Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Preliminary Results of Extraction, Separation and Quantitation of Arsenic Species in Food and Dietary Supplements by HPLC-ICP-MS

  • Nam, Sang-Ho (Mokpo National University, Department of Chemistry) ;
  • Cheng, John (U. S. Food and Drug Administration, Elemental Research Branch, Center for Food Safety and Applied Nutrition) ;
  • Mindak, William R. (U. S. Food and Drug Administration, Elemental Research Branch, Center for Food Safety and Applied Nutrition) ;
  • Capar, Stephen G. (U. S. Food and Drug Administration, Elemental Research Branch, Center for Food Safety and Applied Nutrition)
  • Published : 2006.06.20
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Abstract

Various extraction procedures were investigated using reference materials and samples to evaluate extraction efficiency and effectiveness. Inductively coupled plasma mass spectrometry (ICP-MS) was used to measure total arsenic and to quantitate arsenic species when coupled to an HPLC (high pressure liquid chromatography). Arsenic species were extracted from rice flour (NIST SRM 1568a) with water/methanol mixtures using accelerated solvent extraction (ASE). Total arsenic extraction efficiency ranged from 42 to 64%, for water and various methanol concentrations. From spinach (NIST SRM 1570), freeze-dried apple, and rice flour (NIST SRM 1568a), arsenic species were extracted with trifluoroacetic acid (TFA) at 100 ${^{\circ}C}$. Total arsenic extraction efficiency was 90% for spinach, 75% for freeze-dried apple, and 83% for rice flour. Enzymatic extraction with alpha-amylase and sonication resulted in extraction efficiency of 104% for rice flour, 98% for freeze-dried apple, and 7% for spinach. Chromatograms of arsenic species extracted by the optimum extraction methods were obtained, and the species were quantified. Arsenite (As(III)), arsenate (As(V)), dimethylarsinic acid (DMA), and monomethylarsonic acid (MMA) were found in the apple sample, and DMA and As(V) in the rice flour sample. As(V) and MMA were found in three herbal dietary supplement samples.

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References

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