• 제목/요약/키워드: SEM and EDS

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STS 304L powder 상의 무전해 니켈 도금 (Electroless nickel plating on STS 304L powder)

  • 박소연;이종권
    • 한국산학기술학회:학술대회논문집
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    • 한국산학기술학회 2006년도 춘계학술발표논문집
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    • pp.184-187
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    • 2006
  • Nickel was plated electrolessly on 304L stainless steel powder. To obtain uniform coating and dispension of powder, the bath was continuously agitated with magnetic stirrer. The various pH and bath temperatures were studied. The conditions were in the range of $pH4{\sim}10$ and $45{\sim}65^{\circ}C$, respectively. The coating morphologies were examined by SEM/EDS tests. The optimum condition was pH9 at $55^{\circ}C$.

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Al-Si 코팅된 PWA1426과 PWA658 합금의 미세조직과 고온부식 특성 (Microstructure and Corrosion Characteristics of Al-Si Coated PWA1426 and PWA658 Alloy)

  • 이경구;안종천;서윤종
    • 한국표면공학회지
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    • 제33권1호
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    • pp.17-24
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    • 2000
  • The microstructures and corrosion properties of Al-Si diffusion coated PWA1426 and PWA658 alloys have been investigated. The coated layer and corrosion properties were analysed by SEM, EDS and hot corrosion test. According to the results of SEM, it is supposed that the coated layers were composed of mixed, denuded and inter-diffusion layer. The coated PWA1426 alloy improved corrosion properties, compared to the PWA658 alloy. Corrosion debris generated during hot corrosion test of PWA658 alloy are identified as NiO, $TiO_2$and $NiAl_2$$O_4$from coated layer which increase oxidation rate and decrease adhesion. The PWA1426 alloy heat treated at $1080^{\circ}C$ showed that NiAl and $Al_2$$O_3$formed on coated layer.

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황을 포함한 유기화합물인 NaDDTC의 CuNi합금에 대한 화학적 흡착에 관한 정량적 분석 (Quantitative Analysis on Chemisorption of NaDDTC as Organic Compound containing Sulfur for Cu-Ni Alloy)

  • 정길봉;김동영;장요한
    • 한국군사과학기술학회지
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    • 제18권5호
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    • pp.548-557
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    • 2015
  • This paper is results on Chemisorption of organic compound for the sea water fire fighting line of naval vessels. The quantitative analysis of Chemisorption has been investigated in seawater after immersion in 0.1 % of NaDDTC solutions for 43 hours. The morphology and topography were investigated by FE-SEM and AFM. The chemical elements were analyzed by SEM-EDS, XPS and the depth of chemical elements was measured by depth profiles. The effect of NaDDTC comes from Chemisorption between Copper and Sulfur of NaDDTC. As a result, test results showed that sulfur is helpful to protect a corrosion of seawater line.

화학약품용액(化學藥品溶液)에 침지(浸漬)한 콘크리트의 열화(劣化)에 대한 연구(研究) (A Study on the Erosion of Concrete Immersed in Chemical Solution)

  • 문한영;김성수
    • 대한토목학회논문집
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    • 제12권2호
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    • pp.55-66
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    • 1992
  • 인공해수 및 5종류의 약품용액에 시멘트풀, 모르터 및 콘크리트 공시체를 침지하여 강도 및 중량 변화를 측정하고 X-ray, SEM 및 EDS로서 반응생성물과 미세구조를 분석 고찰하였다. 연구결과 황산 및 황산염용액에서는 ${SO_4}^{2-}$ 이온의 침투로 인한 ettringite와 석고의 생성이 열화의 원인이 되었다. 염화물용액에서는 $Cl^-$ 이온의 침투가 콘크리트를 열화시키는 중요한 요인이 되었음을 알 수 있었다.

