• 한국공작기계학회논문집
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• 제11권5호
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• pp.81-87
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• 2002

The existing compressor steel seal used in automotive air-conditioner has the problem of oil leakage and deterioration in shielding performance, due to the abrasion and corrosion of the material. A new type of polymer resin seal studied in this research has the characteristics of high anti-abrasiveness and anti-corrosiveness, which can oversome the defects of the steel seal. In addition, the seal needs lower manufacturing cost and is appropriate to mass production, because it is made by the injection molding method requiring no mechanical processing. The profile generation program for seal mold has been developed using the gradient method, and the molding characteristics of the seal have analyzed through the flow analysis and the warpage analysis. The program has been verified by comparing the analysis results with the measured data of the test product. The research might be said to provide the basic method to produce the polymer resin seals with various types and dimensions.

• Composites Research
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• 제12권2호
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• pp.70-81
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• 1999

고분자 복합재료 제조공정인 수지이동성형(RTM) 공정은 최근 들어서 고성능 재료를 필요로 하는 항공산업분야에서 관심의 대상이 되고 있다. 본 연구에서는 유한요소/관할부피 기법을 도입한 수치모사를 통해서 수지이동 성형공정에서의 금형충전단계를 해석하였다. 섬유직조망의 투과계수를 정량적으로 측정하고, 또한 수치모사에 이용된 프로그램을 검증하기 위하여 유동가시화 실험을 수행하였다. 실험에 사용된 강화섬유와 수지물질로는 여러 가지 형태의 섬유직조망과 실리콘 기름을 선택하였다. 수치모사와 유동가시화 실험을 병행함으로써 섬유직조망의 구조, 금형의 구조, 금형삽입체가 금형충전단계에서의 수지 유동선단의 형태에 미치는 영향을 살펴보았다. 모델링에 의해 예측된 유동선단은유동가시화 실험을 통해 관찰된 결과와 잘 일치한 것으로 나타났으나, 금형내 불균일한 섬유부피분율로 인해 섬유조직망의 투과계수가 전 영역에서 일정한 값을 가지지 못하기 때문에 약간의 차이를 보여주었다. 원형의 구조물이 금형내에 삽입되어 있는 경우, 월드라인의 위치를 예측된 유동선단으로부터 정성적으로 추정할 수 있었다.

• Korea-Australia Rheology Journal
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• 제19권1호
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• pp.17-25
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• 2007

In liquid composite molding (LCM), composites are produced by impregnation of a dry preform with liquid resin. The resin flow through the preform is usually described by Darcy's law and the permeability tensor must be obtained for filling analysis. While the resin flow in the thickness direction can be neglected for thin parts, the resin flow in the transverse direction is important for thicker parts. However, the transverse permeability of the preform has not been investigated frequently. In this study, the transverse permeability was measured experimentally for five different fiber preforms. In order to verify the experimental results, the measured transverse permeability was compared with numerical results. Five different fiber mats were used in this study: glass fiber woven fabric, aramid fiber woven fabric, glass fiber random mat, glass fiber braided preform, and glass/aramid hybrid braided preform. The anisotropic braided preforms were manufactured by using a three dimensional braiding machine. The pressure was measured at the inlet and outlet positions with pressure transducers.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2000년도 추계학술발표대회 논문집
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• pp.253-256
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• 2000

In order to commercialize the low cost composite fabrication technology in the area of domestic aerospace structure field, Resin Transfer Molding process has been considered as an alternative process to replace the high cost autoclave technology. The end part for the development of RTM process is the control rod of flight control system of aircraft. A braided preform was triaxially designed to improve the dimensional stability and mechanical property in the direction of external loads. Through the flow analysis using CVFEM, the resin filling time was calculated and the resin injection method was determined. The results of the flow analysis were directly applied to RTM mold design. The control rod was successfully manufactured by RTM process using internal pressure. The length and outer diameter of the manufactured part are 1148mm and 32mm, respectively.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2003년도 춘계학술발표대회 논문집
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• pp.184-187
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• 2003

