• Title/Summary/Keyword: Rubbed polyimide

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Effect of conjugation of mesogenic core of nematic liquid crystals for polar anchoring strength on rubbed polyimide surfaces (극각 방향의 결합강도에 관한 네마틱 액정의 분자구조 변화의 효과)

  • 서대식
    • Electrical & Electronic Materials
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    • v.9 no.3
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    • pp.265-269
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    • 1996
  • We have studied the effect of the mesogenic core of nematic liquid crystals (NLCs) for polar (out-of-plane tilt) anchoring strength and surface order parameter on rubbed polyimide (PI) surfaces. The order of polar anchoring strength for NLCs on rubbed PI surfaces is 5CB > PCH5 > CCH5. From the above results, we suggest that the polar anchoring strength depends on the polarizability of the NLCs. The surface order parameter for NLCs is 5CB > PCH5 > CCH5 on rubbed PI surfaces. We conclude that the polar anchoring strength is strongly related to the surface order parameter on rubbed PI surfaces.

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Washing Effects on Generation of Pretilt Angle in NLC, 5CB, on a Polyimide Surface with Trifluoromethyl Moieties

  • Lee, Sang-Keuk;Hwang, Jeoung-Yeon;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.04a
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    • pp.133-135
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    • 2003
  • The washing effects on pretilt angle generation in a nematic liquid crystal (NLC), 4-n-pentyl-4’-cyanobiphenyl (5CB) on a rubbed polyimide (PI) surface with trifluoromethyl moiety have been successfully studied. The pretilt angle of 5CB is increased by the washing process on the rubbed PI surface. The surface tension on the rubbed PI surface increases with the rubbing strength RS and then saturated above RS=150 mm. The pretilt angle of 5CB for all washing processes on the rubbed PI surface decreases with the surface tension. We have found that the pretilt angle of 5CB on the rubbed PI surface may be attributed van der walls (VDW) dispersion interaction between the LC molecules and the polymer surfaces having trifluoromethyl moieties.

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Odd-Even Effects of the Anchoring Strength for Nematic Liquid Crystal on Rubbed Polyimide LB Surfaces (러빙처리된 폴리이미드막 LB막에 있어서 네마틱액정의 결합강도의 홀수짝수 효과)

  • Seo, Dae-Shik
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1453-1455
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    • 1996
  • The odd-even effect of the alkyl chain length of rubbed polyimide Langmuir-Blodgett (LB) surfaces on the extrapolation length of 5CB has been successfully evaluated for the first time by measuring polar anchoring strength. The extrapolation length of 5CB for rubbed PI-LB surfaces with even-numbers is small compared with odd-numbers for alkyl chain lengths of greater than 7 carbons. The extrapolation length of 5CB on rubbed PI-LB surfaces with odd-numbers increases gradually as the temperature increases but tends to diverge near the clearing temperature (Tc=$35.3^{\circ}C$). The extrapolation length diverges because of rapidly decreasing surface order near $T_c$. We suggest that the polar anchoring strength on rubbed PI-LB surfaces with even-number is strong because of relatively high surface ordering caused by more crystalline surfaces. Finally, we conclude that the odd-even effects of the polar anchoring strength in NLCs are strongly related to the character of the polymer and observed clearly for long alkyl chain lengths.

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Effect of Conjugation of Mesogenic Core of Nematic Liquid Crystals for Polar Anchoring Strength on Rubbed Polyimide Films. (극각 방향의 결합강도와 표면질서도에 관한 네마틱 액정의 분자구조 변화의 효과)

  • 서대식;곽희로
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.265-268
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    • 1995
  • We have studied the effect of the mesogenic core of nematic liquid crystals (NLCs) for polar (out-of-plane tilt) anchoring strength and surface order parameter on rubbed polyimide (PI) films. The order of polar anchoring strength for NLCs on rubbed PI films is 5CB > PCH5 > CCH5. This order is the same for all rubbing strengths investigated. The surface order parameter for NLCs is 5CB > PCH-5 > CCH5 on rubbed PI films. From these results, we suggest that the polar anchoring strength is strongly related to the surface order parameter.

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A Study on Response Characteristics of TN Cell on a Polyimide Surface (폴리이미드 표면에서의 TN 셀의 응답 특성에 관한 연구)

  • 황정연;전용제;정연학;서대식
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.9
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    • pp.808-811
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    • 2002
  • We investigated response characteristics of twisted nematic (TN) cell with different nematic liquid crystals (NLCs) and cell gap d on a rubbed polyimide (PI) surface. High transmittance and fast response time of the TN cell on the rubbed PI surface were achieved by using high birefringence (Δn) and low cell gap d. The response time of TN cell on the rubbed PI surface was measured 5.1 ms. The transmittance and response time of the TN cell on the rubbed PI surface decreased with decreasing Δnd.

