• Title/Summary/Keyword: Resins

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Evaluation of the Performance and Formaldehyde Emission Level of Particleboards Bonded with Urea-Formaldehyde Resins (요소수지로 접착된 파티클보드의 포름알데히드 방산량과 성능평가)

  • Oh, Yong-Sung
    • Journal of the Korean Wood Science and Technology
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    • v.26 no.4
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    • pp.92-97
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    • 1998
  • Four urea-formaldehyde (UF) resins were synthesized as a particleboard (PB) binder with the four different initial formaldehyde/urea mole ratio and the final mole ratio of 1.15. The UF resins were characterized according to the standard method of resin adhesive analysis. PBs were manufactured using liquid UF resins at 5 minutes press time and 6% resin solids levels on an ovendry particle weight basis. A total of 20 PBs was fabricated for 5 panel replication per UF resin types. The panels were tested for physical strength properties per the procedure ASTM D 1037. The formaldehyde emission levels from the PBs bonded with the UF resins were tested according to 2-hour desiccator test method ASTM D 5582. There were no significant differences among UF resin types for internal bond strength of PBs. But there were significant differences among UF resin types for formaldehyde emission level of PBs. The results showed that the formaldehyde emission level was influenced by the UF resin types without reducing the adhesive performance.

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Flexural Modulus of Larch Boards Laminated by Adhesives with Reinforcing Material

  • Injeong LEE;Weontae OH
    • Journal of the Korean Wood Science and Technology
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    • v.51 no.1
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    • pp.14-22
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    • 2023
  • Economical use of larix (larch) boards (grade 3) in industries is lower than that of imported hardwood; thus, studies have been conducted toward performance improvement of larix boards. Herein, flexural modulus of larix board samples laminated with wood adhesives polyurethane resins, poly (vinyl acetate) resins, phenol-resorcinol-formaldehyde resins, melamine-formaldehyde resins, and urea-formaldehyde resins was compared with that of the samples bonded with adhesives reinforced with mesh-type basalt fibers. Moreover, the flexural moduli of the laminated samples bonded by mesh-type basalt fibers were compared with those of reinforced samples. The results showed that boards laminated with polyurethane and urea-formaldehyde resin adhesives had higher flexural modulus than those without the lamination. In particular, the increase in the flexural modulus was relatively significant for the 2- and 3-ply board structures laminated with polyurethane adhesives compared to those with reinforcement. The 3-ply board structure without reinforcement had the highest flexural modulus when the urea-formaldehyde resin adhesive was used.

Changes in physicochemical characteristics of cation exchange resins by high dose gamma irradiation

  • Seung Joo Lim;Wang Kyu Choi;Mansoo Choi
    • Nuclear Engineering and Technology
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    • v.56 no.5
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    • pp.1777-1780
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    • 2024
  • Chemical and thermal characteristics of cation exchange resins were examined after irradiation of gamma rays. The degradation of cation exchange resins was mainly observed at doses of up to 500 kGy, whereas the balance between degradation and cross-linking reactions was sustained at 700 kGy. While the carbon content decreased significantly up to a maximum dose of 500 kGy, it showed an increase at higher doses. Conversely, the oxygen content exhibited a decrease in contrast to the carbon content. The continuous reduction in sulfur content was attributed to the decomposition of sulfonic groups. Gamma-ray irradiation caused a decrease in the initiation temperature of sulfonic groups and PS-DVB, but unlike the chemical properties of cation exchange resins due to gamma-ray irradiation, the thermal properties of resins remained unaffected.

Tensile bond strength of four denture resins to porcelain teeth with different surface treatment

  • El-Sheikh, Mohamed;Powers, John
    • The Journal of Advanced Prosthodontics
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    • v.5 no.4
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    • pp.423-427
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    • 2013
  • PURPOSE. This study evaluated the bond strength between porcelain denture teeth (Bioblend 43D) and four different polymerized denture resins (Lucitone 199, Palapress, Acron MC, Triad) with and without a bonding agent and after four different types of surface treatment (polished, HF etched, sandblasted, air-abraded). MATERIALS AND METHODS. Central incisor porcelain denture teeth were divided into 32 groups of 5 each. Tensile bond strength (MPa) was determined using a testing machine at crosshead speed of 0.5 mm/min. Mean and standard deviation are listed. Data were analyzed by two-way ANOVA. Means were compared by Tukey-Kramer intervals at 0.05 significance level. RESULTS. All surface treatment increased bond strength compared to polished surface and the highest bond strength was found with Palapress resin with etched porcelain surface (8.1 MPa). Bonding agent improved the bond strength of all denture resins to porcelain teeth. Superior bonding was found with Palapress and air-abraded porcelain (39 MPa). CONCLUSION. Resins with different curing methods affect the bond strength of porcelain teeth to denture bases. Superior bonding was found with auto-polymerized resin (Palapress). Application of ceramic primer and bonding agent to porcelain teeth with and without surface treatment will improve the bond strength of all denture resins to porcelain teeth.