Complete prediction of second order permeability tensor for three dimensional circular braided preform is critical to understand the resin transfer molding process of composites. The permeability can be predicted by considering resin flow through the multi-axial fiber structure. In this study, permeability tensor for a 3-D circular braided preform is calculated by solving a boundary problem of a periodic unit cell. Flow field through the unit cell is obtained by using a 3-D finite volume method (FVM) and Darcy's law is utilized to obtain permeability tensor. Flow analysis for two cases that a fiber tow is regarded as impermeable solid and permeable porous medium is carried out respectively. It is found that the flow within the intra-tow region of the braided preform is negligible if inter-tow porosity is relatively high but the flow through the tow must be considered when the porosity is low. To avoid checkerboard pressure field and improve the efficiency of numerical computation, a new interpolation function for velocity variation is proposed on the basis of analytic solutions. Permeability of the braided preform is measured through a radial flow experiment and compared with the permeability predicted numerically.

• Restorative Dentistry and Endodontics
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• 제24권2호
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• pp.265-285
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• 1999

The purposes of this investigation were to observe the reaction kinetics of five commercial dual cured resin cements (Bistite, Dual, Scotchbond, Duolink and Duo) when cured under varying thicknesses of porcelain inlays by chemical or light activation and to evaluate the effect of the porcelain disc on the rate of polymerization of dual cured resin cement during light exposure by using thermal analysis. Thermogravimetric analysis(TGA) was used to evaluate the weight change as a function of temperature during a thermal program from $25{\sim}800^{\circ}C$ at rate of $10^{\circ}C$/min and to measure inorganic filler weight %. Differential scanning calorimetry(DSC) was used to evaluate the heat of cure(${\Delta}H$), maximum rate of heat output and peak heat flow time in dual cured resin cement systems when the polymerization reaction occured by chemical cure only or by light exposure through 0mm, 1mm, 2mm and 4mm thickness of porcelain discs. In 4mm thickness of porcelain disc, the exposure time was varied from 40s to 60s to investigate the effect of the exposure time on polymerization reaction. To investigate the effect on the setting of dual cured resin cements of absorption of polymerizing light by porcelain materials used as inlays and onlays, the change of the intensity of the light attenuated by 1mm, 2mm and 4mm thickness of porcelain discs was measured using curing radiometer. The results were as follows 1. The heat of cure of resin cements was 34~60J/gm and significant differences were observed between brands (P<0.001). Inverse relationship was present between the heat of reaction and filler weight % the heat of cure decreased with increasing filler content (R=-0.967). The heat of reaction by light cure was greater than by chemical cure in Bistite, Scotchbond and Duolink(P<0.05), but there was no statistically significant difference in Dual and Duo(P>0.05). 2. The polymerization rate of chemical cure and light cure of five commercially available dual cured resin cements was found to vary greatly with brand. Setting time based on peak heat flow time was shortest in Duo during chemical cure, and shortest in Dual during light cure. Cure speed by light exposure was 5~20 times faster than by chemical cure in dual cured resin cements. The dual cured resin cements differed markedly in the ratio of light and chemical activated catalysts. 3. The peak heat flow time increased by 1.51, 1.87, and 3.24 times as light cure was done through 1mm, 2mm and 4mm thick porcelain discs. Exposure times recommended by the manufacturers were insufficient to compensate for the attenuation of light by the 4mm thick porcelain disc. 4. A strong inverse relationship was observed between peak heat flow and peak time in chemical cure(R=0.951), and a strong positive correlations hip was observed between peak heat flow and the heat of cure in light cure(R=0.928). There was no correlationship present between filler weight % or heat of cure and peak time. 5. The thermal decomposition of resin cements occured primarily between $300^{\circ}C$ and $480^{\circ}C$ with maximum decomposition rates at $335^{\circ}C$ and $440^{\circ}C$.

• 방사성폐기물학회지
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• 제13권2호
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• pp.123-130
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• 2015

순수 베타 핵종인 ⁹⁰Sr 분석은 화학적 거동이 유사한 알칼리 토금속(Ca, Ba, Ra)등 방해 원소를 제거할 분리 공정이 필요하다. 본 연구는 Sr을 추출/정제하기 위해 추출크로마토그래피법을 이용한 최적의 절차를 마련하는 것을 목적으로 한다. Sr resin 1.5 mL BV(Bed Volume)의 최대 Sr 흡착량은 6 mg이었다. 유량 1 mL min^-1과 Ca 200 mg 이하에서는 Sr resin 1.5 mL(BV)의 Sr 회수는 정량적이었으나, 유량을 5 mL min^-1으로 중가 시키면 Sr 회수율이 감소하였다. 같은 양(BV)의 Sr resin을 사용할 경우, 컬럼의 단면적이 작을수록 Sr resin의 분리능이 향상되었다.

