• 한국염색가공학회지
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• 제30권2호
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• pp.77-89
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• 2018

In the case of fiber/rubber composites for tire applications, the interfacial adhesion between fiber and rubber significantly affects the physical properties of the finished products. Generally, organic synthetic fibers used for tire cords are treated with resorcinol formaldehyde latex(RFL) primer on the surface of the fiber to improve the adhesion to rubber. Changes of adhesion between rubber and tire cords might weaken as temperature rises due to overheating of car engine and friction with road. In this study, the effects of temperature on the primer treated polyketone cord/rubber composites and the changes in interfacial adhesion were investigated. Polyketone cord/rubber composites were prepared after RFL solution treatment on the surface of polyketone fibers. After that, composites was thermally aged at different temperature conditions(60, 80, 100, $120^{\circ}C$) and times(1, 5, 10, 15days). The adhesion strength of polyketone cord/rubber composite treated with RFL primer was higher than untreated composite by more than 3 times. After heat aging, the adhesion strength of untreated polyketone cord/rubber composites increased while the RFL treated polyketone cord/rubber composites decreased somewhat.

• International Journal of Automotive Technology
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• 제7권6호
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• pp.741-747
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• 2006

It has been almost impossible to predict the fatigue life in the field of rubber materials by numerical methods. One of the reasons is that there are no obvious fracture criteria and excessively various ways of mixing processes. Tearing energy is considered as a fracture criterion which can be applied to rubber compounds regardless of different types of fillers, relative to other fracture factors. Fatigue life of rubber materials can be approximately predicted based on the assumption that the latent defect caused by contaminants or voids in the matrix, imperfectly dispersed compounding ingredients, mold lubricants and surface flaws always exists. Numerical expression for the prediction of fatigue life was derived from the rate of rough cut growth region and the formulated tearing energy equation. Endurance test data for dumbbell specimens were compared with the predicted fatigue life for verification. Also, fatigue life of industrial rubber components was predicted.

• Elastomers and Composites
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• 제34권4호
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• pp.299-314
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• 1999

Bonding metal and textile components to rubber has always posed a problem. In this paper, an attempt had been made to modify textile and metal surfaces for bonding with rubber. The metal surfaces were modified using silane coupling agents and textile fibers were modified using plasma polymerization techniques. Some results on adhesion of metals to a range of sulfur-cured rubber compounds using a combination of organofunctional silanes are given here. The treatment was not only effective for high-sulfur compounds but also for low-sulfur com pounds as used in engine mounts and even for some semi-EV compounds. Coatings of plasmapolymerized pyrrole or acetylene were deposited on aramid and polyester tire cords. Standard pull-out force adhesion measurements were used to determine adhesion of tire cords to rubber compounds. The plasma coatings were characterized by various techniques and the performance results are explained in an interpenetrating network model.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2004년도 추계학술대회 논문집
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• pp.634-637
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• 2004

This paper presents a Split Hopkinson Pressure Bar(SHPB) technique to obtain compressive stress-strain data for rubber materials. An experimental technique that modifies the conventional Split Hopkinson Pressure Bar(SHPB) has been developed for measuring the compressive stress-strain responses of materials with low mechanical impedance and low compressive strengths such as rubber. This paper introduces an all-polymeric pressure bar which achieves a closer impedance match between the pressure bar and the specimen materials. In addition, we are a pulse shaper to lengthen the rising time of the incident wave to ensure stress equilibrium and homogeneous deformation of a rubber materials. It is found that the modified technique can be determine the dynamic deformation behavior of an NBR rubber more accurately.

• 소음진동
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• 제9권3호
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• pp.472-476
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• 1999

The effect of static preload on the dynamic properties of rubber materials is rather important, especially when good isolation characteristics are required at high frequencies. However, there are still few papers for dynamic characteristics of compressed rubber components. It was demonstrated in reference (4) that for bonded rubber material of a cylindrical shape, a simplified theory equation between linear dynamic and nonlinear static behavior of rubber material was useful to predict their combined effects. This paper presents the second part of the study. It is confirmed that for the compressed rubber material, the stress can be factored into a function of frequency and a function of strain(stretch). The finite element methodis applied to analyze non-linear large deformation of rubber material and its results are compared with those of a simplified theory equation. The predicted dynamic material properties based on non-linear static finite element analyses have a good agreement of experimental results and those based on simplified theory equation.

• Macromolecular Research
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• 제13권1호
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• pp.30-38
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• 2005

Sulfur-cured gum natural rubber vulcanizates were devulcanized using two different concentrations of diallyl disulfide. The devulcanization process was performed at $110^{\circ}C$ min in an open two-roll cracker-cum-mixing mill. Natural rubber vulcanizates having various sulfur/accelerator ratios were used to study the cleavage of monosulfide, disulfide, and polysulfide bonds. The properties of devulcanized natural rubber increased upon increasing the disulfide concentration and the mechanical properties of the revulcanized natural rubber increased upon decreasing the sulfur content in the original rubber vulcanizates. The scorch time and the maximum state of cure both increased when the ground vulcanizates were treated with higher amounts of disulfide. TGA and DMA were conducted to study the effects of the devulcanization on the thermal stability and the $T_g$ behavior of the vulcanizates. SEM analysis was conducted to study how the failure mechanism was affected by the devulcanization process. It was possible to recover $70-80\%$ of the original gum rubber properties by using this process. From IR spectroscopic analysis, we observed that the oxidation of the main chains did not occur during high-temperature milling.

