• 제목/요약/키워드: SEM $T_g

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La 첨가량에 따른 $Bi_{4-x}La_{x}Ti_{3}O_{12}$ 강유전체의 주파수특성 (The Ferroelectric Frequency characteristics of $Bi_{4-x}La_{x}Ti_{3}O_{12}$ ceramics with the variation of Lanthanum additives)

  • 김응권;박복기;박기엽;박춘배
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.463-466
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    • 2001
  • In recent year, Ferroelectric $BLT(Bi_{4-x}La_{x}Ti_{3}O_{12})$ is a promising candidate materials. This study was practiced to make good conditions of BL T targets. In this study, calcination and sintering temperature were kept at $750^{\circ}C$, $1100^{\circ}C$ for 2 hour respectively. the density obtained 7.612, 7.98, $7.877g/cm^{3}$ as $La_{2}O_{3}$ contents were 0.0mol%, 0.25mol%, 0.5mol%. Especially, the lanthanum content of 0.5 mol% measured C-axis (117) preferred orientation more than the others targets in the XRD. In $\varepsilon_{r}-f$ relationship using by HP 4194 A impedance analyzer, the 0.5 mol% observed above 200 relative dielectric constant. but the dissipation factor was higher than others targets at 100Hz~13MHz range. SEM photograph with the content of $La_{2}O_{3}$ was observed like rod and plate types.

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대학생의 자기효능감과 대학생활만족도의 관계: 여가스포츠참여 수준의 조절효과 (The Relationship between Self-Efficacy and College Life Satisfaction: Moderating Effect of Leisure Sport Participation Level)

  • 한건수
    • 한국산학기술학회논문지
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    • 제16권4호
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    • pp.2478-2485
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    • 2015
  • 이 연구는 대학생의 자아효능감, 대학생활만족도 및 여가스포츠 참여만족도의 관계를 분석하는 것에 목적이 있다. 연구의 대상은 G시와 D시에 소재한 대학교 5곳에 재학 중이면서 여가스포츠에 참여중인 대학생들을 모집단으로 선정하여 비확률 표본추출법 중 편의표본추출법을 이용하여 총 350명을 표집 하였으며, 회수된 297부의 설문지 중 질문문항의 일괄적인 처리 혹은 무응답, 오기입 등 신뢰성이 떨어진다고 판단되어지는 38부의 설문지를 제외하고 총 259부를 분석에 사용하였다. SPSS 20.0 및 AMOS 20.0 통계 프로그램을 이용하여 분석한 결과는 다음과 같다. 첫째, 자아효능감과 대학생활만족도의 관계에서 여가스포츠 참여의 조절효과가 있는 것으로 나타났다. 둘째, 자아효능감은 대학생활만족에 유의한 정(+)의 영향을 미치는 것으로 나타났다.

Self-healing Anticorrosion Coatings for Gas Pipelines and Storage Tanks

  • Luckachan, G.E.;Mittal, V.
    • Corrosion Science and Technology
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    • 제15권5호
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    • pp.209-216
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    • 2016
  • In the present study, chitosan based self-healing anticorrosion coatings were prepared by layer by layer (lbl) addition of chitosan (Ch) and polyvinyl butyral (PVB) on mild carbon steel substrate. Chitosan coatings exhibited enhanced coating stability and corrosion resistance in aggressive environments by the application of a PVB top layer. Chitosan layer in the lbl coatings have been modified by using glutaraldehyde (Glu) and silica ($SiO_2$). Performance of different coatings was tested using electrochemical impedance spectroscopy and immersion test. The best anticorrosion performance was observed in case of 10 % Ch_$SiO_2$_PVB coatings, which withstand immersion test over 25 days in 0.5 M salt solution without visible corrosion. 10 % Ch_$SiO_2$ coatings without the PVB top layer didn't last more than 3days. Application of PVB top layer sealed the defects in the chitosan pre-layer and improved its hydrophobic nature as well. Raman spectra and SEM of steel surfaces after corrosion study and removal of PVB_Ch/Glu_PVB coatings showed a passive layer of iron oxide, attributing to the self-healing nature of these coatings. Conducting particle like graphene reinforcement of chitosan in the lbl coatings enhanced corrosion resistance of chitosan coatings.

