• Bulletin of the Korean Chemical Society
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• 제27권2호
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• pp.251-254
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• 2006

The formation of polyaniline (PANI) in the reverse micelles of poly(oxyethylene) nonylphenyl ether, $(NP5, H(CH_2)_9Ph(OC_2H_4)_5OH)$, was investigated by small-angle neutron scattering (SANS). The reverse micellar solution containing initiators in the inner part of reverse micelle was prepared with surfactant (NP5), water, cyclohexane and an initiator (ammonium persulfate (APS)). The core-shell sphere model containing smearing effect reveals that the polymerization occurs on the shell layer of the reverse micelles. Shell thickness averages varied from 48 $\AA$ to 109 $\AA$ with increases of monomer concentration.

• 한국재료학회지
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• 제22권6호
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• pp.298-302
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• 2012

Fe/$SiO_2$ core-shell type composite nanoparticles have been synthesized using a reverse micelle process combined with metal alkoxide hydrolysis and condensation. Nano-sized $SiO_2$ composite particles with a core-shell structure were prepared by arrested precipitation of Fe clusters in reverse micelles, followed by hydrolysis and condensation of organometallic precursors in micro-emulsion matrices. Microstructural and chemical analyses of Fe/$SiO_2$ core-shell type composite nanoparticles were carried out by TEM and EDS. The size of the particles and the thickness of the coating could be controlled by manipulating the relative rates of the hydrolysis and condensation reaction of TEOS within the micro-emulsion. The water/surfactant molar ratio influenced the Fe particle distribution of the core-shell composite particles, and the distribution of Fe particles was broadened as R increased. The particle size of Fe increased linearly with increasing $FeNO_3$ solution concentration. The average size of the cluster was found to depend on the micelle size, the nature of the solvent, and the concentration of the reagent. The average size of synthesized Fe/$SiO_2$ core-shell type composite nanoparticles was in a range of 10-30 nm and Fe particles were 1.5-7 nm in size. The effects of synthesis parameters, such as the molar ratio of water to TEOS and the molar ratio of water to surfactant, are discussed.

• 천문학논총
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• 제11권1호
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• pp.27-47
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• 1996

We have performed the high resolution computer simulation with 1D spherical hydrodynamic code in order to study the dynamical evolution of supernova ejecta interacting with a pre-existing fast wind structure. The fast wind structure has been calculated with $M_{in}=3{\times}10^{-6}M_{\odot}yr^{-1}$ and ${\upsilon}_{in}=1000km/sec$, which velocity is higher than the critical velocity relating to the initial radiative cooling. The fast wind becomes initially adiabatic. After a shell formation time of ${\sim}4000yrs$, the wind becomes radiative cooling at the shell zone, forming a thin dense radiative shell and an adiabatic wind bubble afterward. When supernova explodes in the wind center at 20,000yrs after the wind evolves, the supernova ejecta, which has a dense distribution of ${\rho}{\propto}r^{-n}$(here we have n = 9), interacts initially with, the understood wind zone, producing forward and reverse shocks. The reverse shock heats the supernova ejecta and its temperature increases. In this study, as the mass of the supernova ejecta is larger than that of the wind shell ($M_{ej}=5M_{\odot}$, $M_{sw}=2M_{\odot}$), we can conform two shell structures: an outer shell by the supernova ejecta and a secondarily shocked wind shell by it. The secondarily shocked wind shell should accelerates in this case to be R-T unstable, consequently producing the knots.

• 비파괴검사학회지
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• 제31권4호
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• pp.335-342
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• 2011

FBG (Fiber Bragg Grating) 변형률 센서를 이용하여 철골트러스 지붕의 변형을 계측하였다. 이는 특수한 형태인 콘크리트 역쉘 구조물의 시공 중 안정성을 평가하기 위함이었다. 구조해석을 통하여 FBG 센서의 설치위치를 결정하였으며, 센서를 통한 변형률 값을 구조해석 값과 비교하였다. 이를 통하여 특수 구조물의 시공 중 계측을 위한 사전계측 계획의 필요성을 확인 할 수 있었고, 측정된 변형률 값이 구조해석 값을 통한 허용범위 내에 있어, 대상 구조물은 안전한 것으로 판단되었다.