A Study on the Color Stability of Temporary Resins according to Polymerizing Methods and Staining (온성 방법에 따른 수종의 임시 수복용 레진의 착색시의 색 안정성에 관한 연구)

  • Park, Sung-Ho;Cho, In-Ho
    • Journal of Dental Rehabilitation and Applied Science
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    • v.16 no.1
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    • pp.1-11
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    • 2000
  • Dental temporary resin should have adequate strength and similar esthetics as natural teeth. Recently esthetics has become a high priority in clinical dentistry. Thus the evaluation of color stability of dental temporary resin has become an important part in dental research. The purpose of this study was to evaluate the difference in color stability of 3 resins($Snap^{(R)}$, Temporary bridge $resin^{(R)}$, Trim $II^{(R)}$) according to polymerizing methods and stainning. The resins were divided into groups by 2 types of polymerizing methods ( air or pressure and heat curing) The resins were dyed with coffee, chlorhexidine and artificial saliva and then the color stability was evaluated with a spectrophotometer(CM-503i, Minolta, Japan). The results were as follows ; 1. In the color stability according to polymerizing method, pressure and heat polymerizing method was higher than air polymerizing method. 2. The color stability according to staining fluid decreased in the order of I, II, III group, there was significant difference among the groups of staining fluid. 3. The color stability according to resins decreased in the order of $Snap^{(R)}$, Trim $II^{(R)}$, Temporary Bridge $resin^{(R)}$, The $Snap^{(R)}$ resin was highest color stability, there was significant difference among the 3 resins.

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EVALUATION OF FERROCYANIDE ANION EXCHANGE RESINS REGARDING THE UPTAKE OF Cs+ IONS AND THEIR REGENERATION

  • Won, Hui-Jun;Moon, Jei-Kwon;Jung, Chong-Hun;Chung, Won-Yang
    • Nuclear Engineering and Technology
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    • v.40 no.6
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    • pp.489-496
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    • 2008
  • Ferrocyanide-anion exchange resin was prepared and the prepared ion exchange resins were tested on the ability to uptake $Cs^+$ ion. The prepared ion exchange resins were resin-KCoFC, resin-KNiFC, and resin-KCuFC. The three tested ion exchange resins showed ion exchange selectivity on the $Cs^+$ ion of the surrogate soil decontamination solution, and resin-KCoFC showed the best $Cs^+$ ion uptake capability among the tested ion exchange resins. The ion exchange behaviors were explained well by the modified Dubinin-Polanyi equation. A regeneration feasibility study of the spent ion exchange resins was also performed by the successive application of hydrogen peroxide and hydrazine. The desorption of the $Cs^+$ ion from the ion exchange resin satisfied the electroneutrality condition in the oxidation step; the desorption of the $Fe^{2+}$ ion in the reduction step could also be reduced by adding the $K^+$ ion.

Management of Spent Ion-Exchange Resins From Nuclear Power Plant by Blending Method

  • Kamaruzaman, Nursaidatul Syafadillah;Kessel, David S.;Kim, Chang-Lak
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.1
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    • pp.65-82
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    • 2018
  • With the significant increase in spent ion-exchange resin generation, to meet the requirements of Waste Acceptance Criteria (WAC) of the Wolsong disposal facility in Korea, blending is considered as a method for enhancing disposal options for intermediate level waste from nuclear reactors. A mass balance formula approach was used to enable blending process with an appropriate mixing ratio. As a result, it is estimated around 44.3% of high activity spent resins can be blended with the overall volume of low activity spent resins at a 1:7.18 conservative blending ratio. In contrast, the reduction of high activity spent resins is considered a positive solution in reducing the amount of spent resins stored. In an economic study, the blending process has been proven to lower the disposal cost by 10% compared to current APR1400 treatment. Prior to commencing use of this blending method in Korea, coordinated discussion, and safety and health assessment should be undertaken to investigate the feasibility of fitting this blending method to national policy as a means of waste predisposal processing and management in the future.

A Study on the Flexural Capacity of Rectangular Section Wood Using Synthetic Resins (합성수지를 이용한 사각단면 목재의 휨 보강 성능에 관한 연구)

  • Park, Kwang-Seob;Kang, Pyeong-Doo;Ha, Jong-Han;Park, Sung-Moo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.6 s.58
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    • pp.106-114
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    • 2009
  • The basis principle of conservation about deterioration and corrosion of cultural assets building is the archetype maintenance, and should not make a factitious damage mistake by repair. Accordingly, conservation processing method using synthetic resins is embossed. The purpose of this paper is about flexural capacity of rectangular section wood using synthetic resins, the 11 specimens are manufactured and made an experiment about reinforcement length, ratio, material strength, direction of synthetic resins as variable. The results of this paper has shown that flexural reinforcement of wood by synthetic resins are efficient and found the possibility of using.

