• Title/Summary/Keyword: Role Transition

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The Compatibilizing Effect of Maleic Anhydride in Ethylene-Vinyl Acetate (EVA)/Ethylene-${\alpha}$-Olefin Copolymers Blends

  • Park, Soo-Chul;Choe, Soon-Ja
    • Macromolecular Research
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    • v.13 no.4
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    • pp.297-305
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    • 2005
  • The compatibilizing effect of maleic anhydride (MA) in the immiscible blends of EVA22 (vinyl acetate content 22%)/ethylene-${\alpha}$-olefin copolymers with 1-butene (EtBC) and 1-octene (EtOC)) comonomers was studied. By adding 1, 2, and 3 phr of MA in the presence of dicumylperoxide, the morphology, tensile strength at break, and 100 and 300 % modulus of EVA22/EtBC and EVA22/EtOC blends were significantly enhanced. The melting point and crystallization point depression were observed upon the addition of MA. The changes in the ${\beta}$ transition and glass transition temperature of ethylene-${\alpha}$-olefin copolymers and ethylene-vinyl acetate copolymers, respectively, indicate that MA plays a role of compatibilizer for these immiscible blends. The TGA thermograms, measured from the blends with MA, show that thermal stability is slightly enhanced with MA, indicating that MA acts as a reinforcing agent either by grafting or crosslinking with other copolymers.

A Study on embodiment of Korean tradition of spatial comosition of contemporary residence (현대주택의 공간구성에 있어서 전통성 구현에 관한 연구)

  • 허진석;정용환
    • Journal of the Korean housing association
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    • v.12 no.3
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    • pp.21-28
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    • 2001
  • The purpose of this study is to find Korean tradition of residential space which continues since 1960s. Analysis of house works of contemporary architects on the foundation spatial characteristics of Korean. Traditional residence show that the trend and methods of embodiment of tradition in present architecture. The result of analysis could be summarized as follows. First, most of contemporary architects separate a house into two Chae-An Chae and Sa Rang Chae. Second, spatial flows in contemporary house works are very active through transition spaces just as traditional residence. Third, positive An Ma Dang takes on introversion, extroversion and continuity of space and also plays an important role in a house.

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A Study on the Transition and Workload of Self-Employed Women (여성 자영업자의 변화추이와 노동부담에 관한 소고)

  • 정영금
    • Journal of Family Resource Management and Policy Review
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    • v.5 no.2
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    • pp.1-12
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    • 2001
  • One of the fastest-growing job categories for women in both the developed and the developing nations of the world is that of self-employment. In 1990 women accounted for 29% of all self employed workers. In Korea, self-employed women including unpaid family workers accounted for 40.4% of all female workers. They are in economically low status and have heavy workload. So, this study examines the real state and problems of self-employed woman. For this purpose, the transition of the number of self-employed women is nationally compared. And the statistical data and time use data on them and role conflict due to paid work and household work are presented. In the future society, self-employment will be a good alternative to self-realization and career for women. So, for self-employed women, following education is needed according to stages of business and characteristics of managers; entrepreneurship, management, and balance of work and family.

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Thermodynamics of Reactive Dyes with Different Functional Groups (작용기의 종류에 따른 반응염색의 열역학)

  • 도성국
    • Textile Coloration and Finishing
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    • v.10 no.3
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    • pp.36-42
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    • 1998
  • The dyeabilities of C.I. Reactive Blue 19(B19, MW ; 626), C.I. Reactive Blue 4(B4, MW ; 637) and C.I. Reactive Black 5(B5, MW : 991) were investigated. Initial dyeing rates were increased and the amount of dye on the fabric at equilibrium was decreased with temperature like other ordinary dyeing processes. Activation entropy$(\Delta{S}^*)$ was decreased because of loose bonding between dyestuffes and fiber molecules at transition state. It can be clarified that the entire reaction is exothermic and the number of molecular species at transition state becomes greater from decrease in activation enthalpy$(\Delta{H}^*)$ and the increase in activation free energy$(\Delta{G}^*)$ with temperature, respectively. The amount of B19 on the fabric at equilibrium was greater than that of B4, because B4 became unreactive towards textile substrates through hydrolysis. Due to the biggest size of the dye molecule, the reaction rate of B5 was the slowest but its difunctional group played an important role in achieving the greatest amount of dye on the fabric at equilibrium.

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Contextual Modeling and Generation of Texture Observed in Single and Multi-channel Images

  • Jung, Myung-Hee
    • Korean Journal of Remote Sensing
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    • v.17 no.4
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    • pp.335-344
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    • 2001
  • Texture is extensively studied in a variety of image processing applications such as image segmentation and classification because it is an important property to perceive regions and surfaces. This paper focused on the analysis and synthesis of textured single and multiband images using Markov Random Field model considering the existent spatial correlation. Especially, for multiband images, the cross-channel correlation existing between bands as well as the spatial correlation within band should be considered in the model. Although a local interaction is assumed between the specified neighboring pixels in MRF models, during the maximization process, short-term correlations among neighboring pixels develop into long-term correlations. This result in exhibiting phase transition. In this research, the role of temperature to obtain the most probable state during the sampling procedure in discrete Markov Random Fields and the stopping rule were also studied.

