• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.16 no.1
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• pp.30-36
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• 2020

In SMART, the flow mixing header assembly (FMHA) is used to mix the coolant flowing into the reactor core to maintain a uniform temperature. The FMHA is designed to have enough stiffness so the resonance with reactor internal structures does not occurs during the pipe break and the seismic accidents. Since the gap between the FMHA and the core support barrel assembly is very narrow compared with the diameter of FMHA, the hydrodynamic mass effect acting on the FMHA is not negligible. Therefore the hydrodynamic mass characteristics on the FMHA are investigated to consider the fluid and structure interaction effects. The result of modal analysis for the dry and underwater conditions, the natural frequency of primary vibration mode for the horizontal direction is reduced from 136.67 Hz to 43.76 Hz. Also the result of frequency response spectrum seismic analysis for the dry and underwater conditions, the maximum equivalent stress are increased from 13.89 MPa to 40.23 MPa. Therefore, reactor internal structures located in underwater condition shall consider carefully the hydrodynamic mass effects even though they have sufficient stiffness required for performing its functions under the dry condition.

• BMB Reports
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• v.39 no.6
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• pp.774-781
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• 2006

Human nucleolar phosphoprotein p140 (hNopp140) is a nucleolar phosphoprotein that can bind to doxorubicin, an anti-cancer agent. We have examined the interaction between hNopp140 and doxorubicin as well as the folding property of hNopp140. Also, the effects of ATP and phosphorylation on the affinity of hNopp140 to doxorubicin are investigated by affinity dependent co-precipitation and surface plasmon resonance methods. Doxorubicin preferentially binds to un-phosphorylated form of hNopp140 with a $K_D$ value of $3.3\;{\times}\;10^{-7}$ M. Furthermore, doxorubicin reduces the protein kinase CK2-dependent phosphorylation of hNopp140, indicating that doxorubicin may perturb the cellular function of hNopp140 by reducing the protein kinase CK2-dependent phosphorylation of hNopp140. Low contents of the secondary structures of hNopp140 and the fast rate of proteolysis imply that hNopp140 has a high percentage of flexible regions or extended loop structures.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.26 no.4
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• pp.375-382
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• 2016

The mechanical property of a carbon-fiber-reinforced plastic (CFRP) is subjected to two elements, carbon fiber and polymer resin, in a first step and the selection of multi-layered structure is second one. Many combination of fabric layers, i.e. plainweave, twillweave, can be derived for candidates of test specimen used for a basic mechanical components so that a reliable identification of dynamic nature of possible multi-layered structures are essential during the development of CFRP based component system. In this paper, three kinds of multi-layered structure specimens were prepared and the dynamic characteristics of service specimens were conducted through classical modal test process with impact hammer. In addition, the design sensitivity analysis based on transmissibility function was applied for the measured response data so that the response sensitivity for each resonance frequency were compared for three CFRP test specimens. Finally, the evaluation of CFRP specimen over different multi-layered fabric structures are commented from the experimental consequences.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.211-211
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• 2011

Nanostructures, with a diversity of shapes, built on substrates have been developed within many research areas. Lithography is one powerful, but complex, technique to make structures at the nanometer scale, such as platinum nanowires for studying CO catalytic reactions [1], or aluminum nanodisks for studying the plasmon effect [2]. In this work, we approach a facile method to construct nanostructures using noble metals on a titania thin film by using self-assembled structures as a pattern. Here, a large-scale silica monolayer is transferred to the titania thin film substrates using a Langmuir-Blodgett trough, followed by the deposition of a thin transition metal layer. Owing to the hexagonal close-packed structure of the silica monolayer, we would obtain a metal nanostructure that includes separated metallic triangles (islands) after removing the patterning silica beads. This nanostructure can be employed to investigate the role of metal-oxide interfaces in CO catalytic reactions by changing the patterning silica particles with different sizes or by replacing the oxide support. The morphology and chemical composition of the structure can be characterized by scanning electron microscopy, atomic force microscopy and X-ray photoelectron spectroscopy. In addition, we modify these islands to a connected island structure by reducing the silica size of the patterning monolayer, which is utilized to generating hot electron flow based on the localized surface plasmon resonance effect of the metal nanostructures.

• The Bulletin of The Korean Astronomical Society
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• v.36 no.2
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• pp.94.2-94.2
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• 2011

Electron microbursts, energetic electron precipitation having duration less than 1 sec, have been thought to be generated by chorus wave and electron interactions. While the coincidence of chorus and microburst occurrence supports the wave-particle interaction theory, more crucial evidences have not been observed to explain the origin of microbursts. We propose the measurement of energy dispersion of microbursts could be an evidence supporting wave-particle theory. During chorus waves propagate along magnetic field, the resonance condition should be satisfied at different magnetic latitude for different energy electrons. If we observed electron microbursts at low altitude, the arrival time of different energy electrons should make unique dispersion structures. In order to observe such energy dispersion, we need a detector having fast time resolution and wide energy range. Our study is motivated from defining the time resolution and energy range of the detectors required to measure microburst energy dispersions. We performed test particles simulation to investigate how electrons interact with simple coherent waves like chorus waves. We compute a large number of electron's trajectories and successfully produce energy dispersion structures expected when microbursts are observed with 10 msec time resolution detectors at the altitude of 600 km. These results provide useful information in designing electron detectors for the future mission.

