• Title/Summary/Keyword: S4

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The Monohydrogen Arsenate-sensing Electrodes (Monohydrogen Arsenate 감응 전극)

  • Gwon-Shik Ihn;Il-Bae Park
    • Journal of the Korean Chemical Society
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    • v.31 no.2
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    • pp.162-167
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    • 1987
  • Four component $Ag_2S$-PbS-$PbHAsO_4-Cu_2S$ and three component $Ag_2S$-PbS-$PbHAsO_4$ electrodes have been prepared and evaluated for the direct measurement of monohydrogen arsenate. The 3.0 : 0.5 : 1.0 : 0.25 (mole ratio, $Ag_2S$:PbS:$PbHAsO_4:Cu_2S$) composition is superior in terms of potentiometric response, stability, rapidity of response and reproducibility. Testing was done over the concentration range $10^{-1}$~$10^{-4}M\;HA_SO_4^{2-}$in 0.1F NH4Ac-NH4OH buffer solution at pH 8.50 with constant ionic strength. Interfering ions were $CN^-,\;I^-,\;S^{-2}$ and $Cl^-$.

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Effect of Microstructures and Sintering Additives on the Mechanical Properties of Si$_3$N$_4$ (질화규소의 기계적 특성에 미치는 미세구조 및 소결조제의 영향)

  • Park, Hye-Ryeon;Lee, O-Sang;Park, Hui-Dong;Lee, Jae-Do
    • Korean Journal of Materials Research
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    • v.2 no.5
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    • pp.330-336
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    • 1992
  • Four distinctive hot pressed and heat treated S${i_3}{N_4}$ceramics, S${i_3}{N_4}$-8%${Y_2}{O_3}$, S${i_3}{N_4}$-6% ${Y_2}{O_3}$-2% $A{l_2}{O_3}$, S${i_3}{N_4}$-4% ${Y_2}{O_3}$-3% $A{l_2}{O_3}$, 그리고 S${i_3}{N_4}$-1% MgO-1% Si$O_2$(in wt%), were prepared and characterized by X-ray diffraction, scanning electron microscopy, image analysis and mechanical tests. The fracture toughness of S${i_3}{N_4}$-8% ${Y_2}{O_3}$specimens containing large elongated grains showed the highest value of about 9.8MPa$m^{1/2}$. Two out of four S${i_3}{N_4}$, ceramics(S${i_3}{N_4}$-6% ${Y_2}{O_3}$-2% $A{l_2}{O_3}$and S${i_3}{N_4}$-4% ${Y_2}{O_3}$-3% $A{l_2}{O_3}$) heat treated at 200 $0^{\circ}C$retained the fracture strength of over 900MPa and fracture toughness of over 8.0MPa$m^{1/2}$. Large ${\beta}$-S${i_3}{N_4}$grains having a diameter larger than 1${\mu}$m appeared to contribute to increase in fracture toughness.

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4S-Van Design for Application Environment

  • Lee, Seung-Yong;Kim, Seong-Baek;Lee, Jong-Hun
    • Proceedings of the KSRS Conference
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    • 2002.10a
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    • pp.106-110
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    • 2002
  • 4S-Van is being developed in order to provide the spatial data rapidly and accurately. 4S-Van technique is a system for spatial data construction that is heart of 4S technique. Architecture of 4S-Van system consists of hardware integration part and post-processing part. Hardware part has GPS, INS, color CCD, camera, B/W CCD camera, infrared rays camera, and laser. Software part has GPS/INS integration algorithm, coordinate conversion, lens correction, camera orientation correction, and three dimension position production. In this paper, we suggest that adequate 4S-Van design is needed according to application environment from various test results.

