• Title/Summary/Keyword: S-MMA

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Preparation of IPN-type Polyelectrolyte Films Attached to the Electrode Surface and Their Humidity-Sensitive Properties (전극 표면에 부착된 IPN 형태의 전해질 고분자의 제조 및 그들의 감습특성)

  • Han, Dae-Sang;Gong, Myoung-Seon
    • Polymer(Korea)
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    • v.34 no.6
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    • pp.565-573
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    • 2010
  • Copoly(2-(dimethylamino)ethyl methacrylate)(DAEMA)/butyl acrylate (BA) and copoly(methyl methacrylate)(MMA)/BA/2-(cinnamoyloxy)ethyl methacryate (CEMA), which were cross-linked with dibromoalkane and UV irradiation, respectively, were prepared for the precursors of interpenetrating polymer network (IPN) humidity-sensitive films. 3-(Triethoxysilyl)propyl cinnamate (TESPC) was used as a surface-pretreating agent for the attachment of IPN-polyelectrolyte to the electrode surface by UV irradiation. Humidity sensitive polymeric thin films with an IPN structure were prepared by crosslinking reactions of copoly(DAEMA/BA) with 1,4-dibromobutane (DBB) and copoly(MMA/BA/CEMA) by UV-irradiation. The anchoring of an IPN-polyelectrolyte into the substrate was carried out via the photochemical $[2{\pi}+2{\pi}]$ cycloaddition. The resulting humidity sensors showed a high sensitivity in the range of 20~95%RH and a small hysteresis (<1.5%RH). The response time for adsorption and desorption process at 33~94%RH was 48 and 65 s, respectively, indicating a fast response. The effects of the concentration of copolymers, molar ratio of crosslinking agents and time of the precursor solution for dip-coating on their humidity sensitive properties including water durability were investigated.

Convergence of Korean Traditional Dance and K-Pop Dance : An Analysis of Comments on 2018 MMA BTS 'IDOL' Videos on YouTube (한국 전통춤과 K-pop 댄스의 융합 : 2018 MMA 방탄소년단 'IDOL' 유튜브 댓글 분석)

  • Yoo, Ji-Young;Kim, Mi-Kyung
    • Journal of Korea Entertainment Industry Association
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    • v.13 no.8
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    • pp.189-198
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    • 2019
  • This study aims to make meaning of the reactions of the Korean people through the text mining of comments on videos of the December 2018 MMA performance of intro on YouTube. For this, comments on 15 YouTube videos were collected over the past 10 months. With the collected data, a total of 5,135 comments were analyzed through crawling using the Python and BeautifulSoup programs, data was refined over a total of 3 sessions, and a final total of 5,080 comments were used as analysis material. A mining technique was used for data analysis and the process of refinement, analysis, and visualization was achieved using the Textom program. Research results showed that keyword analysis showed the keywords of 'performance', 'Korea', 'video', 'top', 'cool', 'dance', 'idol', 'legend', 'love', and 'gratitude' in that order and keywords such as 'patriotism' and 'Olympics' also appeared frequently. N-gram analysis showed that comments with contexts such as 'a top performance that will remain a legend among Korean idol performances', and 'an idol performance that displayed the traditional culture of Korea' were in higher ranks. Based on such keyword analysis results, topic modeling was applied and 5 top keywords were extracted from a total of 5 topics. Analysis results of topic contents and distribution showed that topics in the comments of this performance's videos largely consisted of the 3 reactions of 'high praise regarding the stage performance', 'affection towards the fusion and artistic sublimation of Korean traditional dance', and 'gratitude towards the uploading of cool dance videos'

Preparation of Acryl Binder with Silane Type Chain Transfer Agent (실란계 사슬 이동제를 사용한 아크릴 바인더의 제조)

  • Kim, Jin-Gon;Shin, Min-Jae;Shin, Jae-Sup
    • Polymer(Korea)
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    • v.36 no.3
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    • pp.351-356
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    • 2012
  • Acryl binder is a representative organic additive for the manufacture of the display electronic equipment. Acryl binder is usually synthesized by radical copolymerization. Glycidyl methacrylate (GMA), methyl methacrylate (MMA), and methacrylic acid (MAA) were used in this copolymerization of acryl binder. In this study the silane type mercaptane compound was used as a chain transfer agent (CTA) to enhance the adhesion property of the acrylic binder. The CTA used in this experiment was (3-mercaptopropyl) trimethoxysilane (MPTMS). Molecular weight of the copolymer, thickness of the coating, transmittance, and adhesion property were measured. The molecular weight was controlled and the adhesion property was improved by using this silane type chain transfer agent.

Why most patients do not exhibit obstructive sleep apnea after mandibular setback surgery?