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Electrodeposition법으로 제조한 Ni-Fe 나노박막 및 나노선의 특성에 미치는 용액 조성의 영향 (Effect of Solution Compositions on Properties of Ni-Fe Nano Thin Film and Wire Made by Electrodeposition Method)

  • 구본급
    • 한국표면공학회지
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    • 제43권5호
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    • pp.243-247
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    • 2010
  • The micro Vickers hardness and internal stress of Ni-Fe metal thin film synthesized by electrodeposition method at $25^{\circ}C$ were studied as a function of bath composition, and surface microstructure and atomic compositions of thin films were investigated by SEM and EDS. And the shape change of $200\;{\AA}$ Ni-Fe nanowires made using anodic aluminum oxide(AAO) templates by electrodeposition method were observed by SEM as a function of ultrasonic treatment time and bath composition. The Fe deposition contents on the substrate non-linearly increased with Fe ion concentration over total metal ion concentration. In case of low Fe contents film, the grain size is smaller and denser than high Fe contents deposited films, and the micro Vickers hardness increased with Fe contents of electrodeposited films. These results affected the shape change of nanowire after ultrasonic treatments.

Deterioration of tensile behavior of concrete exposed to artificial acid rain environment

  • Fan, Y.F.;Hu, Z.Q.;Luan, H.Y.
    • Interaction and multiscale mechanics
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    • 제5권1호
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    • pp.41-56
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    • 2012
  • This study is focused on evaluation of the tensile properties of concrete exposed to acid rain environment. Acid rain environment was simulated by the mixture of sulfate and nitric acid in the laboratory. The dumbell-shaped concrete specimens were submerged in pure water and acid solution for accelerated conditioning. Weighing, tensile test, CT, SEM/EDS test and microanalysis were performed on the specimens. Tensile characteristics of the damaged concrete are obtained quantitatively. Evolution characteristics of the voids, micro cracks, chemical compounds, elemental distribution and contents in the concrete are examined. The deterioration mechanisms of concrete exposed to acid rain are well elucidated.

용융철에서 알루미늄 탈산 생성 개재물의 형상 (Morphology of the Inclusion as the Al Deoxidation Product of Molten Iron)

  • 이봉옥;이경구
    • 한국주조공학회지
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    • 제19권6호
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    • pp.466-471
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    • 1999
  • To investigate inclusions(oxides) which cause some trouble in the quality of the metal and a steel-making process, samples were manufactured. The molten irons were deoxidized using Al deoxidizer, and the morphology of the deoxidation products and the process of deoxidation were investigated by optical microscope, scanning electron microscope (SEM) and energy dispersive X-ray spectrometer(EDS). The reactions between Fe melt and Al deoxidizer formed deoxidation product, and those reaction may accelerates the reduction of oxide in Fe melt. According to the results of SEM analysis after deoxidizing treatment, it was found that deoxidation products had spherical cluster shape when 1% Al was added and dendritic shape with $2{\sim}3%$ A1 addition. The deoxidation products were globular, dendritic, polygonal(square) and cluster shape.

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Thermodynamic and Isothermal Studies of Congo RedAdsorption onto Modified Bentonite

  • Basava Rao., V. V.;Mohan Rao., T
    • Korean Chemical Engineering Research
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    • 제53권6호
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    • pp.770-775
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    • 2015
  • Adsorption of Congo Red (CR) from dye-containing effluents using modified bentonite (MB) has been investigated here. Isothermal studies were conducted to ascertain maximum adsorption capacity of the adsorbent. MB exhibited superior adsorption capacity compared to other low-cost adsorbents. Experimental data fitted the Langmuir isotherm better, indicating monolayer coverage of CR on MB. The feasibility of the process was measured in terms of separation factor $R_L$. The values of Gibbs free energy, entropy and enthalpy were calculated from the thermodynamics of the process. Adsorption was feasible and spontaneous, being endothermic. Analytical techniques including SEM, EDS, FTIR and XRD were applied to characterize MB and also to provide conclusive proof of the accumulation of CR on to MB.