• Title/Summary/Keyword: SCR 2005

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A study of hydrocarbon SCR(selective catalytic reduction) on Ag/γ-Al2O3 catalyst (Ag/γ-Al2O3 촉매상에서 탄화수소-SCR(Selective Catalytic Reduction) 연구)

  • Kim, Moon-Chan;Lee, Cheal-Gyu
    • Analytical Science and Technology
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    • v.18 no.2
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    • pp.139-146
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    • 2005
  • Removal of NO contained in automobile exhaust gas was accomplished by the non-selective catalyst reduction method. The catalysts were prepared through loading of a specific amount of Ag into ${\gamma}-Al_2O_3$. The conversion of $NO_x$ was studied by varying the temperatures, $O_2$ concentrations and $SO_2$ concentrations for the prepared catalysts. The influence of the structure of catalyst to $NO_x$ conversion was followed through the analysis of the physical properties of the prepared catalysts. Experiments were conducted on each of the catalysts by varying the reaction conditions to find an optimum condition. The catalyst $Ag/{\gamma}-Al_2O_3$ shows a highest $NO_x$ conversion when the Ag content was 2 wt% and a reaction temperature of about $450^{\circ}C$. and after conducting the experiments, samples of before and after experiments analyzed using XRD, XPS, TPR, and UV-Vis DRS experiments. The result indicated that when Ag oxide content could not be maintained well at high temperatures $NO_x$ conversion decreased.

Distribution of Cyanotoxin Microcystin-LR in Han River System and Ecological Park in Seoul and Kyunggi Districts (서울 경기지역의 공원 연못 및 한강 수계내 조류독소 Microcystin-LR의 분포)

  • Suh, Mi-Yeon;Kim, Baik-Ho;Han, Myung-Soo
    • Korean Journal of Ecology and Environment
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    • v.38 no.2 s.112
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    • pp.237-248
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    • 2005
  • To determine the content of hazard microcystin (MC) in Han River system and Ecological Ponds in Seoul City and Kyunggi district, a most toxic derivative, microcystin-LR (MCLR) of 15 samples of 7 ponds, 4 rivers and 4 reservoirs during low precipitation and cold season in 2003 were analyzed by ELISA method. With the change of water temperature ($0.4\;{\sim}\;21.9^{\circ}C$), cyanobacteria including Microcystis aeruginosa dominated the cold phytoplankton community in small ecological ponds such as Kyungbokgung Kyunghyaeru (KBP), Seokchon reservoir (SCR), Yangsoori Ryukgakji (YSS), having the long residence time. Contents of MCLR (the detection limit; $0.05\;{\mu}g\;L^{-1}$) were high in cyanobacteria-rich sites, especially, Microcystis aeruginosa. Total MCLR, cell extracted type plus dissolved type, were $1.39\;{\mu}g\;L^{-1}$ in KBP, $0.55\;{\mu}g\;L^{-1}$ in SCR and $0.59\;{\mu}g\;L^{-1}$ in YSS, in the first sampling having a high temperature (>$20^{\circ}C$), while some detected only in YSS during the cold season. As expected, the MCLR content was correlated with Microcystis aeruginosa (r = 0.526 for cell extracted type, r = 0.433 for dissolved type). Therefore, low concentration of MCLR detected in small ponds and Han river system in Seoul metropolitan city and Kyunggi district, maybe hardly affect human recreation activity, especially the drinking water supply.

Study on Psychological Distress in Women with Breast Cancer by Using SCL-90-R and QSCC II (간이정신진단검사(SCR-90-R)와 사상체질분류 검사지(QSCC II)를 이용한 유방암 환자에서의 부적응 증상 연구)

  • Kwon, Mo-Ran;Kwon, Ku-Yean;Gam, Chul-Woo;Yoo, Ho-Ryong;Bang, Sun-Hwi;Yoo, Hwa-Seung;Cho, Jung-Hyo
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.21 no.5
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    • pp.1313-1318
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    • 2007
  • The objective of this study was to examine the psychological distress in women with breast cancer. Subjects were 25 women with breast cancer and 25 healthy women, who were recruited from January 2005 to September 2006 at Dunsan oriental hospital of Daejeon university. Psychological distress were assessed using SCL-90-R(Symptom-Check-List-90-Revised), and diagnosis of sasang constitution was done by QSCCII (Ousestionnare for Sasang Constitution Classification II). Psychological distress were significantly showed in breast cancer patients compared with healthy women. They are associated with unmarried or divorced women, lower level of education, and longer time lapse after diagnosis. Especially, phobic anxiety was significantly higher in Soeumin than Taeumin and Soyangin. These results lead us to the conclusion that it is necessary to psychological stabilization by various method in care program of breast cancer.

