Nuclear Engineering and Technology

Korean Nuclear Society (한국원자력학회)
권호 표지
DOI QR코드

DOI QR Code

EVALUATION OF FERROCYANIDE ANION EXCHANGE RESINS REGARDING THE UPTAKE OF Cs+ IONS AND THEIR REGENERATION

  • Published : 2008.10.31
Download PDF
⟨ Previous Next ⟩

Abstract

Ferrocyanide-anion exchange resin was prepared and the prepared ion exchange resins were tested on the ability to uptake $Cs^+$ ion. The prepared ion exchange resins were resin-KCoFC, resin-KNiFC, and resin-KCuFC. The three tested ion exchange resins showed ion exchange selectivity on the $Cs^+$ ion of the surrogate soil decontamination solution, and resin-KCoFC showed the best $Cs^+$ ion uptake capability among the tested ion exchange resins. The ion exchange behaviors were explained well by the modified Dubinin-Polanyi equation. A regeneration feasibility study of the spent ion exchange resins was also performed by the successive application of hydrogen peroxide and hydrazine. The desorption of the $Cs^+$ ion from the ion exchange resin satisfied the electroneutrality condition in the oxidation step; the desorption of the $Fe^{2+}$ ion in the reduction step could also be reduced by adding the $K^+$ ion.