  • Kim, Jin-Wook;Kwon, Tae-Geon
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.42
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    • pp.7.1-7.8
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    • 2020
  • Maxillomandibular advancement (MMA) is effective for the treatment of obstructive sleep apnea (OSA). In previous studies, the airway was increased in the anteroposterior and transverse dimensions after MMA. However, the effect of the opposite of mandibular movement (mandibular setback) on the airway is still controversial. Mandibular setback surgery has been suggested to be one of the risk factors in the development of sleep apnea. Previous studies have found that mandibular setback surgery could reduce the total airway volume and posterior airway space significantly in both the one-jaw and two-jaw surgery groups. However, a direct cause-and-effect relationship between the mandibular setback and development of sleep apnea has not been clearly established. Moreover, there are only a few reported cases of postoperative OSA development after mandibular setback surgery. These findings may be attributed to a fundamental difference in demographic variables such as age, sex, and body mass index (BMI) between patients with mandibular prognathism and patients with OSA. Another possibility is that the site of obstruction or pattern of obstruction may be different between the awake and sleep status in patients with OSA and mandibular prognathism. In a case-controlled study, information including the BMI and other presurgical conditions potentially related to OSA should be considered when evaluating the airway. In conclusion, the preoperative evaluation and management of co-morbid conditions would be essential for the prevention of OSA after mandibular setback surgery despite its low incidence.

Synthesis and Biological Activities of Myomodulin E and its Analogs (Myomodulin E 및 유도체들의 합성 및 생리활성)

  • Go, Hye-Jin;Seo, Jung-Kil;Seo, Hae-Jeom;Lee, Min-Jeong;Park, Tae-Hyun;Kim, Gun-Do;Park, Nam-Gyu
    • Journal of Life Science
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    • v.22 no.4
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    • pp.499-507
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    • 2012
  • Previous work has characterized myomodulin A (MMA, PMSMLRLamide) and myomodulin E (MME, GLQMLRLamide) purified from the central nervous systems of the sea hare, $Aplysia$ $Kurodai$, using the anterior byssus retractor muscle (ABRM) of the mussel, $Mytilus$ $edulis$. The amino acid sequences of MMA and MME were the same as those of the myomodulin family peptide found in other mollusks. In this study, we synthesized MME, its derivatives, and other neuropeptides to investigate the relationship between the structure and biological activity of MME. The primary structures of MME's derivatives, Des[$Gly^1$]-MME, Des[$Gly^1,Leu^2$]-MME, and Des[$Gly^1,Leu^2,Gln^3$]-MME, were LQMLRLamide, QMLRLamide, and MLRLamide, respectively. MMA and synthetic peptides were tested on ABRM in $M.$ $edulis$ as well as muscle preparations in $Achatina$ $fulica$. MME displayed an inhibitory effect on phasic contraction of the ABRM at $1{\times}10^{-9}$ M or higher. MME also had a relaxing effect on the catch-tension of AMRM at $1{\times}10^{-8}$ M. Both MMA and its analogs stimulated a contractile response on the crop and relaxed the catch-relaxing response on the penial retractor muscle of $A.$ $fulica$. These results suggest that MME and its analogs have modulatory effects on various muscles of mollusks. This study has also laid the groundwork for future neural and circuit modulation studies during animal behavioral changes.

Study on the fabrication and the characterization of 100 nm T-gate InGaAs/InAlAs/GaAs Metamorphic HEMTs (100 nm T-gate의 InGaAs/InAlAs/GaAs metamorphic HEMT 소자 제작 및 특성에 관한 연구)

  • Kim, H.S.;Shin, D.H.;Kim, S.K.;Kim, H.B.;Im, Hyun-Sik;Kim, H.J.
    • Journal of the Korean Vacuum Society
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    • v.15 no.6
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    • pp.637-641
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    • 2006
  • We present the DC and RF characteristics of 100 nm gate length InGaAs/InAlAs/GaAs metamorphic high electron mobility transistors (MHEMTs). We fabricated the T-gate with 100 nm foot print by using a positive resist ZEP520/P (MMA-MAA)/PMMA trilayer by double exposure method. The fabricated 100 nm MHEMT with a $70\;{\mu}m$ unit gate width and two fingers were characterized through do and rf measurements. The maximum drain current density of 465 mA/mm and extrinsic transconductance $(g_m)$ of 844 mS/mm were obtained with our devices. From rf measurements, we obtained the current gain cut-off frequency $(f_T)$ of 192 GHz, and maximum oscillation frequency $(f_{max})$ 310 GHz.

