• 분석과학
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• 제8권4호
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• pp.649-654
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• 1995

The reactivity of superoxide ion($O{_2}^{-.}$) with halogenated substrates is investigated by cyclic voltammetry and rotated ring-disk electrode method in aprotic solvents. The more positive the reduction potential of the substituted nitrile, the more facile is nucleophilic displacement by $O{_2}^{-.}$. The reaction rates of halogenonitriles with $O{_2}^{-.}$ vary according to the leaving-group propensity of halide (Br>Cl>F). The relative reaction rates of other substituted nitriles are in the order of electron-withdrawing propensity of the substituent group (CN> $C(O)NH_2$ >Ph, $CH_2CN$). The reaction of $O{_2}^{-.}$ with dihalocarbons indicates that five-membered rings can be rapidly formed by the cyclization of substrate and $O{_2}^{-.}$, and the relative rates of cyclization depend on the number of methylenic carbons {$Br(CH_2)_nBr$, [n=1<2<3>4>5]}. Mechanisms are proposed for the reaction of $O{_2}^{-.}$ with halogenated substrates.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2000년도 추계학술대회논문집
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• pp.553-557
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• 2000

Nonlinear Vibrations of a flexible circular ring is studied in this paper. Based upon the von Karman strain theory, the nonlinear governing equations are derived, in which the in-plane bending and extension displacements as well as the out-of-plane bending displacement are fully coupled. After discretizing the governing equations by the Galerkin approximation method, we obtain the linearlized equation by using the pertubation method. The analysis results from the linearlized equations show that the in-plane displacement has effects on the natural frequencies of the out-of-plane displacement.

• 전기화학회지
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• 제16권1호
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• pp.52-58
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• 2013

고분자 전해질 연료전지(Polymer Electrolyte Membrane Fuel Cell, PEMFC) 상용화를 위해 해결해야 할 과제 중의 하나인 가격 저감을 이루기 위한 방법으로 백금 촉매를 대신할 비귀금속(non-precious metal) 촉매 제조에 관한 연구를 수행하였다. 비귀금속 촉매의 합성은 산소환원반응(oxygen reduction reaction, ORR)의 활성점으로 알려져 있는 코발트-질소(Co-N) 결합을 형성하기 위해 질소를 포함하는 폴리아닐린(PANI)과 코발트염(Co precursor), 그리고 카본 블랙(C)을 일정한 비율대로 혼합한 후 특별한 열처리 과정 없이 단순한 화학적 환원법에 제조되었다. 제조된 Co-PANI-C 복합 촉매의 구조 분석을 위해 X-선 회절분석(X-ray diffraction, XRD)과 열중량분석(thermogravimetric analysis, TGA)을 실시하였고, ORR에 대한 활성을 평가하기 위해 rotating disk electrode(RDE) 및 rotating ring disk electrode(RRDE) 측정을 수행하였다. 그 결과 Co-PANI-C 복합 촉매는 ORR반응에 대한 개시 전압은 백금 촉매보다 60 mV 밖에 낮지 않은 값을 보였지만, 반응에 의해 발생되는 환원 전류는 여전히 백금 촉매보다 낮은 값을 보였다. 이 밖에도 전극 회전 속도에 따른 ORR 특성 변화, 전압 사이클 회수에 따른 내구성 변화, 연료전지 적용 시 성능 변화에 대해 논의할 것이다.

• Composites Research
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• 제14권2호
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• pp.8-12
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• 2001

필라멘트 와인딩 공법(filament winding process)은 회전하는 맨드렐에 로빙(roving)형태의 연속섬유를 감는 비교적 간단한 공정이다. 이것은 저장탱크, 화학용 파이프, 그리고 다른 산업에 사용되는 안정적이고 다양한 공법이다. 본 연구에서는 split disk test 치구와 dress disk test 치구에 의한 필라멘트 와인딩 링 시편의 인장강도 값을 실험에서 얻어진 결과와 혼합법칙에 의해 얻어진 이론적인 값을 비교하였다. 이 논문의 목적은 필라멘트 와인딩 구조물의 인장 특성 평가에 대한 적합한 시험법을 제안하고 있는 것이다. dress disk test 치구로 시험한 링 시험편의 인장강도는 split disk test 치구의 모서리 부분에서 발생하는 응력집중 때문에 split disk test의 시험 결과보다 이론적인 인장강도 간에 잘 근절함을 보여준다. 이 실험 결과 시험 치구의 기하학적 형상과 섬유의 연속성, 섬유 장력 그리고 시험편의 응력 집중에 영향은 받음을 알 수 있었다.

