• Proceeding of EDISON Challenge
• /
• 2016.03a
• /
• pp.155-162
• /
• 2016

This study attempts to reveal structures of two-dimensional ring polymer solutions in various polymer concentrations ranging from dilute to concentrated regime. Polymer sizes, single molecule structure factors, bond correlation functions and monomer density distribution functions from center of mass are given in order to clarify the polymer structures. Our study shows that a ring in dilute solution maintain pseudo-circular structure with self-avoiding walk (SAW) statistics, and it seems to be composed of two connecting SAW linear chains. In semidilute solutions, ring polymers are not entangled with each other and adopt collapsed configurations. Such assumption of collapsed structures in the semidilute regime gives an overlap concentration of ${\varphi}^*{\sim}N^{-1/2}$ where N is degree of polymerization. By normalizing the polymer concentration by these overlap concentration, we find universal behaviors of polymer sizes and structure factors regardless of N.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
• /
• 2002.05a
• /
• pp.291-295
• /
• 2002

O-ring seal is usual component part in various mechanical apparatus for sealing that makes efficient performance of the equipments. The sealing performance of O-ring is affected in environments of the O-rings, like that applied pressure, working temperature, pre-compressed ratio and materials. In this paper, a pressurized, compressed elastomeric bi-polymer O-ring inserted into a rectangular groove is analyzed numerically using the MARC finite element program. The calculated FEM results showed that bi-polymer O-ring that is manufactured by NBR for an inner and FFKM for an outer ring shows a low temperature distribution among various bi-polymer O-ring models. But, the normal contact stress between the flange and upper part of the O-ring is small compared to other bi-polymer model.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.3
• /
• pp.975-979
• /
• 2012

Structure and Dynamics of dilute two-dimensional (2D) ring polymer solutions are investigated by using discontinuous molecular dynamics simulations. A ring polymer and solvent molecules are modeled as a tangent-hard disc chain and hard discs, respectively. Some of solvent molecules are confined inside the 2D ring polymer unlike in 2D linear polymer solutions or three-dimensional polymer solutions. The structure and the dynamics of the 2D ring polymers change significantly with the number ($N_{in}$) of such solvent molecules inside the 2D ring polymers. The mean-squared radius of gyration ($R^2$) increases with $N_{in}$ and scales as $R{\sim}N^{\nu}$ with the scaling exponent $\nu$ that depends on $N_{in}$. When $N_{in}$ is large enough, ${\nu}{\approx}1$, which is consistent with experiments. Meanwhile, for a small $N_{in}{\approx}0.66$ and the 2D ring polymers show unexpected structure. The diffusion coefficient (D) and the rotational relaxation time ($\tau_{rot}$) are also sensitive to $N_{in}$: D decreases and $\tau$ increases sharply with $N_{in}$. D of 2D ring polymers shows a strong size-dependency, i.e., D ~ ln(L), where L is the simulation cell dimension. But the rotational diffusion and its relaxation time ($\tau_{rot}$) are not-size dependent. More interestingly, the scaling behavior of $\tau_{rot}$ also changes with $N_{in}$; for a large $N_{in}$ $\tau_{rot}{\sim}N^{2.46}$ but for a small $N_{in}$ $\tau_{rot}{\sim}N^{1.43}$.

• Proceeding of EDISON Challenge
• /
• 2016.03a
• /
• pp.147-154
• /
• 2016

Co-nonsolvency is a puzzling phenomenon that a polymer swells in a good solvent individually, but it collapses in a mixture of good solvents. This structural transition with changing solvent environment has been drawing attention due to practical application for stimuli-responsive polymer. The aim of this work is to describe the physical origin of the co-nonsolvency. In this work, we present Monte Carlo simulations for polymer solutions by using simple and general model. We simulate linear and ring polymers to compare their co-nonsolvency behaviors. Calculating Flory exponents and bridging fractions gives a good description for polymer structures. While the polymer structure shows non-monotonous behavior with increasing the cosolvent fraction, the chemical potential decreases monotonously. This indicates that coil-to-globule transition of polymers is purely controlled by free energy and can be regarded as a thermodynamics transition. We also present that ring polymers have higher looping probability than linear polymers, thus the bridging fraction remains higher at high cosolvent fraction. Our study provides a new perspective to understand polymer structure when the polymer "dissolves well" in any solvent.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2008.11a
• /
• pp.369-370
• /
• 2008

This paper describes the electric field distribution of high voltage polymer bushing with inner field shaper designs. The field control can be achieved by means of the designs of such internal field shaper. But high electric stress occurred between field shaper and central conductor by the closely space. In accordance, the floating and ring shield designs was importance for electric stress grading at critical parts of the bushing. The bushing has a central conductor, and internal ring shield or floating shield, gaps are formed between field shaper and ring shield. Accordance equipotential lines extend through gaps. Maxwell 2D simulator based on the boundary element method was also introduced in order to verify the reliability of the polymer bushing.

