• Title/Summary/Keyword: Reverse Shell

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SANS Studies on the Formation of PANI Nanoparticles in the Reverse Micelles

  • Sim, Jae-Hyun;Kim, Myung-woong;Park, Sang-wook;Bang, Jeong-Hwa;Sohn, Dae-won
    • Bulletin of the Korean Chemical Society
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    • v.27 no.2
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    • pp.251-254
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    • 2006
  • The formation of polyaniline (PANI) in the reverse micelles of poly(oxyethylene) nonylphenyl ether, $(NP5, H(CH_2)_9Ph(OC_2H_4)_5OH)$, was investigated by small-angle neutron scattering (SANS). The reverse micellar solution containing initiators in the inner part of reverse micelle was prepared with surfactant (NP5), water, cyclohexane and an initiator (ammonium persulfate (APS)). The core-shell sphere model containing smearing effect reveals that the polymerization occurs on the shell layer of the reverse micelles. Shell thickness averages varied from 48 $\AA$ to 109 $\AA$ with increases of monomer concentration.

Synthesis of Fe/SiO2 Core-Shell Nanoparticles by a Reverse Micelle and Sol-Gel Processes

  • Son, Jeong-Hun;Bae, Dong-Sik
    • Korean Journal of Materials Research
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    • v.22 no.6
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    • pp.298-302
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    • 2012
  • Fe/$SiO_2$ core-shell type composite nanoparticles have been synthesized using a reverse micelle process combined with metal alkoxide hydrolysis and condensation. Nano-sized $SiO_2$ composite particles with a core-shell structure were prepared by arrested precipitation of Fe clusters in reverse micelles, followed by hydrolysis and condensation of organometallic precursors in micro-emulsion matrices. Microstructural and chemical analyses of Fe/$SiO_2$ core-shell type composite nanoparticles were carried out by TEM and EDS. The size of the particles and the thickness of the coating could be controlled by manipulating the relative rates of the hydrolysis and condensation reaction of TEOS within the micro-emulsion. The water/surfactant molar ratio influenced the Fe particle distribution of the core-shell composite particles, and the distribution of Fe particles was broadened as R increased. The particle size of Fe increased linearly with increasing $FeNO_3$ solution concentration. The average size of the cluster was found to depend on the micelle size, the nature of the solvent, and the concentration of the reagent. The average size of synthesized Fe/$SiO_2$ core-shell type composite nanoparticles was in a range of 10-30 nm and Fe particles were 1.5-7 nm in size. The effects of synthesis parameters, such as the molar ratio of water to TEOS and the molar ratio of water to surfactant, are discussed.

DYNAMICAL INTERACTION OF SUPERNOVA REMNANT WITH PRE-EXISTING WIND BUBBLE (항성풍 거품 내에서의 초신성 잔해의 동역학적 구조)

  • Choi, Seung-Eon;Cha, Seung-Hun;Gu, Bon-Cheol
    • Publications of The Korean Astronomical Society
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    • v.11 no.1
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    • pp.27-47
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    • 1996
  • We have performed the high resolution computer simulation with 1D spherical hydrodynamic code in order to study the dynamical evolution of supernova ejecta interacting with a pre-existing fast wind structure. The fast wind structure has been calculated with $M_{in}=3{\times}10^{-6}M_{\odot}yr^{-1}$ and ${\upsilon}_{in}=1000km/sec$, which velocity is higher than the critical velocity relating to the initial radiative cooling. The fast wind becomes initially adiabatic. After a shell formation time of ${\sim}4000yrs$, the wind becomes radiative cooling at the shell zone, forming a thin dense radiative shell and an adiabatic wind bubble afterward. When supernova explodes in the wind center at 20,000yrs after the wind evolves, the supernova ejecta, which has a dense distribution of ${\rho}{\propto}r^{-n}$(here we have n = 9), interacts initially with, the understood wind zone, producing forward and reverse shocks. The reverse shock heats the supernova ejecta and its temperature increases. In this study, as the mass of the supernova ejecta is larger than that of the wind shell ($M_{ej}=5M_{\odot}$, $M_{sw}=2M_{\odot}$), we can conform two shell structures: an outer shell by the supernova ejecta and a secondarily shocked wind shell by it. The secondarily shocked wind shell should accelerates in this case to be R-T unstable, consequently producing the knots.

