• Restorative Dentistry and Endodontics
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• v.34 no.5
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• pp.450-459
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• 2009

The aim of this study was to measure the initial dynamic modulus changes of light cured composites using a custom made rheometer. The custom made rheometer consisted of 3 parts: (1) a measurement unit of parallel plates made of glass rods, (2) an oscillating shear strain generator with a DC motor and a crank mechanism, (3) a stress measurement device using an electromagnetic torque sensor. This instrument could measure a maximum torque of 2Ncm, and the switch of the light-curing unit was synchronized with the rheometer. Six commercial composite resins [Z-100 (Z1), Z-250 (Z2), Z-350 (Z3), DenFil (DF), Tetric Ceram (TC), and Clearfil AP-X (CF)] were investigated. A dynamic oscillating shear test was undertaken with the rheometer. A certain volume ($14.2\;mm^3$) of composite was loaded between the parallel plates, which were made of glass rods (3 mm in diameter). An oscillating shear strain with a frequency of 6 Hz and amplitude of 0.00579 rad was applied to the specimen and the resultant stress was measured. Data acquisition started simultaneously with light curing, and the changes in visco-elasticity of composites were recorded for 10 seconds. The measurements were repeated 5 times for each composite at $25{\pm}0.5^{\circ}C$. Complex shear modulus G*, storage shear modulus G', loss shear modulus G" were calculated from the measured strain-stress curves. Time to reach the complex modulus G* of 10 MPa was determined. The G* and time to reach the G* of 10 MPa of composites were analyzed with One-way ANOVA and Tukey's test ($\alpha$ = 0.05). The results were as follows. 1. The custom made rheometer in this study reliably measured the initial visco-elastic modulus changes of composites during 10 seconds of light curing. 2. In all composites, the development of complex shear modulus G* had a latent period for $1{\sim}2$ seconds immediately after the start of light curing, and then increased rapidly during 10 seconds. 3. In all composites, the storage shear modulus G" increased steeper than the loss shear modulus G" during 10 seconds of light curing. 4. The complex shear modulus of Z1 was the highest, followed by CF, Z2, Z3, TC and DF the lowest. 5. Z1 was the fastest and DF was the slowest in the time to reach the complex shear modulus of 10 MPa.

• Korean journal of food and cookery science
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• v.3 no.1
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• pp.64-70
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• 1987

The effects of salting on the compositional and textural changes of Korean cabbage were studied. The optimum brining conditions were established ana the dietary fiber composition, mineral contents and moisture content of raw and salted Korean cabbage were determined. The cutting test of cabbage was made by Rheometer and the brittleness and chewiness were evaluated organoleptically. The optimum condition for brining was at 20% NaCl concentration for 6 hours. In the compositional changes of Korean cabbage by salting at 20% NaCl solution for one month, the content of hot water soluble pectin (HW-P) increased from 43.6% to 55.9% and that of hexametaphosphate soluble pectin (HM-P) decreased from 35.9% to 29.5%. The contents of cellulose and hemicellulose increased, but that of lignin decreased slightly by salting, showing no significant differences in raw and salted cabbage. The content of Na increased significantly and those of Ca, Mg and K decreased by salting. And also moisture content decreased from 91% to 79%. In the textural changes of Korean cabbage by salting, the maximum cutting force and cutting work increased five times and two and half times respectively. And organoleptic test did show significant increase in chewiness and decrease in brittleness. The maximum cutting force by Rheometer was well correlated with the sensory parameters. The results taken together showed that the changes in textural properties during salting are relevant to the changes in pectic substances, moisture content and mineral contents, but relatively irrelevant to the changes in cellulose, hemi-cellulose ana lignin. And it is considered that the maximum cutting force by cutting test is good means for the expression of texture of Korean cabbage.

• Restorative Dentistry and Endodontics
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• v.36 no.5
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• pp.377-384
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• 2011

Objectives: The purpose of this study was to observe the change in the viscoelastic properties of thermoplasticized injectable root canal filling materials as a function of temperature and to compare the handling characteristics of these materials. Materials and Methods: Three commercial gutta perchas and Resilon (Pentron Clinical Technologies) in a pellet form were heated in the Obtura-II system (Obtura Spartan) at $140^{\circ}C$ and $200^{\circ}C$, and the extrusion temperature of the thermoplasticized materials was measured. The viscoelastic properties of the materials as a function of temperature were evaluated using a rheometer. The elastic modulus G', viscous modulus G", loss tangent tan${\delta}$, and complex viscosity ${\eta}^*$ were determined. The phase transition temperature was determined by both the rheometer and a differential scanning calorimeter (DSC). The consistency of the materials was compared under compacting pressure at $60^{\circ}C$ and $40^{\circ}C$ by a squeeze test. Results: The three gutta perchas had dissimilar profiles in viscoelastic properties with varying temperature. The phase transition of softened materials into solidification occurred at $40^{\circ}C$ to $50^{\circ}C$, and the onset temperatures obtained by a rheometer and a DSC were similar to each other. The onset temperature of phase transition and the consistency upon compaction pressure were different among the materials (p < 0.05). Resilon had a rheologically similar pattern to the gutta perchas, and was featured between high and low-flow gutta perchas. Conclusions: The rheological characteristics of the thermoplasticized root canal filling materials changed under a cooling process. The dissimilar viscoelastic properties among the materials require different handling characteristics during an injecting and compacting procedure.

