• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1997년도 춘계학술대회 논문집
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• pp.30-34
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• 1997

This paper Describe a modelling method for SCR(selective Catalytic reduction) system in refuse incineration plant. We consider the SCR system as a single input single output system. For modelling the SCR system, an auto regressive exogeneous(ARX) modelling method is used. In this case, we should design the white noise input for modelling and put it on the system as an input (.NH/sap2/.), and taken an outlet NOx as an output. From these two relations, we design the ARX model with 45 second delay time and transform to discrete system with 0.5 sampling time. Using the obtained SCR model, we simulate the SCR system to reduce the outlet NOx content by a conventional PID control method.

• 한국산학기술학회논문지
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• 제9권3호
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• pp.611-614
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• 2008

Urea=SCR 시스템은 질소산화물을 감소하기 위한 효과적인 후처리장치 중의 하나로 알려져 있다. SCR 시스템의 성능을 향상시키기 위해서 우레아 분사시스템을 위한 최적의 기하학적인 조건이 형성되어야한다. 본 연구는 대형 디젤기관에서 우레아를 사용한 SCR시스템의 분무 특성을 가시화 하고자 했다. 실험은 우레아 압력과 우레아 유량 그리고 공기압력과 공기량을 변화시킴으로써 이루어졌다. 가시화는 초고속 카메라를 이용하여 촬영하였다.

• 한국정밀공학회지
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• 제25권11호
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• pp.83-89
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• 2008

The Effect of Space Velocity(SV) on NOx conversion rate was performed to develop NOx reduction after-treatment system. SV is calculated from engine exhaust gas volume and SCR catalyst volume. Found the Urea injection duty of maximum efficiency for NOx conversion if increase SV, NOx Conversion rate is down. Especially, when SV is more than $110,000h^{-1}$, NOx conversion rate decrease suddenly. Same case, if SV is lower than $40,000h^{-1}$, NOx conversion rate is down. Also, the characterization of Urea-SCR system was performed. Three candidate injectors for injecting Urea were tested in terms of 속 injection rate and NOx reduction rate. The performances of SCR catalytic converter on temperature were investigated. The performance of Urea-SCR system was estimated in the NEDC test cycle with and without EGR. It was found that nozzle type injector had high NOx conversion rate. SCR catalytic converter had the highest efficiency at the temperature of $350^{\circ}C$. EGR+Urea-SCR system achieved NOx reduction efficiency of 73% through the NEDC test cycle.

• 전력전자학회논문지
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• 제7권1호
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• pp.41-47
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• 2002

본 논문에서는 대체에너지 발전 시스템을 위한 새로운 자연전류형 SCR 인버터를 제안한다. 제안한 인버터 시스템은 6-펄스 SCR 인버터와 보조회로로 구성된다. 보조회로의 동작으로 인버터 시스템의 펄스 수가 증가하여 출력 전압 및 출력전류의 고조파가 현저히 저감된다. 제안한 방식의 24-펄스 동작을 위한 분석, 제어 및 시물레이션이 제시되고 실험을 통하여 제안한 이론을 입증한다.

• 동력기계공학회지
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• 제19권6호
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• pp.68-74
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• 2015

NOx emission has been controlled because it is a major cause of the acid rain and effects considerably on formation and destruction of ozone. A SCR system on diesel engine is necessary to clear TierIII, because IMO(International Maritime Organization) plans on tightening regulations to TierIII at $1^{st}$ January 2016. In this study, flow analysis was accomplished with ANSYS Fluent program so that the SCR system would be retrofitted in training ship KAYA and the temperature distributions of exhaust gas in SCR sytem were investigated after it was installed. As a result, it was confirmed that pressure and velocity distributions in SCR system were depended on pipe line shapes, then it was designed as the pressure was lower. The temperature differential between 1 and 3 point was $15^{\circ}C$ because of evaporative latent heat of urea and the temperature of 4 point after catalyst was increased by $5^{\circ}C$ than 3 point because of exothermic reaction.

• 공업화학
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• 제22권6호
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• pp.658-663
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• 2011

SNCR-SCR hybrid system은 SNCR에서 NOx를 제거한 뒤, SCR로 NOx를 추가 제거하는 시스템으로 NOx 제거 효율을 향상시키는 경제적인 시스템이다. 본 연구에서는 SNCR-SCR hybrid system에서 운전 변수가 질소산화물 저감 효율에 미치는 영향을 고찰하였다. SNCR을 optimum temperature ($900{\sim}950^{\circ}C$)보다 낮은 온도에서 운전할 경우, 추가적인 암모니아 주입 없이도 $NH_3$ slip을 이용한 NO의 추가적인 제거의 효과가 있었으나 $NH_3$ slip이 높은 것으로 나타났다. 그러나 그 이상의 온도에서는 고온에 의한 암모니아의 분해로 SCR에 의한 추가 제거의 효과를 얻지 못했다. 따라서 SNCR 공정을 optimum temperature에서 운전하는 것이 NO 제거 효율과 $NH_3$ slip 농도를 고찰하였을 때 가장 적절하였으며, $SR_{RES}$가 적정 수준으로 유지되도록 NSR을 조절하는 것이 중요한 운전 변수인 것으로 나타났다.

