• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2002년도 춘계학술대회논문집
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• pp.187-191
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• 2002

The exhaust gas from electric power stations, incinerators and industrial boilers contains considerable amount of harmful nitric oxide which causes air pollution. Selective catalytic reduction system with ammonia as a reductant(NH$_{3}$ SCR) have been applied to remove NOx since 1970. it is widely accepted that the NH$_{3}$ SCR process is the best method for the removal of NOx. In this paper the design of SCR reactor based on the NOx displacement is considered and the design program of SCR reactor is developed. The newly developed design program for de-NOx system maybe used in practice.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2011년도 전기공동학술대회 논문집
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• pp.26-26
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• 2011

• Journal of Advanced Marine Engineering and Technology
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• 제37권5호
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• pp.500-509
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• 2013

SCR 머플러 입구와 촉매사이에 설치되는 다공튜브 형상변화에 따른 촉매 삽입형 urea-SCR 머플러 내부유동특성이 해석적으로 조사되었다. 다공튜브는 요소수 분무와 배기가스 혼합물의 공간분포 향상을 통한 $NO_x$ 저감율 증대 및 암모니아 슬립을 방지하기 위해 사용되는 장치이다. 다공튜브 오리피스 면적비 변화가 챔버 내부 유동 및 촉매 전후단의 속도분포에 끼치는 영향이 조사되었으며, 속도분포에 대한 균일도 지수가 최적설계 관점에서 평가되었다. 해석은 상용 유동해석 프로그램을 이용하여 정상상태에서 수행되었으며 요소수 분무와 배기가스 혼합물 대신 상온의 공기가 작동유체로 사용되었다. 해석결과로부터 다공튜브 형상은 머플러 입구와 촉매 전단 사이에 형성된 챔버 내 벌크 선회유동과 촉매 전후단 속도분포의 균일도지수에 큰 영향을 끼침을 알 수 있었다.

• 설비공학논문집
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• 제28권8호
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• pp.337-342
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• 2016

A marine SCR System is emerging as an alternative to comply with NOx Tier III Emission standards, a restriction on greenhouse gas from vessels implemented by the International Maritime Organization. The system is greatly affected by the uniformity of the fluid flowing into the catalyst, so the performance of the catalyst of an SCR system needs to be guaranteed. This study conducted research on a mixed evaporator of an SCR system, which is one of the factors affecting the uniformity of the fluid. When the angle of the mixed evaporator is set to $90^{\circ}$, the fluid uniformity is at its highest at 83%, under the condition that the length of the mixed evaporator be 3.5 D. When the length was 3.5 D and less, the fluid uniformity had a tendency to improve relative to the case without a bent pipe. However, a longer mixed evaporator results in a more perfect liquidity development in the pipe with a liquidity distribution similar to the case where no curved pipe is formed in front of the catalyst. A lower angle for the mixed evaporator results in a lower flow uniformity, and a longer length of the mixed evaporator results in a lower difference in the flow uniformity caused by the angle. The flow uniformity can be improved by 6% with a mixed evaporator, which confirmed that all factors applied to an SCR system have a close relationship with the efficiency.

• 한국자동차공학회논문집
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• 제19권2호
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• pp.50-56
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• 2011

To meet the NOx limit without a penalty of fuel consumption, Urea-SCR system is currently regarded as promising NOx reduction technology for diesel engines. SCR system has to achieve maximal NOx conversion in combination with minimal $NH_3$ slip. In this study, map based open loop control for urea injection was developed and assessed in the European Transient Cycle (ETC) for heavy duty diesel engine. The basic urea quantity set-value which was calculated using the look up tables of engine out NOx, exhaust flow rate and optimum NSR resulted in NOx reduction of 80% and the average $NH_3$ slip of 24 ppm and maximum of 79 ppm. In order to reduce $NH_3$ slip, $NH_3$ storage control algorithm was applied to correct the basic urea quantity and reduced $NH_3$ slip levels to the average 15 ppm and maximum 49 ppm while keeping NOx reduction of 76%. With high and increasing SCR temperature, the $NH_3$ storage capacity decreases, which leads to $NH_3$ slip. The resulting $NH_3$ slip peak can be avoided by stopping or significantly reducing the urea injection during the SCR temperature gradient is over $30^{\circ}C/min$.

• 한국자동차공학회논문집
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• 제17권2호
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• pp.180-186
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• 2009

To meet the NOx limit without a penalty of fuel consumption, urea SCR system is currently regarded as promising NOx reduction technology for diesel engines. SCR system has to achieve maximal NOx conversion in combination with minimal $NH_3$ slip. In this study, as a basic research to develop an algorithm for urea injection control, the characteristics of engine out NOx emission and behavior of NOx reduction during steady-state and transient conditions were investigated using 2L DI diesel engine. Test results show that on increasing the catalyst temperature the variations in the outlet NOx concentration are faster and maximal allowable $NH_3$ storage exponentially decreases. For change from a low to high engine load, it can be seen that a few seconds after load-step is required to reach full NOx conversion and the adsorbed amount of $NH_3$ at lower temperature desorb during the next temperature increase, causing $NH_3$ slip. Engine out NOx emission needs to be corrected because NOx emissions just after step load is lower than that of steay state condition.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2005년도 전기학술대회논문집
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• pp.521-527
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• 2005

The effects of an urae injection at the exhaust pipe for a 4-cylinder DI(Direct Injection) diesel engine are investigated experimentally. The urea quantity was controlled by NOx quantity and MAF(Manifold Air Flow). The urea injection must be precisely metered and then I used the urea syringe pump. I have tested 4 kinds of items that were with the EGR base engine and without the EGR engine. Then I tested each urea-SCR(Selective Catalytic Reduction) system. As the results, I can caculate the SUF(Stoichiometric Urea Flow) and visualize the NOx results by variation of engine speed and engine load. Also, I can make the NOx map. Therfore, I knew that NOx reduction effects of the urea-SCR system without the EGR engine were better than the with EGR base engine except of low load and low speed.

