• 제목/요약/키워드: SEI film

검색결과 74건 처리시간 0.024초

광학재료로서 triazine기를 갖는 플라스틱 고분자에 대한 연구 (Study about Plastic Polymer bearing Triazine Group as Optical Material)

  • 이용희;김재종;서명교;이영세
    • 한국산업융합학회 논문집
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    • 제6권3호
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    • pp.171-176
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    • 2003
  • The poly(triazine bissulfide) synthesized from 6-dibutylamino-1,3,5-triazine-2,4-dithiol with bis(4-chloro-3-nitrophenyl) sulfone in the presence of the phase transfer catalyst, the maximum algebra viscosity (0.57 dL/g) is stable at reaction temperature of $60^{\circ}C$ overall. We could not acquire the good result about solubility, thermal property, and molecular weight to make cast film, we made base for the synthesis of functionalization polymer material.

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The effects of As addition on the transport property of a-Se:As films using the moving photo-carrier grating technique

  • Park, Chang-Hee;Lee, Kwang-Sei;Kim, Jeong-Bae;Kim, Jae-Hyung
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.252-253
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    • 2005
  • The effects of As addition in amorphous selenium (a-Se) films on the carrier mobilities and the recombination lifetime have been studied using the moving photo-carrier grating (MPG) measurements. The electron and hole mobility, and recombination lifetime of a-Se films with arsenic (As) additions up to 1% have been obtained. We have found an increase in hole drift mobility and recombination lifetime, especially when 0.3% As is added into a-Se film, whereas electron mobility decreases with As addition due to the defect density from shallow traps.

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The Moving Photocarrier Grating (MPG) Technique for the Transport Properties of α-Se:As Films

  • Park, Chang-Hee;Lee, Kwang-Sei;Kim, Jeong-Bae;Kim, Jae-Hyung
    • Transactions on Electrical and Electronic Materials
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    • 제6권6호
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    • pp.280-283
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    • 2005
  • The moving photocarrier grating (MPG) technique for the determination of the carrier mobilities and the recombination lifetime of $\alpha$-Se:As films has been studied. The electron and hole drift mobility and the recombination lifetime of $\alpha$-Se films with arsenic (As) additions have been obtained from measurement of the short circuit current density $j_{sc}$ as a function of grating velocity and spatial period. The hole mobility decreases due to defect density of hole traps when x exceeds 0.003, whereas the hole mobility increases for the case of low As addition (x$\le$0.003). We have found an increase in hole drift mobility and recombination lifetime, especially when As with (x = 0.003) is added into the $\alpha$-Se film.

Characterization of Negative Photoresist Processing by Statistical Design of Experiment (DOE)

  • Mun Sei-Young;Kim Gwang-Beom;Soh Dea-Wha;Hong Sang Jeen
    • Journal of information and communication convergence engineering
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    • 제3권4호
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    • pp.191-194
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    • 2005
  • SU-8 is a epoxy based photoresist designed for MEMS applications, where a thick, chemically and thermally stable image are desired. However SU-8 has proven to be very sensitive to variation in processing variables and hence difficult to use in the fabrication of useful structures. In this paper, negative SU-8 photoresist processed has been characterized in terms of delamination, based on a full factorial designed experiment. Employing the design of experiment (DOE), a process parameter is established, and analyzing of full factorial design is generated to investigate degree of delamination associated with three process parameters: post exposure bake (PEB) temperature, PEB time, and exposure energy. These results identify acceptable ranges of the three process variables to avoid delamination of SU-8 film, which in turn might lead to potential defects in MEMS device fabrication.

Thermal Stability of Lithiated Silicon Anodes with Electrolyte

  • Park, Yoon-Soo;Lee, Sung-Man
    • Bulletin of the Korean Chemical Society
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    • 제32권1호
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    • pp.145-148
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    • 2011
  • The thermal behavior of lithiated Si anodes has been investigated using differential scanning calorimetry (DSC). In particular, the effect of Si particle size on the thermal stability of a fully lithiated Si electrode was investigated. For DSC measurements, a lithiated Si anode was heated in a hermetically sealed high-pressure pan with a polyvinylidene fluoride (PVDF) binder and a 1 M $LiPF_6$ solution in an ethylene carbonate (EC)-diethyl carbonate (DEC) mixture. The thermal evolution around $140^{\circ}C$ increases with lithiation and with decreasing particle size; this phenomenon is attributed to the thermal decomposition of the solid electrolyte interface (SEI) film. Exothermic peaks, following a broad peak at around $140^{\circ}C$, shift to a lower temperature with a decrease in particle size, indicating that the thermal stability of the lithiated Si electrode strongly depends on the Si particle size.

Study of Effect of Adsorbate-Adsorbent Interaction in Multilylayer Physical Adsorption of Gases on Solids

  • Park, Sung-Ju;Lee, Jo W.;Pak, Hyung-Suk;Chang, Sei-Hun
    • Bulletin of the Korean Chemical Society
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    • 제2권2호
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    • pp.56-59
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    • 1981
  • In this paper a further generalization of the theory of multilayer physical adsorption previously developed by the authors is attempted so that the effect of vertical interactions between adsorbent and adsorbate can be explicitly taken into account. In this attempt we have to discard the previously adopted assumption that the molecules in the second layer or above are all in the same physical state. In order to estimate the effect of vertical interactions on the adsorption isotherm the interaction energy between an adsorbed molecule and the adsorbent surface is assumd to vary as $r^{-3}$ where r is the distance that the molecule under consideration is separated from the adsorbent surface. Resulting adsorption isotherm is applied to interpret the adsorption data of tetramethylsilane vapor on iron film and good agreements between observed and calculated values are obtained over wide range of pressure.

