of silk fibroin (SF) is recently highlighted as a biocompatible hydrogel fabrication process, because this method does not need potentially harmful chemical species. However, the resulting crosslinking density is often insufficient to obtain a mechanically stiff hydrogel unless additional oxygen is provided during the reaction. In this study, we proposed a combinational crosslinking method to form an SF hydrogel via the di-tyrosine photo-crosslinking with riboflavin (photoinitiator) and physical interaction of SF chains. In the UV light-irradiated SF solution, small particles formed and these particles promoted β-sheet formation of SF molecules, resulting in quick gelation. The di-tyrosine photo-crosslinking produced nuclei that might trigger regular assembly of SF molecules in high temperature condition. Conclusively, this process would contribute to a development of biocompatible hydrogel fabrication for biomedical uses of SF hydrogels.

Effect of Heifer Frame Score on Growth, Fertility, and Economics

  • Senturklu, S.;Landblom, D.G.;Perry, G.A.;Petry, T.
    • Asian-Australasian Journal of Animal Sciences
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    • 제28권1호
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    • pp.69-78
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    • 2015
  • A non-traditional forage-based protocol was employed to evaluate replacement heifer growth, fertility, and economics between small frame (SF, 3.50; n = 50) and large frame (LF, 5.56; n = 50) heifers using three increasing gain growth phases. Preceding an 85 d growing-breeding period (Phase 3; P3) the heifers were managed as a common group for Phases 1 and 2 (P1 and P2). During P1, heifers grazed common fields of unharvested corn and corn residue (total digestible nutrients [TDN] 56%) with supplemental hay. For P2, heifers grazed early spring crested wheatgrass pasture (CWG; TDN 62%) that was followed by the final P3 drylot growing and breeding period (TDN 68%). Small frame heifers were lighter at the end of P1 in May and at the start of P3 breeding in August (p = 0.0002). Percent of mature body weight (BW) at the end of P1 (209 d) was 48.7% and 46.8%, respectively, for the SF and LF heifers and the percent pubertal was lower for SF than for LF heifers (18.0% vs 40.0%; p = 0.02). At breeding initiation (P3), the percentage of mature BW was 57.8 and 57.2 and the percentage pubertal was 90.0 and 96.0 (p = 0.07) for the SF and LF heifers, respectively; a 5-fold increase for SF heifers. Breeding cycle pregnancy on days 21, 42, and 63, and total percent pregnant did not differ (p>0.10). In drylot, SF heifer dry matter intake (DMI) was 20.1% less (p = 0.001) and feed cost/d was 20.3% lower (p = 0.001), but feed cost/kg of gain did not differ between SF and LF heifers (p = 0.41). Economically important live animal measurements for muscling were measured in May and at the end of the study in October. SF heifers had greater L. dorsi muscle area per unit of BW than LF heifers (p = 0.03). Small frame heifer value was lower at weaning (p = 0.005) and the non-pregnant ending heifer value was lower for SF heifers than for the LF heifers (p = 0.005). However, the total development cost was lower for SF heifers (p = 0.001) and the net cost per pregnant heifer, after accounting for the sale of non-pregnant heifers, was lower for SF heifers (p = 0.004). These data suggest that high breeding efficiency can be attained among March-April born SF and LF virgin heifers when transitioned to a more favorable May-June calving period through the strategic use of grazed and harvested forages resulting in a lower net cost per pregnant SF heifer.