• 대한치과보철학회지
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• 제35권2호
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• pp.277-295
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• 1997

After clinical adjustment of dental casting restoration, re-polishing procedure is recommanded because the smooth gold sureface is lost. But there is the possibility to get more loose contact than that intended by loss of gold alloy according to the kinds of polishing materials and polishing time. Therefore in this study I polished type II gold alloy with 390gm force, 20,000rpm speed, and 8 kinds of gold alloy polishing materials, fabricated by 4 companies and then measured the amount of loss of gold alloy with Surfcorder SEF-30D and observed alloy surfaces polished by 3 brown rubber points with SEM. The amount of loss of gold alloys polished with 8 kinds of polishing materials and the degree of smoothness of gold alloys according to polishing time and polishing materials were compared. The following results were obtained : 1. When the amount of loss of gold alloys polished with 3 kinds of brown rubber point was compared, Alphalex brown point had the most amount of alloy loss, followed in decreasing order by Shofu brown point and Eveflex brown point. There was statistically significant difference in the amount of alloy loss according to polishing materials. 2. When the amount of loss of gold alloys polished with 5 kinds of green rubber point was compared, Shofu green point had the most amount of alloy loss, followed in decreasing order by Alphaflex green point, Dedeco green clasp polisher, and Eveflex green point. There was statistically significant difference in the amount of alloy loss according to polishing materials except Alphaflex green point and Dedeco green clasp polisher. 3. When the amount of loss of gold alloys polished with all kinds of rubber point was compared, there was no significant difference in Eveflex brown point, Alphaflex green point, and Dedeco green clasp polisher. 4. When average amount of alloy loss per 1 revolution by polishing materials was compared, Alphalex brown point had the greatest value as $0.329{\mu}m$ and Shofu supergreen point had the lowest value as $0.022{\mu}m$. 5. When the degree of sureface smoothness of gold alloy polished with 3 kinds of brown rubber point was compared, In Alphalex brown point surface roughness was completely lost after 20 seconds polishing time, in Shofu brown point 30 seconds, in Eveflex brown point 40 seconds. But in every gold alloys fine scratch formed by rubber points was observed. Based on the results of this study, as rubber polishing materials used in polishing of dental casting restoration after clinical adjustment influenced on the tightness of occlusal or proximal contact, we should make dental casting restoration with minimum error through careful laboratory procedure and form very smooth surface of restoration with tripoli and rouge after use of silicone polishing materials.

• Elastomers and Composites
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• 제52권4호
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• pp.303-308
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• 2017

In this study, finite element modeling and material property tests are performed for the finite element analysis of rubber isolator parts which support the engine and isolate the vibration. As a result of the P direction analysis of the rubber isolator parts, the static stiffness in the P direction was 44.2 kg/mm, which is well within the error of 5% as compared with the test result of 46.1 kg/mm. The static stiffness of the rubber isolator parts in the Q direction was calculated to be 7.9 kg/mm, which is comparable to the test result of 8.6 kg/mm, with an error of less than 8%. As a result of the analysis on the Z direction, the static stiffness was calculated as 57.7 kg/mm, and the test results were not available. Through this study, it is expected that the time and cost for prototype development can be reduced through nonlinear finite element analysis for rubber isolator parts.

• Elastomers and Composites
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• 제29권3호
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• pp.207-212
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• 1994

Recently, the develpment of waterproof techniques has been required in morden building field. It is undoubt that one of the best materials for waterproof is polyurethane. Polyurethanes have advantages such as good adhesive ability, durability, weatherproof. However, they have disadvantages like high cost, delicate varnish layer, swelling problem. In this study, we found that the polyurethane with rubber particle of waste tire can solve those problems. We concluded that 10% of rubber particles containing polyurethane was recommened as the waterproof materials.

• Macromolecular Research
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• 제12권1호
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• pp.11-21
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• 2004

Toughening of epoxy resins for improvement of crack resistance has been the subject of intense research interest during the last two decades. Epoxy resins are successfully toughened by blending with a suitable liquid rubber, which initially remains miscible with epoxy and undergoes a phase separation in the course of curing that leads to the formation of a two-phase microstructure, or by directly blending preformed rubbery particle. Unlike the situation for thermoplastics, physical blending is not successful for toughening epoxy resins. Recent advances in the development of various functionalized liquid rubber-based toughening agents and core-shell particles are discussed critically in this review.