• Proceedings of the Korean Ceranic Society Conference
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• 2003.10a
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• pp.106.2-106
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• 2003

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07b
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• pp.790-793
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• 2004

이중의 망간 perovskite 블록을 가진 Ruddlesden-Popper 상(R-P phase) $Sr_3Mn_2O_7$ 은 공기중에서 불안정하다. 본 연구에서는 망간 이온 자리에 철 이온을 소량 치환 함으로써 R-P 상을 안정화 시켰으며 이들의 결정구조는 X-선회절 데이터를 이용하여 Rietveld 법으로 정밀화하였다. 안정화에 필요한 Fe 이온의 양은 약 x=0.15로 나타났으며 Fe이온의 양이 증가함에 따라 쉽게 안정화 되었다. 자화율 측정결과 x=0.20 시료는 120K에서 paramgnetic-antiferromagnetic 전이를 나타내었고 이 전이 온도는 치환되는 Fe이온의 양이 증가함에 따라 감소하는 경향을 나타내었다.

• Coupled systems mechanics
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• v.6 no.1
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• pp.29-40
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• 2017

This work employed density functional theory to investigate the structural and ferroelectric properties of the Ruddlesden-Popper (RP) phase of lead titanate, $Pb_2TiO_4$, as well as its phase transitions with epitaxial strain. A wealth of novel structural instabilities, which are absent in the host $PbTiO_3$ material, were identified in the RP phase through phonon soft-mode analysis. Our calculations showed that the ground state of $Pb_2TiO_4$ is antiferroelectric, distinct from the dominant ferroelectric phase in the corresponding host material. In addition, applied epitaxial strain was found to play a key role in the interactions among the instabilities. The induction of a sequence of antiferroelectric and antiferrodistortive (AFD) phase transitions by epitaxial strain was demonstrated, in which the ferroic instability and AFD distortion were cooperative rather than competitive, as is the case in the host $PbTiO_3$. The RP phase in conjunction with strain engineering thus represents a new approach to creating ferroic orders and modifying the interplay among structural instabilities in the same constituent materials, enabling us to tailor the functionality of perovskite oxides for novel device applications.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.06a
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• pp.351-352
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• 2009

이중의 망간 페로브스카이트 블록을 가진 Ruddlesden-Popper 상 (R-P phase) $Sr_3Mn_2O_7$은 공기중에서 불안정하다. 본 연구에서는 Sr이온 자리에 La, Ca이온을 치환함으로써 R-P상을 안정화 시켰으며, 이들의 결정구조는 Neutron Diffraction 데이터를 이용하여 Rietveld 법으로 정밀화하였다 $La_{1.4}Sr_{0.8}Ca_{0.8}Mn_2O_7$, $La_{1.2}Sr_{0.9}Ca_{0.9}Mn_2O_7$은 $T_N$이 80K이며 25K에서 spin-glass 변이가 관찰되었다.

• Bulletin of the Korean Chemical Society
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• v.32 no.8
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• pp.2761-2764
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• 2011

A new Ruddlesden-Popper phase $NdSr_2MnCrO_7$ has been prepared by the standard ceramic method. The powder X-ray diffraction studies suggest that the phase crystallizes with tetragonal unit cell in the space group I4/mmm. The electrical transport properties show that the phase is an electrical insulator and the electrical conduction in the phase occurs by a 3D variable range hopping mechanism. The magnetic studies suggest that the ferromagnetic interactions are dominant.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.1
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• pp.14-19
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• 2013

We have successfully synthesized $Bi_{4-x}La_xTi_3O_{12}$ (x~2) having Aurivillius-type layered perovskite structure from exfoliated layered perovskite oxide of $K_2La_2Ti_3O_{10}$ with Ruddlesden-Popper structure. The reaction between the exfoliated lanthanum titanate nanosheets and BiOCl nanocrystal resulted in the formation of polycrystalline $Bi_{4-x}La_xTi_3O_{12}$ (x~2) after heating above $700^{\circ}C$. Colloidal suspension of the nanosheets could be obtained by intercalating ethylamine (EA) into the protonated lanthanum titanate, $H_2La_2Ti_3O_{10}$, derived from $K_2La_2Ti_3O_{10}$. Transmission electron microscopic (TEM) analysis show that the exfoliated lanthanium titanate nanosheets have a thickness of a few nano meters. According to X-ray diffraction (XRD) analysis, the exfoliated lanthanium titanate was found to be transformed into $Bi_{4-x}La_xTi_3O_{12}$ (x~2) after restacking with BiOCl and subsequent thermal treatment at > $700^{\circ}C$.

• Journal of the Korean Ceramic Society
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• v.51 no.4
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• pp.265-270
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• 2014

Among the Ruddlesden-Popper series, $La_4Ni_3O_{10}$ has received widespread attention as a promising cathode material by reason of its favorable properties for realizing high performance of intermediate temperature solid oxide fuel cells (IT-SOFCs). The $La_4Ni_3O_{10}$ cathode is prepared using the facile sol-gel method by employing tri-blockcopolymer (F127) to obtain a single phase in a short sintering time. There are no reactions between the $La_4Ni_3O_{10}$ cathode and the $Ce_{0.9}Gd_{0.1}O_{2-\delta}$ (GDC) electrolyte upon sintering at $1000^{\circ}C$, indicating that the $La_4Ni_3O_{10}$ cathode has good chemical compatibility with the GDC electrolyte. The maximum electrical conductivity of $La_4Ni_3O_{10}$ reaches approximately 240 S $cm^{-1}$ at $100^{\circ}C$ and gradually decreases with increasing temperaturein air atmosphere. The area specific resistance value of $La_4Ni_3O_{10}$ composite with 40 wt% GDC is $0.435{\Omega}cm^2$ at $700^{\circ}C$. These data allow us to propose that the $La_4Ni_3O_{10}$-GDC composite cathode is a good candidate for IT-SOFC applications.

• Advances in nano research
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• v.13 no.2
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• pp.187-197
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• 2022

The synthesis of organic and hybrid organic-inorganic perovskites directly from solution improves the cost- and energy-efficiency of processing. To date, numerous research efforts have been devoted to investigating the influence of the various solvent parameters for the synthesis of lead halide perovskites, focused on the effects of different single solvents on the efficiency of the resulting perovskites. In this work, we investigated the effect of solvent blends for the first time on the structure and phase of perovskites produced via the Lewis base vapor diffusion method to develop a new synthetic approach for water-stable CsPbBr₃ particles with nanometer-sized dimensions. Solvent blends prepared with DMF and water-miscible solvents with different Gutmann's donor numbers (D_N) affect the Pb ions differently, resulting in a variety of lead bromide species with various colors. The use of a DMF/isopropanol solvent mixture was found to induce the formation of the Ruddlesden-Popper perovskite based on lead bromide. This perovskite undergoes a blue color shift in the solvated state owing to the separation of nanoplatelets. In contrast, the replacement of isopropanol with DMSO, which has a high DN, induces the formation of spherical CsPbBr₃ perovskite nanoparticles that exhibit green emission. Finally, the integration of acetone in the solvent system leads to the formation of lead bromide complexes with a yellow-orange color and the perovskite CsPbBr₃.