• 한국인터넷방송통신학회논문지
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• 제15권3호
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• pp.219-224
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• 2015

현재 에너지 절감에 대한 사회적 요구가 높다. 이번 기회에 IGBT 딤머시스템이 기존 SSR,SCR 딤머시스템과 비교하여 얼마만큼의 효율성을 갖는 것에 대한 목적을 가지고 연구를 하였다. 방법은 2가지로 첫째는 디머시스템의 조광시 출력에 따른 정현파 변형의 비교실험으로 전력손실이 얼마나 나타나는지에 대하여 오슬로스코프로 비교 측정 실험을 진행하였고, 둘째는 조광시 장비가 갖는 소리에 대한 데시벨 크기를 측정하여 장비 배치에 대한 소음에 대하여 데시벨 측정기로 실험을 진행하였다. 결과는 전력손실에 따른 효율성과 공간에 따른 소음이 많은 SSR, SCR 딤머보다 IGBT 딤머가 효율적이라는 것을 확인 하였다.

• 한국산학기술학회논문지
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• 제19권1호
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• pp.18-24
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• 2018

친환경자동차의 보급 확대를 위한 정책수립과 기술개발이 지속적으로 이루어지고 있는 실정이나 아직까지도 내연기관이 차지하는 비중은 약 95% 차지하고 있다. 화석연료를 기반으로 하는 내연기관의 엄격한 배기가스규제를 충족시키기 위해 자동차와 선박용 후처리장치의 비중이 점차로 증가하고 있다. 천연가스는 대기환경 오염물질을 거의 배출하지 않는 청정연료이며, 주로 시내버스의 연료로 사용되어져 왔다. CNG 버스의 보급률이 계속적으로 증가하고 있으며 이에 대한 엄격한 배기규제를 충족시키고 경제적인 후처리장치의 연구개발이 필요하다. 장기적인 연구로는, CNG 버스에서 배출되는 유독성가스인 $CH_4$와 NOx를 동시저감시키는 새로운 NGOC/LNT+NGOC/SCR 복합시스템을 개발하는 것이다. 이 연구는 복합시스템 후단에 장착되는 선택적인촉매환원(SCR)의 washcoat를 세라믹과 메탈 담체에 코팅하여 $de-CH_4/NOx$ 특성을 파악하는 것이다. V, Cu-SCR 촉매는 $CH_4$ 산화반응에는 영향을 미치지 않고, 이중층으로 코팅된 2, 4번 NGOC/SCR 촉매는 $400^{\circ}C$에서 $CH_4$가 산화되기 시작하여 약 $550^{\circ}C$에서는 약 20% 수준으로 $CH_4$가 저감되었다. NGOC/SCR처럼 two layer로 코팅된 2, 4번 SCR 촉매는 $350^{\circ}C$이상에서는 마이너스(-) NOx 전환률을 나타냈다. 이는 $ NH_4NO_3$(질산염)으로 흡장되어 있는 NOx가 촉매의 반응속도가 저하됨에 따라 $N_2$로 환원되지 못하고 $NO+NO_2$로 탈착되었기 때문이다. 세라믹 기반의 복합시스템은 $400^{\circ}C$에서 약 30%, $500^{\circ}C$에서 LOT50에 이르러 메탈 기반의 복합시스템보다 약 20% CH4 정화 성능이 높았고, NGOC/LNT+Cu-SCR 복합시스템 조합이 적합하다.

• 한국자동차공학회논문집
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• 제14권1호
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• pp.68-78
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• 2006

In the past few years, considerable efforts have been directed towards the further development of Urea-SCR(selective catalytic reduction) technique for diesel-driven vehicle. Although urea possesses considerable advantages over Ammonia$(NH_3)$ in terms of toxicity and handling, its necessary decomposition into Ammonia and carbon dioxide complicates the DeNOx process. Moreover, a mobile SCR system has only a short distance between engine exhaust and the catalyst entrance. Hence, this leads to not enough residence times of urea, and therefore evaporation and thermolysis cannot be completed at the catalyst entrance. This may cause high secondary emissions of Ammonia and isocyanic acid from the reducing agent and also leads to the fact that a considerable section of the catalyst may be misused for the purely thermal steps of water evaporation and thermolysis of urea. Hence the key factor to implementation of SCR technology on automobile is fast thermolysis, good mixing of Ammonia and gas, and reducing Ammonia slip. In this context, this study performs three-dimensional numerical simulation of urea injection of heavy-duty diesel engine under various injection pressure, injector locations and number of injector hole. This study employs Eulerian-Lagrangian approach to consider break-up, evaporation and heat and mass-transfer between droplet and exhaust gas with considering thermolysis and the turbulence dispersion effect of droplet. The SCR-monolith brick has been treated as porous medium. The effect of location and number of hole of urea injector on the uniformity of Ammonia concentration distribution and the amount of water at the entrance of SCR-monolith has been examined in detail under various injection pressures. The present results show useful guidelines for the optimum design of urea injector for reducing Ammonia slip and improving DeNOx performance.