• Journal of the Korean Chemical Society
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• v.27 no.2
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• pp.117-126
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• 1983

$^13C$ and $^51V$ NMR spectroscopy have been used to study the solution structures of the vanadium (v) complexes formed by ethylenediaminetetraacetic acid (EDTA), trans-cyclohexanediaminetetraacetic acid (CDTA), 1,2-propylenediaminetetraacetic acid (PDTA), ethylenediaminediacetic acid (EDDA), 2-hydroxyethylethylenediaminetriacetic acid (HEDTA), diethylenetriaminepentacetic acid (DPTA), and nitrilotriacetic acid (NTA). All of the complexes probably have octahedral structures containiing cis-$VO_2$ core. The coordination of hydroxylethyl group is found to be less favored than that of acetate group. EDDA forms two isomers, ${\alpha}$-cis and ${\beta}$-cis. PDTA also forms two structural isomers due to the methyl group in the ligand.

• Bulletin of the Korean Chemical Society
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• v.29 no.2
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• pp.405-407
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• 2008

Functionalized SAB-15 samples by octadecyltrimethoxysilane (OTC) were studied by 13C magic angle spinning (MAS) cross polarization (CP) nuclear magnetic resonance (NMR) spectroscopy. In the SBA-15 sample fully functionalized by 3-aminopropyltrimethoxysilane (APS) and OTC in 1:1 molar ratio, octadecyl chains were observed to have, on average, more trans conformation than those in the SBA-15 samples fully modified by OTC only. Our results confirm that long chain molecules tend to organize themselves better in the co-presence of short chain molecules on the surface of mesoporous materials by packing of the different length chains in an interdigitized fashion even when the short chains are long enough to have three carbons and a functional group at the ends. In addition, our results indicate that solid-state 13C CP MAS NMR spectroscopy is a simple and non-destructive method to probe the molecular structures of the domains composed of long alkyl chains.

• Journal of the Korean Wood Science and Technology
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• v.36 no.2
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• pp.63-72
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• 2008

As a part of abating formaldehyde emission of urea-formaldehyde (UF) resin adhesive, this study was conducted to investigate chemical structures of UF resin adhesives with different formaldehyde/urea (F/U) mole ratios, using carbon-13 nuclear magnetic resonance ($^{13}C$-NMR) spectroscopy. UF resin adhesives were synthesized at four different F/U mole ratios such as 1.6, 1.4, 1.2, and 1.0 for the analysis. The analysis $^{13}C$-NMR spectroscopy showed that UF resin adhesives with higher F/U mole ratios (i.e., 1.6 and 1.4) had two distinctive peaks, indicating the presence of dimethylene ether linkages and methylene glycols, a dissolved form of free formaldehyde. But, these peaks were not detected at the UF resins with lower F/U mole ratios (i.e., 1.2 and 1.0). These chemical structures present at the UF resins with higher F/U mole ratios indicated that UF resin adhesive with higher F/U mole ratio had a greater contribution to the formaldehyde emission than that of lower F/U mole ratio. Uronic species were detected for all UF resins regardless of F/U mole ratios.

• Bulletin of the Korean Chemical Society
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• v.23 no.12
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• pp.1778-1784
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• 2002

Novel membrane lipids containing the unusual very long chain fatty $acid{\alpha}{\omega}-1316-dimethyloctacosanedioate$, dimethyl. Ester (DME C30) was isolated and purified from thermophilic anaerobic eubacterium, Thermoanaerobacter ethanolicus. Structures of the lipids containing the bifunctional fatty acyl components were proposed by various analyses such as $^1H,\;^{13}C,\;^{31}P$ nuclear magnetic resonance (NMR), Fourier transform infrared(FTIR) spectroscopy, gas chromatography/mass spectrometry (GC/MS) and fast atom bombardment mass spectrometry (FAB/MS). Combined with the GC/MS, $^1H,\;and\;^{13}C$NMR data, we confirmed that the head groups of the lipids contained the glycerol and/or glucosamine molecules. $^{31}P$ NMR spectrum also showed that the lipids contained phosphate in a phosphodiester linkage. The proposed structures of these novel lipid components were the ones in which two head groups were linked by the membrane spanning fatty acyl component(DME C30)and regular chain fatty acids on glycerol moiety of each head group.

• Smart Structures and Systems
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• v.8 no.2
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• pp.205-217
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• 2011

This article describes the research work involving the implementation of an Active Bracing System aimed at the modification of the initial dynamics of a laboratorial building structure to a new desired dynamics. By means of an adequate control force it is possible to assign an entirely new dynamics to a system by moving its natural frequencies and damping ratios to different values with the purpose of achieving a better overall structural response to external loads. In Civil Engineering applications, the most common procedures for controlling vibrations in structures include changing natural frequencies in order to avoid resonance phenomena and increasing the damping ratios of the critical vibration modes. In this study, the actual implementation of an active system is demonstrated, which is able to perform such modifications in a wide frequency range; to this end, a plane frame physical model with 4 degrees-of-freedom is used. The Active Bracing System developed is actuated by a linear motor controlled by an algorithm based on pole assignment strategy. The efficiency of this control system is verified experimentally by analyzing the control effect obtained with the modification of the initial dynamic parameters of the plane frame and observing the subsequent structural response.