• Elastomers and Composites
• /
• v.58 no.4
• /
• pp.201-207
• /
• 2023

Owing to their unique properties originating from slidable cross-links, polyrotaxane derivatives have potential applications as polymer electrolytes for lithium-ion batteries, lightweight polymer alloys for vehicular bodies and their glazing, elastic rubbers for tires, hydrogels for drug delivery. This article reviews the structures of polyrotaxanes comprising cyclic molecules threaded by a linear axle polymer. Next, the versatile characteristics of polyrotaxane gels, elastomers, and polymer alloys such as toughness, elasticity, and softness are discussed in relation to their supramolecular architectures. Finally, the mechanical behavior of solid ring cross-links are compared with that of conventional fixed cross-links for better understanding.

• Tribology and Lubricants
• /
• v.21 no.4
• /
• pp.171-176
• /
• 2005

O-ring seal is an essential component in various mechanical apparatuses for a sealing of oil container and pressure vessels. This paper presents the sealing pressure and compressive contact behaviors of hi-polymer O-rings, which is made by an outer shell of FFKM material and an inner solid ring of FKM one. The contact normal pressure and its ratios are measured by experimental method with an automatic control system of the working temperature and analyzed numerically by using the non-linear Marc FEM program. The results show reasonably good agreements between the computed FEM results and measured ones when the operating temperature is kom normal temperature of $18^{\circ}C$ and a high temperature of $300^{\circ}C$ But the compared values between the computed and tested results show a little difference because of the increased temperature, which is related to the non-linear parameter of the O-ring material. Bi-polymer 0-ring shows a good contact normal stress and compression behavior for a given operation temperature and compression ratio.

• Korean Journal of Optics and Photonics
• /
• v.19 no.3
• /
• pp.219-223
• /
• 2008

To realize a widely tunable laser diode, a polymer coupled-ring reflector is hybrid- integrated with reflective semiconductor optical amplifier. Even though ring-ring and ring-bus coupling ratios are changed by fabrication errors in waveguide width and height, they remain very close to the single peak condition, ensuring high yield in fabrication. The tuning range is observed to be about 35 nm, maintaining the side mode suppression ratio of about 30 dB.

• Bulletin of the Korean Chemical Society
• /
• v.27 no.1
• /
• pp.39-43
• /
• 2006

The relaxed torsional potential of a liquid crystalline polymer containing an ester functional group in a mesogenic unit (hereafter 12-4 oligomer) has been calculated with the ab initio self-consistent-field using 6-31G$^*$ basis set. GIAO^{13}C NMR chemical shifts also have been calculated at the B3LYP/6-31G$^*$ level of theory for each conformational structure obtained from torsional potential calculation. The results show that the phenyl ring-ester linkages are coplanar with the dihedral angle of about 0$^{\circ}$ and the ring-ring linkages in the biphenyl groups are tilted with the dihedral angle of around 43-44$^{\circ}$ in the lowest energy conformer. The biphenyl ring has a comparatively lower energy barrier of internal rotation potential in the ring-ring than that of phenyl ring-ester. The ^{13}C chemical shifts of carbonyl carbons were found to move to upfield due to $\pi$ -conjugation with phenyl ring and slightly affected about 0.5 ppm by dihedral angle of the ring-ring linkage.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.22 no.5
• /
• pp.436-442
• /
• 2009

This paper describes a study on the design of compact polymer bushing with inner control shield. In the bushing, a high electric stress occurred between field shaper and central conductor by the closely space. Also coaxial cylindrical shield has a great height along the axis to control an electric field. Consequently, all the potentials are raised axially along the field shaper and electric stress is concentrated on a part of the surface of the FRP tube near the upper end of the field shaper. In accordance, the field control can be achieved by means of the designs of such inner control shields. The floating and ring shield designs was decreased electric field concentration at critical parts of the bushing. The shield gaps is formed between field shaper and ring shield. Accordance equipotential lines extend through gaps. As a result, the resulting electrical stress are thus reduced in the range $17{\sim}23%$ in the bushing with floating and ring shield designs. Maxwell 2D simulator based on the boundary element method was also introduced in order to verify the reliability of the polymer bushing. The optimized design uses internal elements for electric stress grading at critical parts of the bushing.