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A Survey study on Functional Technologies for Spatial Information System (공간정보체계(4S)를 위한 기술요소와 기능에 대한 조사연구)

  • Jin, Heui-Chae
    • Journal of Korea Spatial Information System Society
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    • v.3 no.1 s.5
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    • pp.17-26
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    • 2001
  • The purpose of this study is to measure of importancy on functional technologies of 4S. This study is significant to both developer and users, since there is little research pertaining functional technologies for 4S. In this paper, we classify functional technologies for 4S with due regard to standards of ISO. Then we analysis the frequency of importance each technologies in the view of developer and users. This research can improve the usability of 4S' products with stable and reliable.

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Design of Disaster Control System with 4S Kernel Component in a Mobile Environment (Mobile 환경에서 4S 핵심 컴포넌트를 이용한 재난재해 시스템 설계)

  • Joo, In-Hak;Oh, Byoung-Woo;Kim, Min-Soo
    • Proceedings of the Korea Information Processing Society Conference
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    • 2001.10a
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    • pp.61-64
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    • 2001
  • 최근 공간정보를 다루는 GIS, SIIS, GNSS, ITS 네 개의 시스템에 대한 통합연계 기술인 4S 기술이 각광받고 있다. 본 논문에서는 컴포넌트 기반의 4S 시스템을 소개하고 4S 기술을 화재, 홍수, 태풍 등의 재난재해 분야에 적용한 시스템을 4S 핵심 컴포넌트를 중심으로 설계하였다. 4S 기술을 이동 환경에서 적용하는 예는 매우 많으나 재난재해 업무에 적용될 경우 매우 큰 효과를 가져올 것이다. 공간데이터를 처리하는 핵심 기술과 재난재해 업무간 공통된 기능은 4S 핵심 컴포넌트로 구현되며, 업무별로 다른 기능은 별도의 업무 컴포넌트로 분리하여 분야별 응용시스템에 따라 사용하게 하였다. 특히 4S-Van 이라는 차량 및 이동단말기 등 현장과 중앙관제센터간에 실시간으로 위치정보와 영상정보 등을 전송하는 방법 및 전송된 정보를 중앙관제센터에서 공간 데이타와 연동.분석하는 방안을 제시하여 신속하고 정확한 상황파악, 의사결정, 지령관제 등을 가능하게 하고 재난재해 분야에 획기적인 업무효율 향상을 가져올 것으로 기대된다.

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A Highly Stereoselective Reaction in Aminolysis of 3-Acyl-4-(S)-isopropyl-1,3-thiazolidine-2-thione with Racemic Amines (3-Acyl-4(S)-isopropyl-1,3-Thiazolidine-2-Thione과 라세미아민의 입체선택적인 반응)

  • Tae Myoung Jeong;Ki Hun Park
    • Journal of the Korean Chemical Society
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    • v.32 no.6
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    • pp.588-592
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    • 1988
  • A chiral recognition was observed in aminolysis of 3-acyl-4(S)-isopropyl-1,3-thiazolidine-2-thione by racemic amine to give an optically active amide (S-excess) and amine (R-excess). This procedure can be applied to synthesis of macrocyclic diamide macrocyclic spermidine alkaloid, and peptide. The rate of this aminolysis is remarkably affected by steric surrounding; completion of reaction can be easily judged by the disappearance of the original yellow color of 4(S)-AITT. These features of the aminolysis suggested a potential recognition racemic amines by a chiral 4 (S)-AITT derivative. Thus 4 (S)-AITT was synthesized from 4 (S)-isopropyl-1, 3-thiazolidine-2-thione and carboxylic acids.

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Photoluminescent Properties of EuGa2S4 and Eu2Ga2S5 Phosphors (EuGa2S4와 Eu2Ga2S5 형광체의 발광 특성)

  • Young-Sik Cho;Min-Kyeong Jang;Young-Duk Huh
    • Journal of the Korean Chemical Society
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    • v.67 no.4
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    • pp.236-240
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    • 2023
  • Non-concentration quenching EuGa2S4 and Eu2Ga2S5 phosphors, in which the concentration of Eu2+ activator ion is 100%, were synthesized by a solid state reaction at temperature range from 800 to 1050 ℃. The wavelength of maximum intensity (λmax) of EuGa2S4 and Eu2Ga2S5 phosphors are 546 and 581 nm, respectively. An examination of the X-ray diffraction patterns and photoluminescent properties of EuGa2S4 and Eu2Ga2S5 phosphors revealed that EuGa2S4 and Eu2Ga2S5 phosphors were formed at lower temperature range (800~900 ℃) and higher temperature range (1000~1050 ℃), respectively.