• 한국산학기술학회논문지
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• 제16권5호
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• pp.3044-3050
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• 2015

본 연구는 자동변속기용 유량제어 오일펌프의 성능을 해석하는데 목적이 있다. 이를 위하여 유량제어 오일펌프의 해석적 모델을 개발하였으며 회전속도 변화에 따른 토출유량, 구동토크, 캐비테이션 발생량 등의 내부 유동특성을 분석하여 고찰하였다. 해석결과, 회전속도가 높아짐에 따라 캐비테이션 발생율이 증가하였으며 체적효율은 2200 RPM에서 90%이상으로 나타났지만 회전속도가 상승함에 따라 감소하여 5000 RPM에서 81%까지 줄어드는 것으로 나타났다. 또한 흡입부 초기에 챔버 내 캐비테이션 비율이 20%~30%로 매우 높은 비율을 보였는데 압축에 의해 붕괴 이후의 캐비테이션 비율은 13% 이하로 낮게 형성되었다. 하지만 고속인 5000 RPM에서 17%로 빠른 속도로 발생량이 증가하는 현상도 확인되었다.

• 천문학회보
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• 제38권2호
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• pp.39.1-39.1
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• 2013

We use high-resolution hydrodynamic simulations to study nonlinear gas responses to imposed non-axisymmetric stellar potentials in barred-spiral galaxies. The gas is assumed to be infinitesimally thin, isothermal, and unmagnetized. We consider various spiral-arm models with differing strength and pattern speed, while fixing the bar parameters. We find that the extent and shapes of spiral shocks as well as the related mass drift depend rather sensitively on the pattern speed. In models where the arm pattern is rotating more slowly than the bar, the gaseous arms extend from the bar ends all the way to the outer boundary, with a pitch angle slightly smaller than that of the stellar counterpart. The arms drive mass inflows at a rate of ${\sim}0.5-2.5M{\odot}/yr$ to the bar region to which the shock dissipation, external torque, and self-gravitational torque contribute about 50%, 40%, and 10%, respectively. About 85% of the inflowing mass is added to bar substructures such as an inner ring, dust lanes, and a nuclear ring. while the remaining 15% encircles the bar region. On the other hand, models where the arms corotate with the bar exhibit mass outflows, rather than inflows, over most of the arm region. In these models, spiral shocks are much more tightly wound than the stellar arms and cease to exist in the region where $M{\bot}/sinp*{\geq}25-40$, where $M{\bot}$ denotes the Mach number of a rotating gas perpendicular to the arms with pitch angle p*. We demonstrate that the distributions of line-of-sight velocities and densities can be a useful diagnostic tool to distinguish if the arms and bar corotate or not.

• 한국전자파학회논문지
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• 제24권7호
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• pp.686-693
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• 2013

본 논문은 기판 집적형 도파관(SIW: Substrate Integrated Waveguide)와 상보적 분할링 공진기(CSRR: Complementary Split Ring Resonator)를 기반으로 한 전기적으로 작은 안테나를 제안한다. 안테나의 전기적 크기는 CSRR과 기존 SIW의 1/8크기인 Eighth-Mode Substrate Integrated Waveguide(EMSIW)를 적용하여 줄일 수 있었다. EMSIW는 기존의 SIW와 비교하였을 때 공진 주파수는 유지하면서 단지 12.5 %의 크기를 차지한다. 또한, EMSIW 안에 CSRR을 회전함으로써 안테나의 방사 특성을 유지하면서 공진 주파수를 바꿀 수 있었다. CSRR을 $0^{\circ}$부터 $360^{\circ}$까지 회전시켜 공진 주파수를 4.74 GHz에서 5.07 GHz까지 변화를 줄 수 있었다. 단향성 방사 패턴이 발생하며, 그 최대 이득은 4.5 dBi에서 5.92 dBi로 관측되었다.

