• Korean Chemical Engineering Research
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• 제47권6호
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• pp.700-704
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• 2009

GTL(gas-to-liquid) 합성유 제조용 SCR(steam carbon dioxide reforming) 공정의 시뮬레이션 연구를 수행하였다. 온도 및 $CH_4/steam/CO_2$ 반응물 비와 같은 변수를 바꾸어 가면서 SCR 공정을 위한 최적 운전조건을 살펴보았다. 공정 시뮬레이션을 위해 Aspen Plus를 사용하였다. 또한 정상상태 가정하의 열역학적 물성치 계산을 위해 Aspen Plus의 RSK (Redlich-Kwong-Soave) 상태방정식을 사용하였다. FT 공정을 위한$H_2/CO$ 비, $CH_4$ 전환율, $CO_2$ 전환율을 살펴봄으로써 최적의 온도와 최적의 반응물 비를 결정하였다. 시뮬레이션 결과, SCR reformer 촉매층 출구 최적온도는 상압에서 $850^{\circ}C$ 였으며, 이 온도에서 $CH_4$ 전환율은 99%, $CO_2$ 전환율은 49%로 계산되었고, $CH_4/steam/CO_2$ 최적 반응물 비율은 1.0/1.6/0.7로 나타났다.

• 한국태양에너지학회 논문집
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• 제29권1호
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• pp.44-49
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• 2009

Steam reforming of methane in the high temperature solar chemical reactor bas advantage in its heating method. Using concentrated solar energy as a heating source of the reforming reaction can reduce the $CO_2$ emission by 20% compared to hydrocarbon fuel. In this paper, the simulation result of methane-steam reforming on a high temperature solar chemical reactor(SCR) using Fluent 6.3.26 is presented. The high temperature SCR is designed for the Inha Dish-1, a Dish type solar concentrator installed in Songdo city. Basic SCR performance factors are referred to the former researches of the same laboratory. Inside the SCR porous metal is used for a receiver/reactor. The porous metal is carved like a dome shape on the incident side to increase the heat transfer. Also, ring-disc set of baffle is inserted in the porous metal region to increase the path length. Numerical and physical models are also used from the former researches. Methane and steam is mixed with the same mole fraction and injected into the SCR. The simulation is performed for a various inlet mass flow rate of the methane-steam mixture gas. The result shows that the average reactor temperature and the conversion rate change appreciably by the inlet mass flow rate of 0.0005 kg/s.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.143-143
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• 2010

GTL(Gas-to-Liquids)공정 중 합성가스 제조공정(Reforming Process)인 ATR(Auto-Thermal Reforming), SCR(Steam Carbon Reforming), POx(Partial Oxidation)의 시뮬레이션 연구를 수행하였다. Reforming 공정에서 생산된 합성가스는 GTL 합성유 제조공정인 FT(Fischer-Thropsch) 반응기로 주입되며, 합성유 생산에 최적의 효율을 보이는 H2/CO 비(합성가스에 포함된 반응물비)는 2.0으로 알려져 있다. FT공정은 합성가스를 원료로 고온 및 고압 반응을 거쳐 GTL 공정의 최종 생산품인 FT합성유를 제조하는 공정이다. 본 연구에서는 FT공정 효율 극대화를 위해 reforming 공정에서 생성되는 합성가스 내 H2/CO의 비를 2로 수렴토록 모사조건을 설정하였으며, 상기 조건을 만족하는 reforming 공정들의 운전 온도 및 feed 조성을 분석하고 비교하고자 한다. 현재 GTL 플랜트관련 산업계에 적용 혹은 주 연구대상인 reforming 공정으로는 ATR, SCR, POx 공정이 있다. ATR 공정은 $850{\sim}1100^{\circ}C$에서 메탄, 스팀 및 산소를 원료로 활용하여 H2 및 CO를 생산하는 공정으로 발열/흡열 반응이 상존하여 에너지 비용이 낮지만 공정구조 상 열회수설비 및 ASU(Air Separation Unit)이 필요하기에 CAPEX(초기설비 설치비용)가 높은 편이다. SCR공정은 CH4, Steam 및 CO2를 연료로 하기에 이산화탄소가 일정부분 포함된 가스전에도 적용이 가능하나 공정 운전 중 지속적으로 외부에서 열을 공급해야 하기에 에너지 투입비용이 높은편이며, 탄소침적의 문제가 있어 대용량 플랜트에는 적합하지 않다. POx공정은 약 $1,500^{\circ}C$의 고온에서 CH4가 O2에 의해 부분 산화되는 방식으로 촉매가 필요없어 설비비가 타 공정에 비해 저렴하나 생산가스의 H2/CO비가 다소 낮아 전체적인 GTL 공정효율이 저하되는 단점이 있다. 상기 세 공정은 GTL 산업계에서 실증 및 효율증대를 위해 주로 연구되는 공정이기에 본 연구의 분석대상으로 설정하였다. 본 연구에서는 상용공정모사기인 Aspen Plus를 활용하여 reforming 공정별로 FT합성공정의 최적 조건(H2/CO=2)을 만족하는 합성가스 생산조건 분석 및 비교를 수행할 예정이다. 운전조건인 공정 운전온도 및 feed 가스조성 등을 모사하기 위해 합성가스 reforming 공정을 모델링하고 공급유량 및 압력 등의 운전변수는 GTL국책과제 1단계 연구수행 결과를 토대로 선정하고자 한다. GTL공정의 경우, 설비의 운전조건이나 연료가스의 구성 및 유량에 따라 적합한 reforming 공정이 다르기에 본 시뮬레이션 결과를 향후 GTL 플랜트 공정모델 설계시 reforming 공정선정에 참고자료로 활용하고자 한다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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• pp.888-888
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• 2009