Optical Properties of Cdlnsub 2Ssub 4 and Cdlnsub 2Ssub 4 : $CdIn_2S_4$$CdIn_2S_4 : Co^{2+}$Single Crystals ($CdIn_2S_4$$CdIn_2S_4 : Co^{2+}$ 단결정의 광학적 특성)

  • Choe, Seong-Hyu;Bang, Tae-Hwan;Kim, Hyeong-Gon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.5
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    • pp.296-302
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    • 1999
  • $CdIn_2S_4 and CdIn_2S_4 : Co^{2+}$ singlecrystals of thenormal spinel structure were grown by the C.T.R. method. The optical energy band structure of these compounds had a indirect band gap at the fundamental optical absorption band edge. The direct and the indirect energy gaps are found to be 2.325 and2.179eV for $Cdln_2S_4$ , and 2.303 and 2.169eV for $CdIn_2S_4 and CdIn_2S_4 : Co^{2+}$ at 5K, respectivly. The fundamental absorption band edge of these single crystals shift to a shorter wavelength region with decreasing temperature, and the temperature dependence of the optical energy gaps in these compounds satisfy Varshni equation. The Varshni constants$\alpha and \beta$ of the direct energy gap are given by $13.39{\times}10_{-4}eV/K$ and 509 K for $Cdln_2S_4$ and $29.73{\times}10_{-4} eV/K$ and 1398K for $CdIn_2S_4 and CdIn_2S_4 : Co^{2+}$. The Varshni constants ${\alpha}and {\beta}$ of the indirect energy gap are given by 9.68${\times}10^{-4}$ eV/K 308K for $Cdln_2S_4$ and $13.33{\times}10_{-4}eV/K$ and 440K for $CdIn_2S_4 : Co^{2+}$ respectivly. The impurity optical absorption peaks due to cobalt dopant are observed in $CdIn_2S_4 : Co^{2+}$ single crystal. These impurity optical absorption peaks can be attributed to the electronic transitions between the split energy levels of $Co_{2+}$ ions located at $T_d$ symmetry site of $Cdln_2S_4$ host lattece.

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Synthesis and luminescence properties of $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ phosphors ($Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ 형광체의 합성과 발광 특성)

  • Sung, Hye-Jin;Huh, Young-Duk
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.6
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    • pp.267-272
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    • 2006
  • A series of $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ phosphors have been synthesized by solid-state reaction. The photoluminescence and structural properties of $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ have been examined. The $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ phosphors have a strong absorption at 400 nm, which is the emission wavelength of a violet light emitting diode (LED). The emission peaks of $SrGa_2S_4:Ce,Na$are located at 448 nm and 485 nm. The partial replacement of Sr by Ca in $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ causes a red shift of emission wavelengths. The $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ can be used as blue emitting phosphors pumped by the violet LED for fabricating the multi-band white LED.

MORITA EQUIVALENCE FOR HOMOGENEOUS C*-ALGEBRAS OVER LOWER DIMENSIONAL SPHERES

  • Park, Chun-Gil
    • Journal of the Chungcheong Mathematical Society
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    • v.19 no.2
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    • pp.111-121
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    • 2006
  • All d-homogeneous $C^*$-algebras $T^d$ over $\prod^{s_4}S^4{\times}\prod^{s_2}S^2{\times}\prod^{s_3}S^3{\times}\prod^{s_1}S^1$ are constructed. It is shown that $T^d$ are strongly Morita equivalent to $C(\prod^{s_4}S^4{\times}\prod^{s_2}S^2{\times}\prod^{s_3}S^3{\times}\prod^{s_1}S^1)$.

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