• Proceedings of the Korean Society of Rheology Conference
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• 2002.11a
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• pp.23-26
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• 2002

No Abstract, See Full Text

• Proceedings of the Acoustical Society of Korea Conference
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• autumn
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• pp.265-268
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• 1999

감쇠가 큰 고분자 복합재료에서 초음파 다중반사파를 이용한 Pulse Echo법, 공진주파수에서 내부마찰계수 측정법과 Rheometer를 이용한 동적탄성계수 측정법을 사용하여 음향감쇠계수를 측정하고 각각의 측정자료를 비교하는 연구를 수행하였다. Pulse Echo법을 이용하여 0.5, 1.0, 2.25MHz에서 음향감쇠계수를 측정하였고, 이때 폴리에틸렌기지 복합재료의 음향감쇠계수는 강화재의 부피분율에 따라 3-15dB/cm 정도로 큰 값을 나타내었다. 폴리에틸렌기지 복합재료를 600kHz 근처에서 공진주파수를 가지도록 시편을 만든 후에 내부마찰계수를 측정한 결과로 계산된 음향감쇠계수는 Pulse Echo 실험에서 구한 값과 잘 일치하는 결과를 얻을 수 있었다. Rheometer를 이용한 동적탄성계수 측정법은 0.1-100Hz의 주파수에서 측정한 자료를 TTSP 이론을 이용하여 1MHz의 결과와 비교하였는데, 단일 고분자 재료에서는 다른 측정방법과 음향감쇠계수가 일치하였지만 복합재료에서는 음향감쇠계수값이 일치하지 않는 결과를 나타내었다.

• Elastomers and Composites
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• v.52 no.3
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• pp.187-193
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• 2017

In this study, the effect of the cure, mechanical properties, and oil resistance of NBR (acrylonitrile-butadiene rubber)/peroxide compounds were investigated for various co-agents. NBR compounds were characterized using a swelling test, a rheometer (MDR), and a compression set test. Mechanical properties were tested with original compounds, heated in air and exposed to the ASTM No.1, IRM 903 oil. NBR compounds were prepared using peroxide as the crosslinking agent. Trimethylolpropane trimethacrylate (TMPTMA), triallyl isocyanurate (TAIC), and 1,2-polybutadiene (HVPBD) were used as co-agents. The NBR compounds containing TMPTMA and HVPBD lowered the scorch time, while the addition of TAIC did not significantly change the scorch time. NBR compounds containing TMPTMA increased the crosslinking density, while the addition of TAIC and HVPBD lowered the crosslinking density. Moreover, the addition of TMPTMA improved the oil resistance of the NBR compound.

• Journal of Sericultural and Entomological Science
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• v.43 no.1
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• pp.21-25
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• 2001

Jeung-pyun added to mulberry leaves powder was tested to prove in inorganic ingredients, physical function, chromaticity and rheometer. For cake, mulberry leaves powder were added to rice flour in the ratio of 0%, 1%, 2%, and 3% respectively. In inorganic ingredients test, the amounts of calcium, magnesium and potassium were increased according to adding levels of mulberry leaves powder. But the amounts of iron, copper and zinc, were not correlated with it. Calcium, magnesium and potassium are anti-hypertension inorganic substances. Thus, it is considered that food with plenty amountsz of inorganic ingredients is an effective diet for the patients who suffer from cardiovascular disease. In physical evalution test, the ratio of mulberry leaves powder was not correlated with the appearance of Jeung-pyun. The value of color decreased as the ratio of mulberry leaves powder increases. In texture, Jeung-pyun. The value of color decreased as the ratio of mulberry leaves power increase. In texture, Jeung-pyun added with 2% mulberry leaves powder had the highest value. In moisture, as the level of mulberry leaves powder was increased, the value was decreased. In rheometer test, Jeung-pyun 0% mulberry leaves powder had the highest value in hardness. While the ratio of mulberry leaves powder was not correlated with cohesiveness. Jeung-pyun added to 1% mulberry leaves powder had the highest value. In gummines and brittleness, 0% Jeung-pyun had the highest value, but the ratio was not correlate with cohesiveness.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.5
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• pp.2511-2515
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• 2013

Carbon black from pyrolysis of waste tires was used to modify and improve the fatigue properties and low temperature cracking of asphalt binder. 0%, 5%, 10%, 15% and 20% of pyrolyzed carbon black was mixed. Couple of laboratory tests, such as dynamic shear rheometer test and bending beam rheometer test, were carried out. The use of pyrolyzed carbon black decreased the fatigue at room temperature and improved the resistance of low temperature cracking up to $-12^{\circ}C$, but, was off the criteria at $-18^{\circ}C$.

• Journal of the Korean Applied Science and Technology
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• v.32 no.3
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• pp.497-504
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• 2015

Apart from hydrates, asphaltenes, and inorganic minerals, paraffinic waxes are also very important in flow assurance area. Evaluation of wax gel behavior has been important as off-shore oil recovery becomes more popular in oil production. Restart after either planned or emergency shutdown requires pump operation in high pressure since a waxy oil forms troublesome gel. In this paper, vane method is introduced to determine wax gel strength by determining yield stress. Prediction of gel strength are discussed in qualitative and quantitative manners.

• Polymer(Korea)
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• v.33 no.5
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• pp.490-495
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• 2009

The reactive compatibilization of amorphous poly-${\alpha}$-olefins (APAO)/amorphous polyamide (aPA) blends was carried out using two kinds of reactive compatibilizers such as maleated polypropylene and ethylene-glycidyl methacrylate-methyl acrylate copolymer. The grafting reaction rates between aPA and the compatibilizers were examined using FT-IR, SEM and rheometer. The effect of the reactive compatibilization on the mechanical property of the blends was investigated with a universal testing machine. The adhesion strength of the blends including a hydrocarbon tackifier resin, C9 was also measured.