• Title/Summary/Keyword: Reversible system

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Semi-Circular Potential Sweep Voltammetry: Electrochemically Quasi-Reversible System

  • Park, Kyungsoon;Hwang, Seongpil
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.379-383
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    • 2020
  • The novel voltammetry using a semi-circular potential wave for quasi-reversible charge transfer system on electrode is theoretically investigated. Compared with conventional voltammetry based on linear sweep such as linear sweep voltammetry (LSV), semi-circular potential sweep voltammetry (SCV) may decrease the charging current outside the center of potential range and increase the faradaic current at the midpoint due to variable scan rate. In this paper, we investigate the system based on macroelectrode where simple 1 dimensional (1 D) diffusion system is valid with various charge transfer rate constant (k0). In order to observe the amplification at midpoint, voltammetric response with different midpoint ranging from -200 mV to 200 mV are studied. SCVs shows both the shift of peak potential and the amplification of peak current for quasi-reversible electrode reaction while only higher peak current is observed for reversible reaction. Moreover, the higher current at midpoint enable the amplification of current at low overpotential region which may assist the determination of onset potential as a figure-of-merit in electrocatalyst.

Verification of Kinetic Theoretical Prediction of Diffusion-influenced Reversible

  • Yang, Min O;Sin, Guk Jae
    • Bulletin of the Korean Chemical Society
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    • v.21 no.1
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    • pp.93-96
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    • 2000
  • A diffusion-influenced pseudo-first order reversible reaction A + B ⇔C + B is investigated by the molecular dynamics (MD) simulation method. Theoretical finding that the temporal evolution of reactants [conditional probabilities] in the reversible system can be expressed by the irreversible survival probability with an effective rate parameter is confirmed even in the presence of solvent particles. We carry out molecular dynamics simulations for both the irreversible and the reversible cases to evaluate the survival and the conditional probabilities for each cases. When the resultant irreversible survival probability is inserted into the proposed relation, the conditional probabilities given by the simulation are exactly reproduced.

A Decentralized and Non-reversible Traceability System for Storing Commodity Data

  • He, Xiaojian;Chen, Ximeng;Li, Kangzi
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.13 no.2
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    • pp.619-634
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    • 2019
  • In the field of traceability systems, researchers focus on applications in the agricultural food traceability and scanning commodities. The purposes of this paper, however, is to propose an efficient and reliable traceability system that can be applied to all kinds of commodities. Currently, most traceability systems store data in a central server, which is unreliable when the system is under attack or if the administrator tampers with the data for personal interests. Therefore, it is necessary to design a system that can eliminate these threats. In this paper, we propose a decentralized and non-reversible traceability system for storing commodity data. This system depends on blockchain technology, which organizes data in the form of chains without a central server. This chain-style storage mechanism can prevent malicious modifications. In addition, some strategies are adopted to reduce the storage pressure and response time when the system has stored all kinds of commodity data.

Reconstruction of Thermodynamics by the Concept of Available Energy (II) - Thermodynamics of Real World - (가용 에너지에 의한 열역학의 재구성 (II) - 실제세계 열역학 -)

  • Jung, Pyung-Suk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.12
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    • pp.1573-1581
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    • 2004
  • Thermodynamic principles are described with a new point of view. In present study, the interaction between two systems is focused instead of the behavior of a system in conventional thermodynamics. The state change of a system cannot occur by itself but it is the result of the interaction between systems. However, the interaction itself is also the result of another kind of interaction, the interaction between two interactions. To reconstruct thermodynamics with such a point of view, the reversible world is imagined, in which conservations and measurements are discussed. There exists a conserved quantity for each mode of reversible interaction. The conserved transferring quantity in the interaction between interactions is the effective work, which is supposed to be measurable and conserved in reversible world. Effective work is the primary concepts of energy. It is the key factor to explain measurements, energy conservation and energy dissipation. The concepts developed in reversible world are applied to the real world in which irreversible phenomena may occur. Irreversibility is the result of effective energy dissipation, in which effective work irreversibly changes into entropy. A quantitative relation between the disappearing effective work and the generated entropy is dissipation equation which is given by experiments. A special temperature scale to give a very simple type of the dissipation equation is the absolute temperature scale, which gives the conventional conservation of energy.

The study of isolation driver for Reversible Power Converter (가역전력변환기 구동의 절연에 관한 연구)

  • Chun, J.H.;Lee, H.W.;Taniguchi, Hatsunori
    • Proceedings of the KIEE Conference
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    • 2005.07b
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    • pp.1349-1351
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    • 2005
  • In this paper discusses isolation driver of single phase AC-DC reversible power converter The reversible power converter driven by binary combination at different transformer winding ratio by BCD code level. It has a advantage that constructs a control system simply and obtain load current of good quality with out filter circuit and free from noise or isolation for lower switching frequency. In this research, study on current type converter and inverter circuit that consist for possibility of AC-DC/BC-AC multi-level reversible converter.