Theoretical Models of Ethylene Polymerization

  • 장만채
    • Bulletin of the Korean Chemical Society
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    • v.20 no.11
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    • pp.1269-1276
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    • 1999
  • Metallocenes, whether using a cocatalyst or not, act as catalysts in ethylene polymerization. The positive charge on the transition metal of a metallocene might have an important role in polymerization as an active site in our model approach. Using semiempirical calculations in the absence of cocatalyst, we show one of the possibilities that the positive charge on a metallocene might be more easily transferred through the Cp ring of a ligand to the ethylene than to transfer directly from the transition metal to the ethylene. In these calculations, the charge on titanium in an eight C2H4 system is transferred and a polymer chain is produced. This reaction takes place only when ethylenes are arranged in a particular direction with respect to the ring, but does not take place for ethylenes near Ti or Cl atoms. The same mechanism is shown for a metallocene ligand which is sterically hindered or where the Cp ring is replaced by fluorenyl. These results suggest an entirely new polymerization mechanism in the absence of a cocatalyst in which the Cp ring is the active site.

Theoretical Researches of Kinetics and Anharmonic Effect for the Reactions Related to NO in the Ozone Denitration Process

  • Yu, Hongjing;Xia, Wenwen;Liu, Yancheng;Yao, Li
    • Journal of the Korean Chemical Society
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    • v.65 no.3
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    • pp.185-196
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    • 2021
  • For studying the reaction mechanism of the reactions related to NO in the ozone denitration reactions, the harmonic and anharmonic rate constants were calculated by the transition state (TS) theory and Yao and Lin (YL) method. According to above calculations, the reactions of NO with O3 and NO3 play an essential role, and the kinetic parameters considering anharmonic effect were fitted. Furthermore, the rate constants were up as temperature increasing, and the tendencies of high temperature were more gradual than the low temperature. The research will provide theoretical basis for the ozone denitration reactions.

A Study on Nurturing Korean Star Character by Analysis of Nintendo Super Mario Character Transition - Focusing on Robot Taekwon V - (닌텐도 '슈퍼마리오' 캐릭터 변천 분석에 따른 한국형 스타캐릭터 육성에 관한 연구 - 로봇태권 V를 중심으로 -)

  • Tak, Yeon-Suk
    • Journal of Korea Multimedia Society
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    • v.22 no.3
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    • pp.395-402
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    • 2019
  • Star characters play a key role in the background of contents that secure global competitiveness. In this study, we study the growth factors and transitional forms of Nintendo Super Mario Bros. and suggest the direction of nurturing Korean star characters. As a result of the analysis of Super Mario Bros., it was possible to derive the growth factors of Originality, repeatability, Continuity, Pertain, and Star Fame and the transition result of step development method. Robot Taekwon V was presented as a reference model while Korean game characters with global competitiveness were excavated. Robot Taekwon V, which combines the features of friendly, unique, symbolism, and narrative, could be used to present a development model of the type of jump development. In the jump development model, character development and Upbringing, diversification of genre, pioneering of new markets combined with new technology, and fostering of characters through linkage with other industries were presented.

Random sequence synchronization failure detection algorithm for synchronous stream cipher system using RMVD (RMVD를 이용하는 동기식 스트림 암호 데이터 통신시 난수동기 이탈 검출 알고리듬)

  • 박종욱
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.10 no.3
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    • pp.29-36
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    • 2000
  • It is very import role to increase communication quality that fast detection of random sequence synchronization fail in synchronous stream cipher system using initial synchronization mode. Generally it sends additional information to detect random sequency synchronization fail. But we can't transmit additional informations to decide synchronization fail in a system using RMVD to correct channel error. In this paper we propose a method to detect synchronization fail in the receiver even though a system using RMVD has no margin to send additional information, For detecting random sequency synchronization fail we decipher receiver data analyze probability of transition rate for pre-determined period and decide synchronization fail using calculated transition rate probability. This proposed method is fast very reliable and robust in noisy channel and is easily implemented with hardware.

The Current State of Foreign Transition to Open Access Journal Publishing in the Field of HSS (해외 인문사회과학 학술지 오픈액세스 전환 동향 연구)

  • Lee, Jae Yun;Joung, Kyoung Hee
    • Journal of the Korean Society for information Management
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    • v.37 no.3
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    • pp.301-326
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    • 2020
  • This study analyzed recent cases of transition to open access(OA) journals in humanities and social sciences(HSS) in foreign countries to find a way to transition to OA journals in Korea. Ling OA and UP led by researchers, OLH and KU led by libraries, S2O led by publishers and L+F model led by funders and libraries were analyzed. Programs by national funding agencies such as the Norwegian Research Council, Canada Social Sciences and Humanities Research Council, Austrian Science Fund, and Swiss Academy of Humanities and Social Sciences were also reviewed. Based on the results of the analyses, this study suggests for transition in Korean HSS field as follows; 1) transitions to open access journals in HSS should be supported at national level 2) the stakeholder in scholarly communications such as the nation, universities, libraries, research funders, scholarly societies etc has their own role in the transition but funders and libraries are the most important in financial support for open access publishing 3) but the financial support for the first stage of the transition should be done at national level 4) and open access journal publishing consortium comprised of libraries and information service institutions in the public sector such as KERIS, KISTI and the national library should be established 5) non commercial publishing platforms for scholarly societies should be developed and distributed.