• Tribology and Lubricants
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• 제31권6호
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• pp.302-307
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• 2015

The use of turbocharger in internal combustion engines has increased as it is a key components for improving system efficiency without increasing engine size. Because of increasing demand, many studies have evaluated rotordynamic performance so as to increase rotation speed. This paper presents a linear and nonlinear analysis model for a turbocharger rotor supported by a floating ring bearing. We constructed rotor model by using the finite element method and approximated bearings as being infinitely short. In the linear model, we considered fluid film force as stiffness and damping element. In nonlinear analysis, calculation of the fluid film force involved solving the time dependent Reynolds equation. We verified the developed model by comparing the results to those of previous research. The analysis results show that there are four unstable modes, which are rigid body modes combining ring and rotor motion. As the rotating speed increases, the logarithmic decrement shows that certain unstable modes goes into the stable area or the stable mode goes into the unstable area. These unstable modes appear as sub-synchronous vibrations in nonlinear analysis. In nonlinear analysis frequency jump phenomenon demonstrated in several experimental studies appears. The analysis results also showed that frequency jump phenomenon occurs when the vibration mode changes and the sequence of unstable mode matches the linear analysis result. However, the natural frequency predicted using linear analysis differs from those obtained using nonlinear analysis.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 춘계학술대회
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• pp.1475-1480
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• 2004

Plasma Enhanced Chemical Vapor Deposition (PECVD) process uses unique property of plasma to modify surfaces and to achieve the high deposition rates. In this study, a vertical thermal RF-PECVD (Radio Frequency-PECVD) reactor is modeled to investigate thermal flow and the deposition rates with various shapes of the showerhead. The showerhead in the CVD reactor has the shape of a ring and gases are injected in parallel with the susceptor, which is a rotating disk. In order to achieve the high deposition rates, we have simulated the thermal flow fields in the reactor with several showerhead models. Especially the effects of the number of injection holes and the rotating speed of the susceptor are studied. Using a commercial code, CFDACE, which uses FVM (Finite Volume Method) and SIMPLE algorithm, governing equations have been solved for the pressure, mass-flow rates and temperature distributions in the CVD reactor. With the help of the Nusselt number and Sherwood number, the heat and mass transfers on the susceptor are investigated. In order to characteristics of measure the flatness of the layer, furthermore, the relative growth rate (RGR) is considered.

• 천문학회보
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• 제45권1호
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• pp.33.2-33.2
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• 2020

Our HI monster sample is a set of local HI-rich galaxies identified by the ALFALFA survey (Arecibo Legacy Fast Survey ALFA) at z<0.08. Intriguingly, they are also found with a relatively large molecular gas reservoir compared to the galaxies with similar stellar mass and color, yet their star formation rate is quite comparable to normal spirals. This makes our HI monsters good candidates of galaxies in the process of gas accretion which may lead to the stellar mass growth. One feasible explanation for their relatively low star formation activity for a given high cool gas fraction is the gas in monsters being too turbulent to form stars as normal spirals. In order to verify this hypothesis, we probe the molecular gas kinematics of 10 HI monsters which we observed using the Atacama Large Millimeter/sub-millimeter Array (ALMA). We utilize the tilted ring model to investigate what fraction of the molecular gas in the sample is regularly and smoothly rotating. In addition, we model the molecular gas disk using the GALMOD package of the Groningen Image Processing System (GIPSY) and compare with the observations to identify the gas which is offset from the 'co-planar differential rotation'. Based on the results, we discuss the possibility of gas accretion in the sample, and the potential origin of non-regularly rotating gas and the inefficient star formation.