Study of Effect of Lateral Intermolecular Interaction on Multilayer Physical Adsorption of Gas

  • Han, Sang-Hwa;Lee, Jo W.;Pak, Hyung-Suk;Chang, Sei-Hun
    • Bulletin of the Korean Chemical Society
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    • 제1권4호
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    • pp.117-121
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    • 1980
  • The effect of lateral intermolecular interactions among the adsorbate molecules has been incorporated into the theory of multilayer physical adsorption developed previously by the present authors within the frame of Bragg-Williams approximation and the resulting adsorption isotherm has been used to interpret the adsorption data of tetramethylsilane vapor on clean iron film which we failed to account for in our previous works. The result has shown that up to the point where the relative pressure is about 0.7 considerable improvement is obtained but beyond this point there still remains large difference between theoretical and experimental isotherm. Such difference is supposed to arise from the neglect of effect of vertical interaction between the adsorbate molecules and the adsorbent surface.

EVA 에멀젼의 내수성 및 기계적 특성에 미치는 금속 이온 가교제의 효과 (Effect of Metal Ionic Crosslinking Agents on the Water Resistance and Mechancial Properties of EVA Emulsion)

  • 이은경;최세영
    • 접착 및 계면
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    • 제9권2호
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    • pp.24-31
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    • 2008
  • 본 연구에서는 EVA 에멀젼에 내수성 및 기계적 특성을 향상시키기 위하여 금속 이온 가교제인 calcium hydroxide 및 magnesium carbonate를 사용하여 이온성 가교결합을 도입하였다. EVA 에멀젼 필름의 가교밀도, 열적특성, 표면자유에너지 그리고 인장강도, 파단신율 및 인열강도 특성을 고찰하였다. 금속 이온 가교제 양이 증가함에 따라 EVA 에멀젼의 가교밀도는 증가하였고, 이에 내수성과 $T_g$ 값도 증가하였다. 그러나 EVA 에멀젼 필름의 표면에너지 및 기계적 특성들은 다소 다른 거동을 보였다. Calcium hydroxide 0.4% 그리고 magnesium carbonate 0.5%를 첨가한 경우가 EVA 에멀젼에 강한 이온성 가교결합이 형성되어 가장 높은 표면 자유에너지 값과 인장강도 및 인열강도를 보였다. 그러므로 본 연구에서 calcium hydroxide 및 magnesium carbonate와 같은 금속 이온 가교제가 EVA 에멀젼의 내수성과 기계적 물성을 향상시킴을 확인하였다.

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스핀 스프레이 방식으로 제조된 바륨계 페라이트 박막의 EMI (Electromagnetic Interference) 차폐 특성 (EMI (Electromagnetic Interference) Shielding Properties of Barium-Based Ferrite Thin Films Prepared by Spin Spray Method)

  • 오혜령;박연주;이우성;유찬세;유명재;서인태
    • 한국전기전자재료학회논문지
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    • 제37권2호
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    • pp.195-201
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    • 2024
  • The low-temperature deposition of BaNi(2-x)CoxFe16O27 thin films with a Ba hexaferrite structure for electromagnetic shielding was studied. The BaNi(2-x)CoxFe16O27 thin films produced through the spin spray process were suitable for thin film deposition on a flexible substrate because it crystallized well at low temperature below 90℃. The change in shielding characteristics depending on the Co content of the BaNi(2-x)CoxFe16O27 thin film was investigated, and excellent shielding characteristics with S21 of -1 dB were obtained in a wide frequency range of 26~40 GHz when the Co content was 0.4 or more. The purpose of this study is to analyze changes in shielding properties caused by change in Co content in relation to phase changes in BaNi(2-x)CoxFe16O27 and obtain basic data for developing excellent flexible electromagnetic wave shielding materials.

피복재료가 강활의 추대 및 생육에 미치는 영향 (Effect of Mulching Materials on Bolting and Growth in Angelica koreana Max.)

  • 이상석;최효심;손형락;허봉구;오세명;김수용
    • 한국자원식물학회지
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    • 제20권4호
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    • pp.331-335
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    • 2007
  • 본 시험은 최근에 경북 북부지역을 중심으로 면적이 증가하고 있는 강활재배에서 노두로 번식되고 있는 북강활을 중심으로 피복재료에 따른 추대반응과 생육특성을 분석하여 재배기술 체계를 확립코자 수행한 결과를 요약하면 다음과 같다. 1. 토양 피복재료별 오전 10시의 지온은 무피복구에 비해 흑색P.E피복구와 투명P.E피복구가 각각 0.5, $2.9^{\circ}C$ 높았고, 오후 2시의 지온은 각각 0.8, $4.8^{\circ}C$ 높았으며, 볏짚피복구는 무피복구에 비해 지온이 낮았다. 2. 추대율은 무피복구 및 볏짚피복구에 비해 투명P.E피복구와 흑색P.E피복구구는 각각 11.4, 13.6%로 유의하게 높았고, 개화기는 투명P.E피복구와 무피복구에서 빨랐으며, 화경장과 화경수는 피복재료에 따른 차이가 없었다. 3. 근생엽장은 흑색P.E피복구가 가장 길었고 다음이 투명P.E피복구이며, 엽수 및 노두수는 흑색P.E피복구에서 가장 많았다. 지하부의 건근수량은 흑색P.E피복구에서 가장 높았고 다음이 투명P.E피복구이며 벗짚피복구과 무피복구가 가장 낮았다. 토양 피복재료별 잡초발생은 무피복구와 투명P.E피복구에서 많았고, 흑색P.E피복구에서 가장 적었다. 강활재배에 있어서 흑색P.E피복이 추대율을 다소 증가시키는 반면 잡초방제와 수량 증대에 가장 효과가 있는 것으로 나타났다.