Keywords

References

  1. Y. Inoue, H. Yamazaki and F. Kasuga, 'Studies on the Hydrous Titanium Oxide Ion Exchanger and Rate of the Isotopic Exchange of Sodium Ions between the Exchanger in the $Na^+$ Ion Form and Aqueous Solution', Bull. Chem. Soc., 68, 191 (1995) https://doi.org/10.1246/bcsj.68.191
  2. T. J. Tranter, R. S. Herbst, T. A. Todd, A. L. Olson and H. B. Eldredge, 'Application of a Second Order Kinetic Model for the Preliminary Design of an Adsorption bed System Using Ammonium Molybdophosphate Polyacrylonitrile for the Removal of $^{137}Cs$ from Acidic Nuclear Waste Solutions', Advances in Environmental Research, 7, 913 (2003) https://doi.org/10.1016/S1093-0191(02)00086-2
  3. J. K. Moon, E. H. Lee, Y. J. Han, B. C. Lee and H. T. Kim, 'Multi-component Ion Exchange Kinetics with PANKCoFC Composite Ion Exchanger', Korean J. Chem. Eng., 22, 1 (2005) https://doi.org/10.1007/BF02701454
  4. H. H. Someda, A. A. ElZahhar, M. K. Shehata and H. A. El-Nagger, 'Supporting of Some Ferrocyanides on Polyacrlonitrile (PAN) Binding Polymer and Their Application for Cesium Treatment', Separation and Purification Technology, 29, 1 (2002) https://doi.org/10.1016/S1383-5866(01)00157-5
  5. K. Watari, K. Imai, Y. Ohmomo, Y. Muramatsu, Y. Nishimura, M. Izawa and L. R. Baciles, 'Simultaneous Adsorption of Cs-137 and I-131 from Water and Milk on Metal Ferrocyanide-Anion Exchange Resin', J. Nucl. Sci. Techn. 25, 5 (1988)
  6. T. R. Folsom, N. Hansen, T. J. Tatum and V. F. Hodge, 'Recent Developments in Method for Concentrating and Analyzing Radiocesium in Sea Water', J. Radiation. Res., 16, 19 (1975) https://doi.org/10.1269/jrr.16.19
  7. D. R. Mann and S. A. Casso, 'In Situ Chemisorption of Radiocesium from Sea Water', Marine Chem., 14, 307 (1984) https://doi.org/10.1016/0304-4203(84)90027-6
  8. K. Tanihara, 'Method for the Preparation of an Ion Exchanger for Cesium Ions and Method for Regeneration Thereof', Patent No. US 5601722 (1997)
  9. Y. Onodera, H. Mimura, T. Iwasaki, H. Hayashi and T. Ebina, 'Biopolymer Composite Ion Exchanger with High Cesium Selectivity and Its Manufacturing Method', US Patent 6616860 B1 (2003)
  10. R. W. Peters, 'Chelant Extraction of Heavy Metals from Contaminated Soils', Journal of Hazardous Materials, 66, 1(1999) https://doi.org/10.1016/S0304-3894(98)00214-3
  11. P. K. A. Hong, C. Li, S. K. Banerji and Y. Wang, 'Feasibility of Metal Recovery from Soil Using DTPA and Its Biostability', Journal of Hazardous Materials, B 94, 253 (2002)
  12. M. S. Yang, J. H. Park, W. I. Ko, K. C. Song, K. M. Choi and J. K. Kim, 'Evaluation of Proliferation Resistance Using the INPRO Methodology', Nuclear Engineering and Technology, 39, 2 (2007) https://doi.org/10.5516/NET.2007.39.2.149
  13. J. S. Kim, Y. S. Jeon, S. D. Park, B. C. Song, S. H. Han and J. G. Kim, 'Dissolution of Irradiated U-Zr Alloy Nuclear Fuel by Chemical Methods', Nuclear Engineering and Technology, 38, 3 (2006)
  14. H. J. Won, B. G. Ahn, C. H. Jung, G. N. Kim and W. Z. Oh 'Fixation of - Radionuclides by the PVA-PMAA System', J. Korean Nuclear Society, 32, 3 (2000)
  15. D. M. Ruthven, 'Principles of Adsorption and Adsorption Process', John Wiey & SONS, New York (1994)
  16. S. M. Robinson, W. D. Arnold and C. W. Byers, 'Multicomponent Liquid Ion Exchange with Chabazaite Zeolites', ORNL/TM-12403, Oak Ridge National Laboratory (1993)
  17. J. K. Moon, C. H. Jung, E. H. Lee, H. T. Kim and Y. G. Shul, 'Preparation of PAN-Zeolite 4A Composite Ion Exchanger and Its Uptake Behavior for Sr and Cs Ions in Acid Solution', Korean J. Chem. Eng., 19, 5 (2002)
  18. S. D. Collyer, F. Davies, A. Lucke, C. J. M. Stirling and S. P. J. Higson, 'The Electrochemistry of the Ferri/ferrocyanide couple at a calix[4]resorcinarene- tetrathiol-modified Gold Electrode as a Study of Novel Electrode Modifying Coatings for Use within Electroanalytical Sensors', J. Electroanalytical Chemistry, 549, 119 (2003) https://doi.org/10.1016/S0022-0728(03)00270-5
  19. M. Pourbaix, 'Atlas of Electrochemical Equilbria in Aqueous Solutions', National Association of Corrosion Engineers, Houston, Texas, USA (1974)
  20. M. Ebadi, 'Electrocatalytic Oxidation and Flow Amperometric Detection of Hydrazine in a Dinuclear Ruthenium Phthalocyaninemodified Electrode', Can. J. Chem., 81, 2 (2003)
  21. H. J. Won, M. K. Kim, G. N. Kim, C. H, Jung, J. H. Park and W. Z. Oh, 'Treatment of Simulated Soil Decontamination Waste Solution by Ferrocyanide-Anion Exchange Resin Beads', J. Kor. Rad. Waste Soc., 3, 1 (2005)

Cited by

  1. Immobilization of Metal Hexacyanoferrate Ion-Exchangers for the Synthesis of Metal Ion Sorbents—A Mini-Review vol.20, pp.12, 2015, https://doi.org/10.3390/molecules201119718
  2. Investigations on sorption performance of some radionuclides, heavy metals and lanthanides using mesoporous adsorbent material vol.314, pp.3, 2017, https://doi.org/10.1007/s10967-017-5620-4
  3. Chitosan-ferrocyanide sorbents for concentrating Cs-137 from seawater vol.52, pp.12, 2017, https://doi.org/10.1080/01496395.2017.1321669