$CH_4-H_2-O_2$계로부터 성장된 Diamond 박막의 Raman spectra (Raman spectra of Diamond thin film grown from $CH_4-H_2-O_2$ system)

  • 구효근;박승태;최종규;박상현;박재철
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1994년도 하계학술대회 논문집 C
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    • pp.1490-1492
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    • 1994
  • Diamond thin films were deposited on Si substrate from $CH_4-H_2-O_2$ system by MWPECVD at the condition of power of 800W, pressure of 80torr, $H_2$ flow rate of $75{\sim}81sccm$, $O_2$ flow rate of $0{\sim}3.8sccm$, $CH_4$ flow rate of $4.8{\sim}9sccm$, substrate temp, of $950{\sim}1010^{\circ}C$ and deposition time of 5hr. The deposited films were characterized by SEM, XRD and Raman spectroscopy. The growth rates of thin films and particles was measured. Good quality were synthesized at 40% of oxygen concentration which 6% of fixed metane concentration, and at 50%. Its deposition rates were $2.4{\mu}m/h$ respectively. As oxygen concentration increased, it was known that the broad peak of $1350 cm^{-1}$ was shifted to $1332cm^{-1}$ due to etching of carbon component.

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공정변수를 조절한 폴리에틸렌 산화왁스 합성에 관한 연구 (A Study on the Synthesis of Oxidized Polyethylene Wax by Controlling Reaction Parameters)

  • 양천회
    • 한국응용과학기술학회지
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    • 제20권2호
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    • pp.141-147
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    • 2003
  • Oxidized polyethylene wax is obtained by oxidation of polyethylene wax and it is composed of various chemicals, e.g., fatty acid, alcohol, ketone and ester. The application of oxidized polyethylene wax is determined by the composition of these chemical substances. In this basic study we observed the basic reaction parameters of time, temperature, oxygen concentration and catalysts on the oxidation reaction of low molecular weight polyethylene(PE wax) by analyzing the acid value, physical and chemical properties of oxidized PE wax to develop a new oxidation process. Acid values are increased with temperature increase in the rage of $150^{\circ}C^{\sim}180^{\circ}C$ but decreased beyond 190$^{\circ}C$. Acid values are also increased with oxygen concentration. As the oxidation reaction proceeds the molecular weight and softening points of oxidation products are decreased by cracking reaction, but the viscosities are increased. To observe the crystallinity of oxidation products SEM experiment was performed. To obtain a high acid-value product in a mild condition, we adopted free radical catalysts and the acid value of the product using catalyst was higher than the product obtained without catalyst in the same reaction condition. The effective initiators were dicumyl peroxide(DCPO), t-butylperoxy-2-ethyl hexanoate(HOPO) and benzoyl peroxide(BPO) having long half-life.

Assumed strain quadrilateral C0 laminated plate element based on third-order shear deformation theory

  • Shi, G.;Lam, K.Y.;Tay, T.E.;Reddy, J.N.
    • Structural Engineering and Mechanics
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    • 제8권6호
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    • pp.623-637
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    • 1999
  • This paper presents a four-noded quadrilateral $C^0$ strain plate element for the analysis of thick laminated composite plates. The element formulation is based on: 1) the third-order shear deformation theory; 2) assumed strain element formulation; and 3) interrelated edge displacements and rotations along element boundaries. Unlike the existing displacement-type composite plate elements based on the third-order theory, which rely on the $C^1$-continuity formulation, the present plate element is of $C^0$-continuity, and its element stiffness matrix is evaluated explicitly. Because of the third-order expansion of the in-plane displacements through the thickness, the resulting theory and hence elements do not need shear correction factors. The explicit element stiffness matrix makes the present element more computationally efficient than the composite plate elements using numerical integration for the analysis of thick layered composite plates.