Studies on the Characteristic of Removal Type Pressure-Sensitive Acrylic Adhesives (4원 공중합체 박리형 아크릴 점착제의 특성에 관한 연구)

  • Seo, Young-Ok;Seul, Soo-Duk
    • Journal of Adhesion and Interface
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    • v.1 no.1
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    • pp.15-22
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    • 2000
  • To prepare acrylic type pressure-sensitive adhesive, quarter polymers were synthesized from butylacrylate (BA), 2-ethylhexylacrylate (2-EHA), methyl methacrylate (MMA), 2-hydroxyethylmethacrylate (2-HEMA). The quarter polymer was identified by FT-IR. Molecular weight was measured by Gel Pearmeation Chromatograhy. Also, viscosity, solid content and peel strength were investigated. The peel strength was $160g_f/25mm$ when the volume ratio of feed monomer to solvent was 1.3:1 and the ratio was relevant to commercial usage. The pot life of adhesive was 30 s at the 50 m/min of heat treatment rate, and it indicated that the minimum drying time was 30 s. Not only weathering resistance keep up peel strength $160{\sim}180g_f/25mm$ after 1000 h, but also no residual remains.

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Preliminary Results of Extraction, Separation and Quantitation of Arsenic Species in Food and Dietary Supplements by HPLC-ICP-MS

  • Nam, Sang-Ho;Cheng, John;Mindak, William R.;Capar, Stephen G.
    • Bulletin of the Korean Chemical Society
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    • v.27 no.6
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    • pp.903-908
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    • 2006
  • Various extraction procedures were investigated using reference materials and samples to evaluate extraction efficiency and effectiveness. Inductively coupled plasma mass spectrometry (ICP-MS) was used to measure total arsenic and to quantitate arsenic species when coupled to an HPLC (high pressure liquid chromatography). Arsenic species were extracted from rice flour (NIST SRM 1568a) with water/methanol mixtures using accelerated solvent extraction (ASE). Total arsenic extraction efficiency ranged from 42 to 64%, for water and various methanol concentrations. From spinach (NIST SRM 1570), freeze-dried apple, and rice flour (NIST SRM 1568a), arsenic species were extracted with trifluoroacetic acid (TFA) at 100 ${^{\circ}C}$. Total arsenic extraction efficiency was 90% for spinach, 75% for freeze-dried apple, and 83% for rice flour. Enzymatic extraction with alpha-amylase and sonication resulted in extraction efficiency of 104% for rice flour, 98% for freeze-dried apple, and 7% for spinach. Chromatograms of arsenic species extracted by the optimum extraction methods were obtained, and the species were quantified. Arsenite (As(III)), arsenate (As(V)), dimethylarsinic acid (DMA), and monomethylarsonic acid (MMA) were found in the apple sample, and DMA and As(V) in the rice flour sample. As(V) and MMA were found in three herbal dietary supplement samples.

Polymerization and Effect of Organic/Organic Core Shell Binder (Organic/organic Core Shell 바인더의 중합과 처리영향)

  • Sim, Dong-Hyun;Ban, Ji-Eun;Kim, Min-Sung;Seul, Soo-Duk
    • Polymer(Korea)
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    • v.32 no.5
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    • pp.470-477
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    • 2008
  • Core shell binder of organic/organic pair that has two different properties within a particle were prepared by a step emulsion polymerization of methacrylate (MMA), styrene (St), ethyl acrylate (EA), butyl acrylate (BA), and 2-HEMA by using an water soluble initiator(APS) in the presence of an anionic surfactant (SDBS). Unwoven tensile strength of the core shell binder after processing and measuring the PSt/PMMA/2-HEM core shell with the binder is a value represents the highest was $10.75\;kg_f$/2.5cm, elongation measurements PEA/PBA core shell binder showed the highest value was 120.00%. In conclusion, using the core shell binders were able to control the mechanical properties such as tensile strength and elongation.

Synthesis of Polymer Materials Containing Platinum Nanoparticles and Their Application for Contact Lenses (백금 나노입자를 포함한 고분자재료의 합성 및 콘택트렌즈로의 응용)

  • Ye, Ki-Hun;Sung, A-Young
    • Journal of the Korean Chemical Society
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    • v.54 no.1
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    • pp.99-104
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    • 2010
  • Platinum nanoparticles were added to a mixture of HEMA (2-hydroxyethyl methacrylate), NVP (N-vinyl pyrrolidone) and MMA (methyl methacrylate) in a mould at various concentrations. The resulting mixture was copolymerized by heating at $70^{\circ}C$ for 40 min, $80^{\circ}C$ for 40 min, and $100^{\circ}C$ for 40 min, respectively. The physical properties of contact lens were then measured. The oxygen transmissibility of $9{\sim}15{\times}10^{-9}$ cm/s mL $O_2$/mL ${\times}$ mmHg, water content of 34.22~35.52%, refractive index of 1.432~1.435, visible transmittance of 88.3~91.2% and tensile strength of 0.141~0.152 kgf were obtained. The addition of platinum nanoparticles to the polymer allowed the contact lens to have various colors without artificial coloring agents. The polymer materials satisfied the physical properties required to produce contact lenses, making the material suitable to be applied as a functional material for ophthalmological purposes.