A simulation study on SCR (Steam Carbon dioxide Reforming) process in gas-to-liquid (natural gas to Fischer-Tropsch synthetic fuel) process was carried out in order to find optimum reaction conditions for GTL (gas-to-liquid) process reaction. Optimum SCR operating conditions for synthesis gas to FT (Fischer-Tropsch) process were determined by changing reaction variables such as feed temperature and pressure. During the simulation, overall synthesis process was assumed to proceed under steady-state conditions. It was also assumed that physical properties of reaction medium were governed by RKS (Redlich-Kwong-Soave) equation. SCR process was considered as reaction models for synthesis gas in GTL proess. The effect of temperature and pressure on SCR process $H_2$/CO ratio and the effect of reaction pressure on SCR reaction were mainly examined. Simulation results were also compared to experimental results to confirm the reliability of simulation model. Simulation results were reasonably well matched with experimental results.

• 한국수소및신에너지학회논문집
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• 제25권2호
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• pp.105-113
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• 2014

Performance tests on $Ni/Ce-ZrO_2/Al_2O_3$ catalysts with additives (MgO, $La_2O_3$) were investigated in the combined reforming processes (SCR, ATR, TRM) in order to produce hydrogen and carbon monoxide (it is called "syngas".). The catalyst characterization was conducted using the BET surface analyzer, X-ray diffraction (XRD), SEM, TPR and TGA. The combined reforming process was developed to adjust the syngas ratio depending on the synthetic fuel (methanol, DME and GTL) manufacturing processes. Ni-based catalysts supported on alumina has been generally recommended as a combined reforming reaction catalyst. It was found that both free NiO and complexed NiO species were responsible for the catalytic activity in the combined reforming of methane conversion, and the $Ce-ZrO_2$ binary support employed had improved the oxygen storage capacity and thermal stability. The additives, MgO and $La_2O_3$, also seemed to play an important role to prevent the formation of the carbon deposition over the catalysts. The experimental results were compared with the equilibrium data using a commercial simulation tool (PRO/II).

• 한국연소학회지
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• 제12권3호
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• pp.1-7
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• 2007

A combined hydrogen generator of plasma and catalytic reformer was developed, and was applied to stabilize unstable flame of 200,000 Kcal/hr LPG combustor. The role of the plasma reformer was to generate hydrogen in a short period and to heat-up the catalytic reformer during the start-up time. After the start-up period, the catalytic reformer generates hydrogen through steam reforming with oxygen (SRO) reactions. The maximum capacity of the hydrogen generator was enough 100 lpm to stabilize the flame of the present combustor. In order to reduce NOx and CO emissions simultaneously, 1) FGR (Flue Gas Recirculation) technique has been adopted and 2) the hydrogen was added into the fuel supplied to the combustor. Test results showed that the addition of 25% hydrogen and 30% FGR rate lead to simultaneous decrease of CO and NOx emissions. The technique developed in the present study showed good potential to replace $NH_3$ SCR technique, especially in the small-scale combustor applications.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2007년도 제34회 KOSCO SYMPOSIUM 논문집
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• pp.187-190
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• 2007

A combined hydrogen generator of plasma and catalytic reformers has been developed, and has been applied to stabilize unstable flame of 200,000 Kcal/hr LPG combustor. The role of the plasma reformer is to generate hydrogen in a short period and to heat-up the catalytic reformer during the start-up time. After the start-up period, the catalytic reformer generates hydrogen through steam reforming with oxygen (SRO) reactions. The maximum capacity of the hydrogen generator is 100 lpm that is sufficient to be used to stabilize the flame of the present combustor. In order to reduce NOx and CO emissions simultaneously, 1) FGR (Flue Gas Recirculation) technique has been adopted and 2) the hydrogen has been added into the fuel supplied to the combustor. Test results shows that 25 % addition of hydrogen and 30 % FGR rate lead to simultaneous decrease of CO and NOx emissions. The technique proposed in the present study shows good potential to replace $NH_3$ SCR technique, especially in the case of small-scale combustor applications.