A Study on NOx Removal Efficiency using SNCR Process in the Industrial Waste Incineration Plant (산업폐기물 소각로에서 SNCR공정에 의한 NOx 제거효율에 관한 연구)

  • Ryu Hae-Yeol;Kim Min-Choul;Jung Jong-Hyeon;Lee Gang-Woo;Chung Jin-Do
    • Journal of Environmental Health Sciences
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    • v.31 no.4 s.85
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    • pp.332-339
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    • 2005
  • The environmental regulations in the world has been reinforced and many nations has devoted themselves to the development of cost-effective technology. Selective catalyst reduction(SCR) and selective non-catalyst reduction (SNCR) processes are mainly used to treat nitrogen oxidants generated from fossil-fuel combustion. One of these typical technologies for reduction of do-NOx is SNCR process has increased continuously because of the low cost for building and maintenance. Nevertheless the researches on the application to real scale plant by the reductant like Urea are rarely studied. In this paper, an experimental investigations were performed on the SNCR process in the industrial waste incineration plant. With no reducing agent, the concentration of NOx stayed in around 180 ppm $(O_2\;12\%)$ with the exhausting temperature of $950^{\circ}C$ and changed within the range of 20 ppm to remain relatively consistent. When $10\;wt\%)$ of a solution was added, the efficiency of denitrification reached above $61.4\%$ with the NSR of 2.0 and the exhausting temperature of $950^{\circ}C.$ When the concentration of the urea solution was set to $10\;wt\%$ and the sprinkling to four nozzles, the reaction temperature was reduced to about $50~100^{\circ}C$ with a mixture of $10\;wt\%\;CH_3OH\;and\;5wt\%\;Na_2CO_3$ in $40\;wt\%$ of the solution. The NOx removal efficiency increased to $78.4\%,$ achieving a broader and expansive range of reaction temperatures than the addition of an unmixed pure solution.

DeNOx by Hydrocarbon-Selective Catalytic Reduction on Ag-V/γ-Al2O3 Catalyst (Ag-V/γ-Al2O3 촉매상에서 탄화수소-Selective Catalytic Reduction에 의한 질소산화물 저감)

  • Kim, Moon-Chan;Lee, Cheal-Gyu
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.328-336
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    • 2005
  • In order to remove the NO contained in exhaust gas by the non-selective catalyst reduction method, the catalysts were prepared by varing the loading amount of Ag and V into ${\gamma}-Al_2O_3$. The conversion of $NO_x$ using the prepared catalysts was studied by varying the temperatures, $O_2$ concentrations and $SO_2$ concentrations using. The influence of the catalyst structure on $NO_x$ conversion was studied through the analysis of the physical properties of the prepared catalysts. In the case of $AgV/{\gamma}-Al_2O_3$ catalyst, the $NO_x$ conversion was lower than that of $Ag/{\gamma}-Al_2O_3$ at higher temperatures but higher than that of $Ag/{\gamma}-Al_2O_3$ at lower temperatures. Even though $SO_2$ was contained in the reaction gas, the $NO_x$ conversion did not decrease. Based on the analysis including XRD, XPS, TPR, and UV-Vis DRS before and after the experiments, the experimental results were examined. The results indicated that, $NO_x$ conversion decreased at higher temperatures since Ag oxide could not be maintained well due to the addition of V, whereas it increased at temperatures lower than $300^{\circ}C$ due to the catalytic action of V.

Evaluation of the Optimum Dietary Protein to Energy Ratio of Juvenile Japanese eel, Anguilla japonica (뱀장어 치어의 사료내 에너지에 대한 적정 단백질 비 평가)

  • Han, Kyung-Min;Bae, Jun-Young;Eme Okorie okorie;Go Su-Hong;Yoo Jin-Hyung;Bai SungChul-C.
    • Journal of Aquaculture
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    • v.18 no.3
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    • pp.135-141
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    • 2005
  • A 16-week feeding trial was conducted to estimate the optimum dietary protein to energy ratio (P/E ratio, mg/kcal) in juvenile Japanese eel, Anguilla japonica. Six experimental diets were formulated with three energy levels and two protein levels at each energy level. Three energy levels of 3800, 4150 and 4500 kcal per kg diets were included at 45 and 50% crude protein (CP) levels, respectively $(_{120}P_{45},\;_{110}P_{45},\;_{100}P_{45},\;_{130}P_{50},\;_{120}P_{50},\;and\;_{110}P_{50})$. After four weeks of the conditioning period, fish initially averaging $15.0{\pm}3g\;(means{\pm}SD)$ were randomly distributed into each tank as groups of 20 fish. Each diet was fed to fish in three randomly selected tanks at a rate of $2{\sim}3%$ wet body weight per day in the recirculated system. Weight gain (WG) and specific growth rate of fish fed diet $_{100}P_{45}$ were significantly higher (P<0.05) than those of fish fed the other diets. WG of fish fed diet $_{120}P_{50}$ was also significantly higher than those of fish fed diets $_{130}P_{50}$ and $_{110}P_{50}$. Feed efficiency ratio of fish fed diets $_{100}P_{45}$ and $_{110}P_{45}$ were significantly higher (P<0.05) than those of fish fed other diets. These results suggest that the optimum P/E ratio may be 100 mg/kcal with 45% protein diets, and 120 mg/Kcal 50% protein diets for the maximum growth of juvenile Japanese eel under the experimental condition.