• 천문학논총
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• 제12권1호
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• pp.111-143
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• 1997

We have developed a spherical FCT code in order to simulate the interaction of supernova remnants with stellar wind bubbles. We assume that the density profile of the supernova ejecta follows the Chevalier mode1(1982) where the outer portion has a power-law density distribution($\rho{\propto}\gamma^{-n}$) and the SN ejecta has a kinetic energy of $10^{51}$ ergs. The structure of wind bubble has been calculated with the stellar mass loss rate $\dot{M}=5\times10^{-6}M_{\odot}/yr$ and the wind velocity $\upsilon=2\times10^3$ km/s We have simulated seven models with different initial conditions In the first two models we computed the evolution of SNRs with n=7 and n=14 in the uniform medium The numerical results agree with the Chevalier's similarity solution at early times. When all of the power-law portion of the ejecta is swept up by the reverse shock, the evolution slowly converges to the Sedov-Taylor stage. There is not much difference between the two cases with different n's The other five models simulate SNRs produced inside wind bubbles. In model III, we consider the SN ejecta of 1.4 $M_{\odot}$ and the radius of bubble ~2.76 pc so that ratio of the mass $\alpha(=M_{W.S}/M_{ej}$ is 2. We follow the complex hydrodynamic flows produced by the interaction of SN shocks with stellar shocks and with the contact discontinuities, In the model III, the time scale for the SN shock to cross the wind shell $\tau_{cross}$ is similar to the time scale for the reverse shock to sweep the power-law density profile $\tau_{bend}$. Hence the SN shock crosses the wind shell. At late times SN shock produces another shell in the ambient medium so that we have a SNR with double shell structure. From the numerical results of the remaining models, we have found that when $\tau_{cross}/\tau_{bend}\leq2$, or equivalently when $\alpha\leq50$, the SNRs produced inside wind bubbles have double shell structure. Otherwise, either the SN shock does not cross the wind shell or even if it crosses at one time, the reverse shock reflected at the center accelerates the wind shell to merge into the SN shock Our results confirm the conclusion of Tenorio-Tagle et a1(1990).

• 한국식품영양과학회지
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• 제28권6호
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• pp.1226-1229
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• 1999

In order to investigate the harvest time for the production of high value added ark shell(Scapharca subcrenata) cultured at the south coast of Korea, the seasonal variations of proximate composition(mois ture, protein, fat, ash and glycogen) in the edible portions of ark shell were measured from December 1994 to December 1995. Moisture contents were the lowest in spring, but the highest in summer season being the spawning season of the S. subcrenata. The other hand, protein contents were a maximum in spring and minimum in summer. In June, just before the spawning season, fat and glycogen content was the highest, and ash content was little changed through a year. After spawning season, glycogen contents, showed decrement. In evaluating the seasonal variation of protein, moisture, and glycogen content in ark shell, the relationships of moisture protein content, moisture glycogen content and glycogen protein content show to be reverse.

• 소성∙가공
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• 제3권4호
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• pp.440-453
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• 1994

The multi-stage deep-drawing processes including normal-drawing, reverse-drawing, and re-drawing are analyzed by use of the rigid-plastic finite element method. Computational results on the punch/die loads and thickness distributions were compared with the experiments of the current drawing processes. Deep-drawing processes of the redesigned shell to improve the specific strength and stiffness were simulated with the numerical method developed. With varying several process parameters such as blank size, corner radii of tools, and clearances, the simulation results showed the improvements in reducing the forming loads. Also forming defects were found during simulation and appropriate blank size could be verified.

• 한국세라믹학회지
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• 제45권9호
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• pp.512-517
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• 2008

In this study, yttrium-doped $SiO_2$ nanoparticles are synthesized using a reverse micelle technique combined with metal alkoxide hydrolysis and condensation. Spherical Y-doped $SiO_2$ nanoparticles with a uniform size distribution are prepared using selfassembly molecules in conjunction with the hydrolysis and condensation of organometallic precursors. The water/surfactant molar ratio influenced the Y-doped $SiO_2$ particles distribution of the core-shell composite particles and the distribution of Y doped $SiO_2$ particles was broadened as the water to surfactant ratio increased. The particle size of Y increase linearly as the $Y(NO_3)_3$ solution concentration increased. The average size of the cluster was found to depend on the micelle size, the nature of the solvent, and the concentration of the reagent. The effects of synthesis parameters, such as the molar ratio of water to surfactant and the molar ratio of water to TEOS, are discussed.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2000년도 추계총회,초청강연,특별강연,연구발표회
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• pp.85.2-85
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• 2000

• Smart Structures and Systems
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• 제30권2호
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• pp.121-133
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• 2022

An analytical approach for the free vibration behavior of a sandwich cylindrical shell with a functionally graded (FG) core is presented. It is considered that the FG distribution is in the direction of thickness. The material properties are temperature-dependent. The sandwich cylindrical shell with a FG core is considered with two cases. In the first model, i.e., Ceramic-FGM-Metal (CFM), the interior layer of the cylindrical shell is rich metal while the exterior layer is rich ceramic and the FG material is located between two layers and for the second model i.e., Metal-FGM-Ceramic (MFC), the material distribution is in reverse order. This study develops Carrera's Unified Formulation (CUF) to analyze sandwich cylindrical shell with an FG core for the first time. Considering the Principle of Virtual Displacements (PVDs) according to the CUF, the dependent boundary conditions and governing equations are obtained. The coupled governing equations are derived using Galerkin's method. In order to validate the present results, comparisons are made with the available solutions in the previous researches. The effects of different geometrical and material parameters on the free vibration behavior of a sandwich cylindrical shell with an FG core are examined.