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Synthesis and Characterization of Intergrowth Type Perovskite Oxide NdSr2MnCrO7

  • Received : 2011.02.17
  • Accepted : 2011.07.08
  • Published : 2011.08.20

Abstract

A new Ruddlesden-Popper phase $NdSr_2MnCrO_7$ has been prepared by the standard ceramic method. The powder X-ray diffraction studies suggest that the phase crystallizes with tetragonal unit cell in the space group I4/mmm. The electrical transport properties show that the phase is an electrical insulator and the electrical conduction in the phase occurs by a 3D variable range hopping mechanism. The magnetic studies suggest that the ferromagnetic interactions are dominant.

Keywords

References

  1. Ruddlesden, S. N.; Popper, P. Acta Cryst. 1957, 10, 538. https://doi.org/10.1107/S0365110X57001929
  2. Ruddlesden, S. N.; Popper, P. Acta Cryst. 1958, 11, 54. https://doi.org/10.1107/S0365110X58000128
  3. Rao, C. N. R.; Ganguly, P.; Singh, K. K.; Mohan Ram, R. A. J. Solid State Chem. 1988, 72, 14. https://doi.org/10.1016/0022-4596(88)90003-5
  4. Adler, P. J. Solid State Chem. 1994, 108, 275. https://doi.org/10.1006/jssc.1994.1043
  5. Sreedhar, K.; McElfresh, M.; Perry, D.; Kim, D.; Metcalf, P.; Honig, J. M. J. Solid State Chem. 1994, 110, 208. https://doi.org/10.1006/jssc.1994.1161
  6. Jung, W.-H. J. Mat. Sci. Lett. 2000, 19, 1307. https://doi.org/10.1023/A:1006724426186
  7. Arbuzova, T. I.; Naumov, S. V.; Arbuzov, V. L. Phy. Solid State 2003, 45, 1513. https://doi.org/10.1134/1.1602889
  8. Jung, W.-H. J. Mat. Sci. Lett. 2003, 22, 527. https://doi.org/10.1023/A:1022990420545
  9. Sudhakar, N.; Rajeev, K. P. J. Electronic Materials 2004, 33, 1259. https://doi.org/10.1007/s11664-004-0150-6
  10. Zhang, R. L.; Zhao, B. C.; Song, W. H.; Ma, Y. Q.; Yang, J.; Sheng, Z. G.; Dai, J. M. J. App. Phys. 2004, 96, 4965. https://doi.org/10.1063/1.1794907
  11. Yankin, A. M.; Fedorova, O. M.; Zvereva, I. A.; Titova, S. G.; Balakirev, V. F. Glass Physics and Chemistry 2006, 32, 574. https://doi.org/10.1134/S1087659606050117
  12. Fedorova, M. O.; Yankin, A. M.; Zvereva, I. A.; Titova, S. G.; Balakirev, V. F. Glass Physics and Chemistry 2008, 34, 201. https://doi.org/10.1134/S1087659608020144
  13. Gundakaram, R.; Lin, J. G.; Lee, F. Y.; Tai, M. F.; Shen, C. H.; Liu, R. S.; Huang, C. Y. J. Phys.: Condens. Matter 1999, 11, 5187. https://doi.org/10.1088/0953-8984/11/26/319
  14. Zhang, J.; Wang, F.; Zhang, P.; Yan, Q. J. Appl. Phys. 1999, 86, 1604. https://doi.org/10.1063/1.370933
  15. Reveau, R.; Maignan, A.; Martin, C.; Mahendiran, R.; Hervien, M. J. Solid State Chem. 2000, 151, 330. https://doi.org/10.1006/jssc.2000.8722
  16. Zhang, J.; Yan, J. Q.; Wang, F.; Yuan, P.; Zhang, P. J. Phys.: Condens. Matter 2000, 12, 1981.
  17. Maignan, A.; Martin, C.; Hervien, M.; Raveau, B. Solid State Commun. 2001, 117, 377. https://doi.org/10.1016/S0038-1098(00)00482-8
  18. Martin, C.; Maignan, A.; Hervien, M.; Antret, C.; Raveau, B.; Khomski, D. I. Phys. Rev. B 2001, 63, 174404. https://doi.org/10.1103/PhysRevB.63.174404
  19. Sahu, R. K.; Mohammad, Q.; Rao, M. L.; Manoharan, S. S.; Nigam, A. K. App. Phys. Lett. 2002, 80, 88. https://doi.org/10.1063/1.1431398
  20. Sudhakar, N.; Rajeev, K. P.; Nigam, A. K. J. Appl. Phys. 2003, 93, 8331. https://doi.org/10.1063/1.1556977
  21. Mizutani, N.; Kitazawa, A.; Okuma, N.; Kato, M. Kogyo Kagaku Zasshi 1970, 73, 1097. https://doi.org/10.1246/nikkashi1898.73.6_1097
  22. Taguchi, H.; Yoshioka, H.; Matsuda, D.; Nagao, M. J. Solid State Chem. 1993, 104, 460. https://doi.org/10.1006/jssc.1993.1181
  23. Rodriguez-Carvajal, J. Physica B 1993, 192, 55. https://doi.org/10.1016/0921-4526(93)90108-I
  24. Suzuki, N.; Noritake, T.; Yamamoto, N.; Hioki, T. Mater. Res. Bull. 1991, 26, 1. https://doi.org/10.1016/0025-5408(91)90032-H
  25. Sharma, I. B.; Magotra, S. K.; Singh, D.; Batra, S.; Mudher, K. D. S. J. Alloys Compds. 1999, 291, 16. https://doi.org/10.1016/S0925-8388(99)00257-1
  26. Singh, D.; Singh, R. J. Chem. Sci. 2010, 122, 807. https://doi.org/10.1007/s12039-010-0068-x
  27. Subramanian, M. A.; Torardi, C. C.; Johnson, D. C.; Pannetier, J.; Sleight, A. W. J. Solid State Chem. 1998, 72, 24.
  28. Maignan, A.; Martin, C.; Damay, F.; Hervien, M.; Raveau, B. J. Magn. Magn. Mater. 1998, 188, 185. https://doi.org/10.1016/S0304-8853(98)00161-9