Reliability and Validity of the Early Trauma Inventory Self Report-Short Form among Korean Adolescents

  • Park, Subin
    • Journal of the Korean Academy of Child and Adolescent Psychiatry
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    • 제29권1호
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    • pp.2-6
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    • 2018
  • Objectives: Experiencing early childhood trauma is related to multiple psychiatric problems in adolescents and adulthood. This study aimed to examine the reliability and validity of the Korean version of the Early Trauma Inventory Self Report-Short Form (ETISR-SF) among Korean adolescents. Methods: A total of 86 adolescents aged 12-17 years (mean age $14.50{\pm}1.35years$, range 12-17) were assessed using the ETISR-SF. Other instruments, including the Children's Depression Inventory (CDI), the revised Children's Manifest Anxiety Scale (RCMAS), and the List of Threatening Experiences Questionnaire (LTE-Q), were used to assess clinical symptoms. After 2 months, 51 of the 86 participants were evaluated using the ETISR-SF to assess test-retest reliability. Results: The Cronbach's coefficient alpha for the ETISR-SF was high (0.803). Adolescents with depressive disorder showed higher ETISR-SF scores compared to healthy controls. The ETISR-SF scores were correlated higher with the scores on the LTE-Q (r=0.485) than with the scores on the CDI or RCMAS (r=0.165 and 0.347, respectively). Conclusion: The ETISR-SF was temporally stable, showing acceptable reliability (r=0.776). These findings suggest that the Korean version of the ETISR-SF appears to be a reliable and valid instrument for the measurement of reported childhood trauma.

전력설비에서의 SF6 저감기술 동향 및 특성 분석 (Trends and Characteristics in SF6 Emission Reduction Technology of Electrical Equipment)

  • 김예원;김정만;박상혁;이문구
    • 한국기후변화학회지
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    • 제4권3호
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    • pp.269-278
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    • 2013
  • $SF_6$ 가스는 $CO_2$에 비해 배출량은 적지만 GWP는 $CO_2$ 가스의 22,800배1)로 높으며, 최근 $non-CO_2$에 의한 온실가스 규제가 강화됨으로에 따라 온실가스 감축을 고려한 친환경 $SF_6$ 처리 기술 개발이 대두되고 있다. 본 연구에서는 전력설비 내에서 절연체로 사용되는 $SF_6$ 가스의 배출양상에 따른 배출 특성을 분석하고, 그에 따른 $SF_6$ 가스 저감기술을 살펴보았다. 주요 기술로는 사용 중의 유지보수와 폐기단계에 적용될 수 있는 가스의 회수율($85{\rightarrow}99%$)을 재고시키는 기술과 $SF_6$ 가스 제거를 위한 촉매 제조에 관한 기술 및 차단기 내부 점검 시 별도 $SF_6$ 가스 회수 없이 충전된 상태에서 내시경으로 차단기 내부를 점검하여 $SF_6$ 가스를 저감하는 기술이 있으며, 이러한 기술을 통해 대기 중 $SF_6$ 가스 저감이 이루어질 것으로 판단된다.

Raman Spectroscopy를 이용한 $SF_6$ 혼합 하이드레이트의 분광학적 해석에 관한 연구 (A Study on Spectroscopic Analysis by using Raman Spectrometer of Multi-Guest Mixed Hydrates Containing $SF_6$)

  • 신형준;문동현;김민철;김영석;서용원;이강우
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2008년도 추계학술대회 논문집
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    • pp.223-225
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    • 2008
  • 하이드레이트는 저온.고압에서 저분자량의 게스트(guest)가 호스트(host)인 물분자 속에 포획되어 만들어지는데 일련의 과정은 물리적 반응을 통해 생성된다.본 연구에서는$CO_2$보다 지구온난화지수(Global Warming Potential)가 23,900배 높은 $SF_6$의 회수 및 정제기술로써 하이드레이트화를 이용하는 신기술 개발의 일환으로 분광학적 접근을 통해 $SF_6$ 혼합 하이드레이트의 정성 및 정량분석을 수행하였다. Raman Shift 분석 결과 $SF_6$$770cm^{-1}$에서 $v_1$ 진동주파수를 확인함으로써 하이드레이트 내 $SF_6$가 안정적으로 포집됨을 확인하였고 혼합가스 내 $SF_6$ 농도별로 만들어진 샘플의 Raman Shift를 통해서 $SF_6$의 하이드레이트 전환율을 가늠할 수 있었다.

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