• Bulletin of the Korean Chemical Society
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• v.29 no.2
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• pp.319-322
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• 2008

The viability of acetylene addition in each step of aromatic formation initiated by vinyl radical and acetylene also with its competition with structure rearrangement is investigated by determining optimal geometries and barrier and reaction energies using quantum mechanical methods. In principle, the addition reaction has more difficult in term of free energy and enthalpy compared to geometry arrangement. Under combustion conditions, i.e. T = 1200 K, acetylene addition is unfavorable mechanism as the barrier energy values rise much higher than that of geometry arrangement. However, in longer chain hydrocarbon case, e.g. n-CxHx+1 where x ³ 8, C-C bond rotation is rather difficult and requires high energy to form a ring structure, elongation chain is preferable.

• Bulletin of the Korean Chemical Society
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• v.13 no.6
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• pp.659-662
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• 1992

The pressure-jump relaxation method has been used to determine the rate constants for the formation and dissociation of maganese(Ⅱ), cobalt(Ⅱ), and nickel(Ⅱ) with some dicarboxylates in aqueous solution at zero ionic strength. The carboxylate ligands used are 3-nitrophthalate, 4-nitrophthalate, and phenylmalonate. The activation parameters have alse been obtained from the temperature dependence of the rate constants. A dissociative interchange mechanism with a chelate ring closure step as rate determining is employed to interpret the kinetic data of manganese(Ⅱ) and cobalt(Ⅱ) complexes. The rates of formation of nickel(Ⅱ) complexes are controlled by both the solvent exchange step and the chelate ring closure step.

• YAKHAK HOEJI
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• v.38 no.5
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• pp.504-510
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• 1994

A facile synthesis of 2-aryl-5-benzoxazolepropionic acid derivatives(1 0a-d), which are potent antiinflammatory agent, is reported. Methyl ${\alpha}$-(p-hydroxyphenyl)propionate(5) was prepared from Friedel-Crafts reaction of isopropoxy benzene with methyl ${\alpha}$-chloro-${\alpha}$-(methylthio) acetate(1), followed by desulfurization, methylation and clevage of ether bond. Compounds(10a-d) were made from(5) by a sequence of nitration, reduction, formation of benzoxazole ring, and hydrolysis in good yields, respectively.

• Proceedings of the Korean Fiber Society Conference
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• 2002.04a
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• pp.251-254
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• 2002

Poly(ethylene 2,6-naphtalenen dicarboxylate)(PEN)에 관한 연구는 1948년 Cook 등에 의해 처음으로 PET의 benzene ring을 naphthalene ring으로 대체하는 새로운 합성방법이 보고되었다[1]. 그 역사는 비교적 오래 되었지만 1980년대까지 PEN의 구조에 관한 연구는 거의 이루어지지 않았다. 그러나 1980년대 후반이 되면서 소위 "high performance polymers"에 관한 관심의 증가로 매우 좋은 기계적 물성과 열 안정성을 가지고 있는 PEN은 매우 중요한 소재로 인식되었다[2]. (중략)

• Journal of the Korean Chemical Society
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• v.16 no.3
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• pp.189-192
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• 1972

2, 6-Disubstituted-3-pyridazinones were synthesized from the reaction of trichloroethylideneacetophenone with substituted phenylhydrazines. Trichloroethylideneacetophenone 2, 4-dinitrophenylhydrazone was isolated from the reaction of trichloroethylideneacetophenone with 2, 4-dinitrophenylhydrazine and it gave 2-(2, 4-dinitrophenyl)-6-phenyl-3-pyridazinone through ring closure. This indicates that pyridazinones are produced through hydrazone formation and ring closure as suggested previously. The effect of substituents of phenylhydrazine on the reaction was also discussed.

• Bulletin of the Korean Chemical Society
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• v.8 no.3
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• pp.206-211
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• 1987

The photoreaction of 5,7-dimethoxycoumarin with adenosine has been carried out in a dry film state. The mixture of DMC and adenosine was irradiated with 350 nm UV light and two major products were isolated. The structure was determined by various spectroscopic measurements involving $^{13}C$ nuclear magnetic resonance and fast atom bombardment mass spectrometry. These addition products were produced by covalent bond formation between the pyrone ring at carbon 3 or 4 and the sugar ring moiety of adenosine at carbon 5'.

• Bulletin of the Korean Chemical Society
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• v.13 no.3
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• pp.290-296
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• 1992

Four plausible precursors (21, 22, 24, and 25), just prior to formation of the oxathiazepine ring in eudistomin, were synthesized by the Pictet-Spengler condensation of N-hydroxytryptamine (15) or N-hydroxytryptophan ester (19) with cysteinal derivatives (5 and 10). In the case of the parent compound (21), one of these four precursors, treatment with dihalomethane in the presence of a phase transfer catalyst gave an eudistomin analogue (26) having the oxathiazepine ring in 35-50% yield.

• Kyungpook Mathematical Journal
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• v.63 no.4
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• pp.521-537
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• 2023

A module M is called a simple-direct-injective module if, whenever A and B are simple submodules of M with A ≅ B and B is a direct summand of M, then A is a direct summand of M. Some new characterizations of these modules are proved. The structure of simple-direct-injective modules over a commutative Dedekind domain is fully determined. Also, some relevant counterexamples are indicated to show that a left simple-direct-injective ring need not be right simple-direct-injective.

• Bulletin of the Korean Chemical Society
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• v.15 no.8
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• pp.680-684
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• 1994

Pilocarpine analogs were prepared by empoying a radical cyclization reaction as a key step for the five-membered ring formation.

• Journal of the Korean Chemical Society
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• v.32 no.6
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• pp.528-535
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• 1988

The rates of oxygen ring formation of $[Mo_2O_3(Ox)_2(OxH)_2(NCS)_2]$ have been investigated spectrophotometric method in binary aqueous mixtures. Temperature was $20^{\circ}C$ to $40^{\circ}C$ and pressure was varied up to 1500 bar. The observed rate constants are increased by hydrogen ion and decreased by thiocyanate. The more increasing of co-solvents dielectric constant, the more stable intermediate is formed. The observed rate constant is given by, $k_{obs}^{-1} = k^{-1} (1 + K^{-1}[H_2O]^{-1}) All activation parameters are positive values. The oxygen ring formation of [Mo_2O_3(Ox)_2(OxH)_2(NCS)_2]$ is believed to be a interchange-dissociative mechanism..