Ambient Vibration measurements and finite element modelling for the Hong Kong Ting Kau Bridge

  • Au, F.T.K.;Tham, L.G.;Lee, P.K.K.;Su, C.;Han, D.J.;Yan, Q.S.;Wong, K.Y.
    • Structural Engineering and Mechanics
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    • 제15권1호
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    • pp.115-134
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    • 2003
  • The Ting Kau Bridge in Hong Kong is a cable-stayed bridge comprising two main spans and two side spans. The bridge deck is supported by three towers, an end pier and an abutment. Each of the three towers consists of a single reinforced concrete mast which reduces its section in steps, and it is strengthened by transverse cables and struts in the transverse vertical plane. The bridge deck is supported by four inclined planes of cables emanating from anchorages at the tower tops. In view of the threat from typhoons, the dynamic behaviour of long-span cable-supported bridges in the region is always an important consideration in their design. This paper is devoted to the ambient vibration measurements of the bridge for evaluation of dynamic characteristics including the natural frequencies and mode shapes. It also describes the modelling of the bridge. A few finite element models are developed and calibrated to match with the field data and the results of subsequent structural health monitoring of the bridge.

비도금 핫스탬핑용 보론강판의 분위기 산소량에 따른 산화층 분석 (Oxide Layer Analysis of Uncoated Boron Steel Sheet for Hot Stamping According to the Atmosphere Oxygen Content)

  • 이지호;최태훈;송정한;배기현
    • 소성∙가공
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    • 제32권3호
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    • pp.160-165
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    • 2023
  • As the supply of eco-friendly vehicles increases, the application rate of hot stamping components is rising to reduce vehicle weight and improve safety. Although Al-Si coated steel sheets are commonly used in hot stamping processes, their manufacturing costs are elevated due to process patents and royalties. Various hot stamping studies have been conducted to reduce these production costs. In this study, we derived a process control method for suppressing the oxide layer of hot stamping parts using uncoated boron steel sheets. Firstly, hat-shaped parts were hot stamped under atmospheric conditions to analyze the tendency of oxide layer formation by location. Then, the Gleeble system was used to observe oxide layer formation based on oxygen content under various atmospheric conditions. Finally, the oxide layer thickness was quantitatively measured using SEM images.

Experimental and numerical analyses of RC beams strengthened in compression with UHPFRC

  • Thomaz E.T. Buttignol;Eduardo C. Granato;Tulio N. Bittencourt;Luis A.G. Bitencourt Jr.
    • Structural Engineering and Mechanics
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    • 제85권4호
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    • pp.511-529
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    • 2023
  • This paper aims to better understand the bonding behavior in Reinforced Concrete beams strengthened with an Ultra-High Performance Fiber Reinforced Concrete (RCUHPFRC) layer on the compression side using experimental tests and numerical analyses. The UHPFRC mix design was obtained through an optimization procedure, and the characterization of the materials included compression and slant shear tests. Flexural tests were carried out in RC beams and RC-UHPFRC beams. The tests demonstrated a debonding of the UHPFRC layer. In addition, 3D finite element analyses were carried out in the Abaqus CAE program, in which the interface is modeled considering a zero-thickness cohesive-contact approach. The cohesive parameters are investigated, aiming to calibrate the numerical models, and a sensitivity analysis is performed to check the reliability of the assumed cohesive parameters and the mesh size. Finally, the experimental and numerical values are compared, showing a good approximation for both the RC beams and the RC strengthened beams.

Theoretical rotational stiffness of the flexible base connection based on parametric study via the whale optimization algorithm

  • Mahmoud T. Nawar;Ehab B. Matar;Hassan M. Maaly;Ahmed G. Alaaser;Osman Hamdy
    • Structural Engineering and Mechanics
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    • 제88권1호
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    • pp.43-52
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    • 2023
  • This paper handles the results of an extensive parametric study on the rotational stiffness of the flexible base connection using ABAQUS program. The results of the parametric study show the relation between the applied moment and the relative rotation for 96 different base connections. The configurations of the studied connections considered different numbers, diameters, and spacing of the anchor bolts along with different thicknesses of the base plate to investigate the effect of these parameters on the rotational stiffness behavior. The results of the previous parametric research used through the whale optimization algorithm (WOA) to detect different equation formulation of the moment-rotation (M-Ɵr) equation to detect optimum equation simulates the general nonlinear rotational behavior of the flexible base connection considering all variables used in the parametric study. WOA is a relatively new promising algorithm, which is used in different types of optimization problems. For more verification, the classical genetic algorithm (GA) is used to make a comparison with WOA results. The results show that WOA is capable of getting an optimum equation of the M-Ɵr relation, which can be used to simulate the actual rotational stiffness of the flexible base connections. The rotational stiffness at H/150 can be calculated using WOA (1) method and be used as a design aid for engineering design.