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Strain Measurement of Steel Roof Truss Using FBG Sensor during Construction of Reverse Shell Shaped Reinforced Concrete Structure (FBG 센서를 이용한 철근 콘크리트 역쉘구조물의 시공 중 건전성 관리를 위한 지붕철골트러스 변형률 계측)

  • Lee, Kun-Woo;Rhim, Hong-Chul;Seo, Tae-Seok
    • Journal of the Korean Society for Nondestructive Testing
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    • v.31 no.4
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    • pp.335-342
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    • 2011
  • Application of FBG (Fiber Bragg Grating) sensors to measure strain of steel roof trusses has been performed. This is to check and confirm the structural integrity of an unusually shaped, reverse shell structure made of reinforced concrete. The issue was to place sensors at proper location and compare the measured values to the results from structural analysis. It has been learned that a deliberate measurement scheme is needed in order to monitor a complex structure during construction. In this study, the measured values were within allowable range of strain, thus confirming the safety of the structure during measurement and construction.

INTERACTION OF SUPERNOVA REMNANTS WITH STELLAR-WIND BUBBLES (초신성 잔해와 항성풍 공동간의 상호 작용)

  • Lee, Jae-Kwan;Koo, Bon-Chul
    • Publications of The Korean Astronomical Society
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    • v.12 no.1
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    • pp.111-143
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    • 1997
  • We have developed a spherical FCT code in order to simulate the interaction of supernova remnants with stellar wind bubbles. We assume that the density profile of the supernova ejecta follows the Chevalier mode1(1982) where the outer portion has a power-law density distribution($\rho{\propto}\gamma^{-n}$) and the SN ejecta has a kinetic energy of $10^{51}$ ergs. The structure of wind bubble has been calculated with the stellar mass loss rate $\dot{M}=5\times10^{-6}M_{\odot}/yr$ and the wind velocity $\upsilon=2\times10^3$ km/s We have simulated seven models with different initial conditions In the first two models we computed the evolution of SNRs with n=7 and n=14 in the uniform medium The numerical results agree with the Chevalier's similarity solution at early times. When all of the power-law portion of the ejecta is swept up by the reverse shock, the evolution slowly converges to the Sedov-Taylor stage. There is not much difference between the two cases with different n's The other five models simulate SNRs produced inside wind bubbles. In model III, we consider the SN ejecta of 1.4 $M_{\odot}$ and the radius of bubble ~2.76 pc so that ratio of the mass $\alpha(=M_{W.S}/M_{ej}$ is 2. We follow the complex hydrodynamic flows produced by the interaction of SN shocks with stellar shocks and with the contact discontinuities, In the model III, the time scale for the SN shock to cross the wind shell $\tau_{cross}$ is similar to the time scale for the reverse shock to sweep the power-law density profile $\tau_{bend}$. Hence the SN shock crosses the wind shell. At late times SN shock produces another shell in the ambient medium so that we have a SNR with double shell structure. From the numerical results of the remaining models, we have found that when $\tau_{cross}/\tau_{bend}\leq2$, or equivalently when $\alpha\leq50$, the SNRs produced inside wind bubbles have double shell structure. Otherwise, either the SN shock does not cross the wind shell or even if it crosses at one time, the reverse shock reflected at the center accelerates the wind shell to merge into the SN shock Our results confirm the conclusion of Tenorio-Tagle et a1(1990).