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Availability of Energy and Reconstruction of Thermodynamics(I) Thermodydamics of the Reversible World (에너지의 가용성과 열역학의 재구성 (I) 가역세계 열역학)

  • 정평석;노승탁
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.5
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    • pp.1227-1236
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    • 1993
  • In conventional thermodynamics, energy is regarded as a physical quantity transferring from one system to another, but in present study, the real energy is regarded as a physical quantity coming out from one interaction and absorbing into another interaction between two systems. To reconstruct thermodynamics with such a point of view, available work is distinguished from half work in conventional work concepts, and a special space named reversible world is proposed in which every process is reversible and the only measurable quantity is available work and just the equality between the intensities of two systems can be verified. As results, thermodynamic laws are arranged into two principles in the reversible world-conservations of energy elements and conservation of available energy. It means the exsistences of state properties corresponding to transferring energy elements and the available work. The former are extensive properties and the later is named potential work which is a property of the composite system and a kind of mathematical distance. The conventional available energy (exergy) and internal energy can be explained as the special cases of potential work, and the conventional first law of thermodynamics can be derived from the principle of the conservation of available energy. With these new concepts, the description of thermodynamic processes is more comprehensive. The second law of thermodynamics is no longer needed in the reversible world.

A Hybrid Inference System for Efficiently Controlling Reversible Lane (가변 차로를 효율적으로 통제하기 위한 하이브리드 추론 시스템)

  • Kwon, Hee-Chul;Yoo, Jung-Sang
    • Journal of the Korea Society of Computer and Information
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    • v.17 no.11
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    • pp.19-26
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    • 2012
  • Reversible lanes in urban intersections is used to efficiently control vehicles, reduce traffic congestion and increase the capacity of a roadway. But by far traffic control systems in urban intersections are simple and manually operated by police officers. In this study, we present a hybrid algorithm that intelligently resolve the moving direction of reversible lanes to efficiently manage the flow of traffic at intersection. The proposed algorithm consists of three stages:(i) fuzzy inference method to get the efficiency of moving direction, (ii) a provisional decision whether to change the reversible lane to different direction, (iii) a final evaluation criterion for changing the directions of the reversible lanes. The fuzzy inference results of efficiency are shown by using matlab application.

Photoisomerization of Cellulose Derivatives Obtained from Homogeneous System (균질계에서 얻은 셀룰로오스 유도체의 광이성질화 현상 연구)

  • No, Young-Ran;Park, Keun-Ho;Lee, Soo
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.4
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    • pp.273-278
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    • 2000
  • Cellulose tosylate(CT) was prepared by reaction of cellulose with p- toluenesulfonylchloride in DMAc/LiCl homogeneous system. In order to study a reversible photoisomerization of disperse red 1(DR-1) attached on natural polymer, cellulose tosylate containing DR-1(DR-1/CT adduct) was prepared at $110^{\circ}C$ in DMAc, and the changes of UV/Vis spectra of its solutions and thick film were investigated by alternate irradiation technique. Form the UV/Vis spectra of DR-1/CT adduct dissolved in cosolvents, such as DMAc, DMAc/THF, DMAc/benzene, and DMAc/chloroform and irradiated with 360 nm and 450 nm ligths, we found out changes of UV/Vis spectra were reversible in all solvents systems and we found out changes of UV/Vis spectra were reversible at thick film, also.

Degradation Evaluation of 1Cr-lMo-0.25V Steel by Measuring Reversible Magnetic Permeability (가역 투자율 측정에 의한 1Cr-1Mo-0.25V 강의 열화도 평가)

  • Ryu, Kwon-Sang;Kim, Yong-Il;Nahm, Seung-Hoon;Yu, Kwang-Min;Cho, Youk;Son, De-Rac
    • Journal of the Korean Society for Nondestructive Testing
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    • v.20 no.5
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    • pp.445-450
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    • 2000
  • The integrity of the turbine rotors can be assessed by measuring reversible permeability and Vickers hardness of the aged rotors at service temperature. The measurement system of reversible permeability, which measured by applied alternating perturbing magnetic field, was constructed in order to evaluate material degradation, nondestructively. The test specimen was 1Cr-1Mo-0.25V steel used widely for turbine rotor material, and the specimens were prepared by the isothermal heat treatment at $630\;^{\circ}C$. The reversible permeability of the test materials were measured at room temperature. The peak interval of reversible permeability and Vickers hardness decreased with the increase of degradation. The degradation of test material may be determined nondestructively by the lineality of Vickers hardness and the peak interval of reversible permeability.

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Reversible Data Hiding based on QR Code for Binary Image (이진 이미지를 위한 QR 코드 기반의 가역적인 데이터 은닉)

  • Kim, Cheonshik
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.14 no.6
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    • pp.281-288
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    • 2014
  • QR code (abbreviated from Quick Response Code) is code system that is strong in against to apply image processing techniques (skew, warp, blur, and rotate) as QR codes can store several hundred times the amount of information carried by ordinary bar codes. For this reason, QR code is used in various fields, e.g., air ticket (boarding control system), food(vegetables, meat etc.) tracking system, contact lenses management, prescription management, patient wrist band (patient management) etc. In this paper, we proposed reversible data hiding for binary images. A reversible data hiding algorithm, which can recover the original image without any distortion from the marked (stego) image after the hidden data have been extracted, because it is possible to use various kinds of purposes. QR code can be used to generate by anyone so it can be easily used for crime. In order to prevent crimes related QR code, reversible data hiding can confirm if QR code is counterfeit or not as including authentication information. In this paper, we proved proposed method as experiments.