A STUDY ON THE DEGREE OF CONVERSION OF LIGHT CURING COMPOSITE RESIN ACCORDING TO THE DEPTH OF CURE AND LIGHT CURING TIME (수종 광중합 복합 레진의 중합 깊이와 광조사 시간에 따른 중합률에 관한 연구)

  • Kim, Kyung-Hyun;Kwon, Oh-Sung;Kim, Hyun-Gee;Baek, Kyu-Chul;Um, Chung-Moon;Kwon, Hyuk-Choon
    • Restorative Dentistry and Endodontics
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    • v.22 no.1
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    • pp.35-60
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    • 1997
  • Physical properties of composite resins such as strength, resistance to wear, discoloration, etc, depend on the degree of conversion of the resin components. The clinical behavior of restorative resins varies brand to brand. Part of this variation is associated with the filler and differences in the polymer matrix. The polymer matrix of resins may differ because the involved monomers are dissimilar and because of variation in the catalyst system. The purpose of this study was to evaluate the degree of conversion of the composite resins according to the depth of cure and light curing time. 7mm diameter cylindrical aluminum molds were filled with each of five different hybrid light curing composite resins(Z-100, Charisma, Herculite XRV, Prisma TPH, Veridonfil) on the thin resin films. The molds were 1mm, 2mm, 3mm, 4mm, and 5mm in depth to produce resin films of various heights. Each sample was given 20sec, 40sec, and 60sec illumination with a light source. The degree of conversion of carbon double bonds to single bonds in the resin films was examined by means of Fourier Transform Infrared Spectrometer. The results were obtained as follows; 1. There was difference in the degree of conversion among five light curing composite resins according to the depth of cure for 20sec, 40sec, and 60sec illumination with light source with statistical significance(P<0.05). 2. Five light curing composite resins show lower degree of conversion at surface of the resin than depth of 1mm. 3. The degree of conversion of five light curing composite resins was siginificantly reduced from the maximum for the resin film when the light passed through as little as 1mm of each composite. 4. The degree of conversion of five light curing composite resins decrease significantly at the depth of 4mm, and polymerization was not occured at the depth of 5mm except for Prisma TPH. 5. The degree of conversion of five light curing composite resins was increased with increased light curing time, and there was no significant differences in the degree of conversion above 4mm in Z-100, 3mm in Charisma, and at depth of 5mm in Herculite XRV and Veridonfil(P>0.05).

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RHEOLOGIC STUDY ON THE VISCOELASTIC PROPERTIES OF FLOWABLE AND CONDENSABLE RESIN COMPOSITES (유동성 및 응축성 복합레진의 점탄성에 관한 유변학적 연구)

  • Lee, In-Bog;Cho, Byeong-Hoon;Son, Ho-Hyun;Kwon, Hyuk-Choon;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.25 no.3
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    • pp.359-370
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    • 2000
  • The purpose of this investigation was to observe the viscoelastic properties of five commercial flowable(Aeliteflo, Flow it, Revolution, Tetric flow, Compoglass flow), three conventional hybrid(Z-100, Z-250, P-60) and two condensable(Synergy compact, SureFil) resin composites. A dynamic oscillatory shear test was done to evaluate the storage shear modulus (G'), loss shear modulus(G"), loss tangent(tan ${\delta}$) and complex viscosity(${\eta}^*$) of the resin composites as a function of frequency - dynamic frequency sweep test from 0.01 to 100 rad/s at $25^{\circ}C$ - by using Advanced Rheometric Expansion System(ARES). To investigate the effect on the viscosity of resin composites of filler volume fraction, the filler weight % and volume % were measured by means of Archimedes' principle using a pyknometer. The results were as follows 1. The complex viscosity ${\eta}^*$ of flowable resins was lower than that of hybrid resins and significant differences were observed between brands. The complex viscosity ${\eta}^*$ of condensable resins was higher than that of hybrid resins. The order of complex viscosity ${\eta}^*$ at ${\omega}$=10 rad/s was as follows, Surefil, Synergy compact, P-60, Z-250, Z-100, Aeliteflo, Tetric flow, Compoglass flow, Flow it, Revolution. The relative complex viscosity of flowable resins compared to Z-100 was 0.04~0.56 but Surefil was 30.4 times higher than that of Z-100. 2. The storage shear modulus G' and the loss shear modulus G" of flowable resins were lower than those of hybrid resins but those of condensable resins were higher. The patterns of the change of loss tangent, tan ${\delta}$, of resin composites with increasing frequency were significantly different between brands. The phase angles, ${\delta}$, ranged from $30.2{\sim}78.1^{\circ}$ at ${\omega}$=10 rad/s. 3. All composite resins represent pseudoplastic nature with increasing shear rate. 4. The complex shear modulus $G^*$ and the phase angle ${\delta}$ was represented by the frequency domain phasor form, $G^*({\omega})=G^*e^{i{\delta}}=G^*{\angle}{\delta}$. The locus of frequency domain phasor plots in a complex plane was a valuable method that represent the viscoelastic properties of composite resins. 5. There was no direct linear correlationship but a weak positive relation was observed between filler volume % or weight % and the viscosity of the resin composites.

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