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Seasonal Variation of Proximate Composition in Edible Portion or Ark Shell (Scapharca subcrenata) (새고막(Scapharca subcrenata) 가식부 일반성분의 계절변동)

  • 박춘규
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.28 no.6
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    • pp.1226-1229
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    • 1999
  • In order to investigate the harvest time for the production of high value added ark shell(Scapharca subcrenata) cultured at the south coast of Korea, the seasonal variations of proximate composition(mois ture, protein, fat, ash and glycogen) in the edible portions of ark shell were measured from December 1994 to December 1995. Moisture contents were the lowest in spring, but the highest in summer season being the spawning season of the S. subcrenata. The other hand, protein contents were a maximum in spring and minimum in summer. In June, just before the spawning season, fat and glycogen content was the highest, and ash content was little changed through a year. After spawning season, glycogen contents, showed decrement. In evaluating the seasonal variation of protein, moisture, and glycogen content in ark shell, the relationships of moisture protein content, moisture glycogen content and glycogen protein content show to be reverse.

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A Study on the Process Improvements of the Multi-stage Deep Drawing by the Rigid-plastic Finite Element Method (강소성 유한요소법을 이용한 다단계 디프드로잉의 공정개선에 관한 연구)

  • 전병희;민동균;김형종;김낙수
    • Transactions of Materials Processing
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    • v.3 no.4
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    • pp.440-453
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    • 1994
  • The multi-stage deep-drawing processes including normal-drawing, reverse-drawing, and re-drawing are analyzed by use of the rigid-plastic finite element method. Computational results on the punch/die loads and thickness distributions were compared with the experiments of the current drawing processes. Deep-drawing processes of the redesigned shell to improve the specific strength and stiffness were simulated with the numerical method developed. With varying several process parameters such as blank size, corner radii of tools, and clearances, the simulation results showed the improvements in reducing the forming loads. Also forming defects were found during simulation and appropriate blank size could be verified.

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Synthesis and Characterization of Yttrium-doped Core-Shell SiO2 Nanoparticles by Reverse Micelle and Sol-gel Processing

  • Kim, Jun-Seop;Chu, Min-Cheol;Cho, Seong-Jai;Bae, Dong-Sik
    • Journal of the Korean Ceramic Society
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    • v.45 no.9
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    • pp.512-517
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    • 2008
  • In this study, yttrium-doped $SiO_2$ nanoparticles are synthesized using a reverse micelle technique combined with metal alkoxide hydrolysis and condensation. Spherical Y-doped $SiO_2$ nanoparticles with a uniform size distribution are prepared using selfassembly molecules in conjunction with the hydrolysis and condensation of organometallic precursors. The water/surfactant molar ratio influenced the Y-doped $SiO_2$ particles distribution of the core-shell composite particles and the distribution of Y doped $SiO_2$ particles was broadened as the water to surfactant ratio increased. The particle size of Y increase linearly as the $Y(NO_3)_3$ solution concentration increased. The average size of the cluster was found to depend on the micelle size, the nature of the solvent, and the concentration of the reagent. The effects of synthesis parameters, such as the molar ratio of water to surfactant and the molar ratio of water to TEOS, are discussed.

Free vibration analysis of a sandwich cylindrical shell with an FG core based on the CUF

  • Foroutan, Kamran;Ahmadi, Habib;Carrera, Erasmo
    • Smart Structures and Systems
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    • v.30 no.2
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    • pp.121-133
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    • 2022
  • An analytical approach for the free vibration behavior of a sandwich cylindrical shell with a functionally graded (FG) core is presented. It is considered that the FG distribution is in the direction of thickness. The material properties are temperature-dependent. The sandwich cylindrical shell with a FG core is considered with two cases. In the first model, i.e., Ceramic-FGM-Metal (CFM), the interior layer of the cylindrical shell is rich metal while the exterior layer is rich ceramic and the FG material is located between two layers and for the second model i.e., Metal-FGM-Ceramic (MFC), the material distribution is in reverse order. This study develops Carrera's Unified Formulation (CUF) to analyze sandwich cylindrical shell with an FG core for the first time. Considering the Principle of Virtual Displacements (PVDs) according to the CUF, the dependent boundary conditions and governing equations are obtained. The coupled governing equations are derived using Galerkin's method. In order to validate the present results, comparisons are made with the available solutions in the previous researches. The effects of different geometrical and material parameters on the free vibration behavior of a sandwich cylindrical shell with an FG core are examined.