• 동력기계공학회지
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• 제18권3호
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• pp.14-19
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• 2014

The purpose of the study is to investigate the effect of additive catalyst according to the thermal aging of vanadia SCR catalysts. At a fresh condition, the $3V_2O_5-5WO_5-92TiO_2$ SCR showed the highest NOx conversion rate of about 30%, the performance of 5 kinds of SCR to which additive catalysts were added was not improved due to the insignificant effect of acid site control. For catalysts aged for 12h at $700^{\circ}C$, the SCR to which 3wt% Zeolite was added decreased in NOx conversion rate by 2.5% on average compared to the fresh SCR, it showed higher thermal durability than other additive catalyst. For 3Zeolite with high performance of NOx conversion rate during thermal aging, the Zeolite with stronger durability at a high temperature than other 5 kinds of SCR catalysts decreased the sintering of catalysts.

• 한국자동차공학회논문집
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• 제22권1호
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• pp.135-141
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• 2014

$NH_3$-SCR has high NOx removal efficiency approximately 80~90%. Recently, the copper or iron ion-exchanged zeolite catalysts are widely used as automobile SCR catalysts. In this paper, the effect of the space velocity, temperature of reaction and $NO_2$ addition on the $NH_3$-SCR reaction were studied using various zeolite SCR catalysts. The test was conducted with small sized fresh catalysts in a laboratory fixed-bed flow reactor system using simulated gases. It is found that the activity of the BEA is better than MFI. It seems that three-dimensional framework and a wide pore entrance of BEA enhances the SCR activity. It is also found that low temperature activity of Cu-zeolites was better than Fe-zeolites. Once $NO_2$ was added, the NOx conversion activity of the Cu-zeolite was slightly enhanced, whereas remarkable improvement was achieved by Fe-zeolite.

• 한국항해항만학회지
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• 제40권4호
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• pp.173-181
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• 2016

2016년부터 배출통제지역(ECA : Emission Control Atea)을 운항하는 선박에 대하여 배출되는 NOx(질소산화물) 및 SOx(황산화물)의 배기량 감소규제가 강화되었다. 상기의 규제 물질 중 NOx를 제거하는 탈질장비 중 선택적 촉매 환원(SCR : Selectivity Catalytic Reduction) 시스템은 효율이 높고 상업적으로 많이 활용되고 있으나, 높은 온도에서 요소수가 활성화되는 단점이 있다. 이에 초미세기포를 이용하여 낮은 온도에서도 반응할 수 있는 요소수 및 요소수 활성화 기기를 개발하여 상기의 문제점들을 최소화 할 수 있도록 하였다. 또한 SCR 시스템의 효율성을 향상시키는 방안을 마련하기 위하여, ANSYS-CFX package를 이용한 전산유체역학(CFD : Computational fluid dynamics)기법을 사용하였다. Navier-Stokes 방정식을 해석의 지배방정식으로 적용하여 SCR 시스템의 점성유동해석 시뮬레이션을 수행하였다. SCR 시스템의 형상은 CATIA V5를 사용하여 3D 모델링을 하였고, SCR 시스템의 효율성을 비교하기 위해 요소수 분사 노즐의 위치를 요소수 분사 노즐은 배기관의 입구로부터 1/3, 1/2, 2/3로 변경하며 확인하였다. 또한, 노즐의 분사구 수가 SCR 시스템의 효율에 미치는 영향을 확인하기 위하여 분사구 수가 4, 6, 8개일 경우를 시뮬레이션 하여 비교 분석하였다. 시뮬레이션 결과 배기관 입구에 가까울수록, 분사구 수가 많을수록 효율이 향상됨을 확인하였다.

• 한국자동차공학회논문집
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• 제20권1호
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• pp.95-105
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• 2012

The selective catalytic reduction (SCR) system is a highly-effective aftertreatment device for NOx reduction of diesel engines. Generally, the ammonia ($NH_3$) was generated from reaction mechanism of SCR in the SCR system using the liquid urea as the reluctant. Therefore, the precise urea dosing control is a very important key for NOx and $NH_3$ slip reduction in the SCR system. This paper investigated NOx and $NH_3$ emission characteristics of urea-SCR dosing system based on model-based control algorithm in order to reduce NOx. In the map-based control algorithm, target amount of urea solution was determined by mass flow rate of exhaust gas obtained from engine rpm, torque and $O_2$ for feed-back control NOx concentration should be measured by NOx sensor. Moreover, this algorithm can not estimate $NH_3$ absorbed on the catalyst. Hence, the urea injection can be too rich or too lean. In this study, the model-based control algorithm was developed and evaluated on the numerical model describing physical and chemical phenomena in SCR system. One channel thermo-fluid model coupled with finely tuned chemical reaction model was applied to this control algorithm. The vehicle test was carried out by using map-based and model-based control algorithms in the NEDC mode in order to evaluate the performance of the model based control algorithm.