Polymer Layer Effects on Anchoring Strength and Surface Ordering in NLC, 5CB, by the Washing Process after Rubbing on the Polyimide Surfaces

  • Lee, Sang-Keuk;Han, Jeong-Min;Hwang, Jeoung-Yeon;Seo, Dae-Shik
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.2
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    • pp.5-9
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    • 2003
  • The liquid crystal (LC) aligning capabilities by the washing processes after rubbing on the two kinds of the rubbed polyimide (Pl) surface were studied. The polar anchoring energy of 4-n-pentyl-4'-cyanobiphenyl (5CB) increased with the rubbing strength RS on the two kinds of the rubbed PI surface. The polar anchoring energy of 5CB on the rubbed PI surface with alkyl side chains is larger than the rubbed PI surface with CONH moiety. Also, the surface ordering of 5CB on the rubbed PI surface with alkyl side chains is larger than the rubbed PI surface with CONH moiety. Therefore, the surface ordering of 5CB strongly depends on the polymers and washing process.

Polymer Layer Effects on Anchoring Strength and Surface Ordering in NLC, 5CB, by the Washing Process after Rubbing on the Polyimide Surfaces

  • Lee, S.K.;Lee, J.U.;Han, J.M.;Hwang, J.Y.;Seo, D.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.506-509
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    • 2003
  • The liquid crystal (LC) aligning capabilities by the washing processes after rubbing on the two kinds of the rubbed polyimide (PI) surface were studied. The polar anchoring energy of 4-n-pentyl-4'-cyanobiphenyl (5CB) increased with the rubbing strength RS on the two kinds of the rubbed PI surface. The polar anchoring energy of 5CB on the rubbed PI surface with alkyl side chains is larger than the rubbed PI surface with CONH moiety. Also, the surface ordering of 5CB on the rubbed PI surface with alkyl side chains is larger than the rubbed PI surface with CONH moiety. Therefore, the surface ordering of 5CB strongly depends on the polymers and washing process.

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Evaluation of LCD device parameters and rubbed surface of Polyimide by means of renormalized spectroscopic ellipsometry

  • Kimura, Munehiro;Hasegawa, G.;Sakamoto, H.;Akahane, T.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1715-1718
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    • 2006
  • Evaluating method of the device parameters of liquid crystal display (LCD) by means of the renormalized transmission spectroscopic ellipsometry is demonstrated. Dielectric and elastic constant, threshold voltage, pretilt angle, cell gap and Anchoring strength coefficients can be evaluated from the measurement of ellipsometric parameters measured by the symmetrically oblique incidence transmission ellipsometry (SOITE). Furthermore, rapid evaluating method for rubbed polyimide film is also demonstrated.

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Control of High Pretilt Angle for Nematic Liquid Crystal of Negative Dielectric Anisotropy on Blending Polymer Surfaces (복합 폴리머 표면에서의 부의 유전율을 가진 네마틱액정의 고프리틸트각 제어)

  • 황정연;서대식;남상회
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.12
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    • pp.1023-1026
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    • 2001
  • The control of high pretilt angle for nematic liquid crystal (NLC) with negative dielectric anisotropy on the rubbed blending polyimide (PI) of homeotropic and homogeneous alignment surface was studied. High LC pretilt angle on the rubbing blending polyimide of homeotropic PI and SE-7492 surface was measured and the LC pretilt angle increased wish blending ratio and rubbing strength. However, the low LC pretilt angle on the rubbed blending polyimide of homeotropic PI and SE-150 surface was measured. The high pretilt angle of NLC can be achieved by using the blending PI surface.

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Washing Effects on Generation of Pretilt Angle in NLC, 5CB, on a Polyimide Surface with Trifluoromethyl Moieties

  • Lee, Sang-Keuk;Han, Jeong-Min;Hwang, Jeoung-Yeon;Seo, Dae-Shik
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.1
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    • pp.21-23
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    • 2003
  • The washing effects on pretilt angle generation in a nematic liquid crystal (NLC), 4-n-pentyl-4'-cyanobiphenyl (5CB) on a rubbed polyimide (PI) surface with trifluoromethyl moiety have been successfully studied. The pretilt angle of 5CB is increased by the washing process on the rubbed PI surface. The surface tension on the rubbed PI surface increases with the rubbing strength RS and then saturated above RS: 150 mm. The pretilt angle of 5CB for all washing processes on the rubbed PI surface decreases with the surface tension. We have found that the pretilt angle of 5CB on the rubbed PI surface may be attributed van der walls (VDW) dispersion interaction between the LC molecules and the polymer surfaces having trifluoromethyl moieties.