• Journal of the Korean Wood Science and Technology
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• 제45권4호
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• pp.471-481
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• 2017

As the molecular weight (MW) of urea-formaldehyde (UF) resins had a great impact on their properties, this work was conducted to study effect of analytical parameters of gel permeation chromatography (GPC) on the MW measurement of UF resins. GPC parameters such as flow rate, column, detector temperature, and sample injection temperature were selected to compare number-average molecular weight (Mn), weight-average molecular weight (Mw), molecular weight distribution (MWD) and polydispersity index (PDI) of two UF resins with different viscosities. As expected, UF resin with higher viscosity resulted in greater Mn and Mw than those of low viscosity UF resin. When the flow rate increased, both Mn and Mw of UF resins decreased and MWD became narrower. By contrast, both Mn and Mw increased and MWD became wide when the column, detector, and sample injection temperature increased. The column, detector, and sample injection temperature of $50^{\circ}C$ at a flow rate of $0.5m{\ell}/min$ resulted in the highest MW and broadest MWD for the GPC analysis. These results suggest that the apparent molecular size or a hydrodynamic radius of UF resin molecules dissolved in the mobile phase affect to Mn, Mw and MWD.

• Composites Research
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• 제26권6호
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• pp.363-372
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• 2013

RTM (Resin Transfer Molding) 공정을 수치해석하기 위해 Level set 방법과 결합된 확장 유한 요소 법을 적용하였다. 유동 전면 부에서 비연속적인 구배를 가지는 압력을 계산하기 위해 확장 유한 요소 법을 이용하여 계산의 정밀성을 높였다. 확장 유한 요소 법에 이용되는 확장 형상 함수는 Level set 값을 이용하여 정의하였다. 이 확장 형상 함수는 요소를 통과하는 수지 유동 전면부의 위치를 반영할 수 있다. 게다가 Level set 법이 금형 충전 동안 수지 유동 전면부의 위치를 계산할 때 적용되었다. 수지 유동 전면부의 위치를 계산하는 미분방정식은 내연적 특성 Galerkin 유한 요소 법을 적용하여 풀었다. 선형 시스템 계산에서는 IPSAP의 다중 프론트 솔버를 이용한다. 본 연구에서 계산한 해석 값은 이론 값과 비교하여 검증하였다. 계산 효율을 높이기 위해 확장 유한 요소 법과 Level set 방법의 국소화 기법이 제안되었다. 이 기법은 계산 영역을 수지 유동 전면 부 근처의 영역으로 축소한다. 그러므로 전체 계산 양은 최소화될 수 있었다. 이 기법의 계산 효율은 채널 유동 모델을 이용하여 평가된다. 본 연구의 해석 능력을 보여주기 위해 몇 가지 적용 예제를 계산하였다. 첫 번째 예제를 이용해서 복잡하게 흘러가는 수지 전면부의 갈라짐과 합쳐지는 현상 해석하였다. 그리고 금형 내부의 Race-tracking 효과와 기공 생성 현상을 확인하기 위해 복잡한 모양의 구조물을 시뮬레이션 하였다.

• Composites Research
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• 제36권5호
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• pp.310-314
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• 2023

VaRTM(Vacuum assisted resin transfer molding)과 VAP(Vacuum assisted process) 공정은 RTM(Resin transfer modling) 공정의 한 종류로서, 대형구조물을 저가에 제작할 수 있는 대표적인 탈 오토클레이브(OOA, Out of Autoclave) 공정이다. 본 논문에서는 VaRTM과 VAP 공정을 상호 비교하기 위하여 수지 충진시험을 진행하였으며, 충진과정과 치수 안정성 등을 상호 비교하였다. 또한, 충진과정을 모사할 수 있는 해석기법을 개발하였으며, 유전센서를 사용하여 수지의 유동선단을 검출하여 이를 해석결과와 상호 비교하였다. 수지 충진시험 결과, 복합재 평판의 총 충진시간은 VAP공정은 48분, VaRTM 공정은 145분으로 측정되어, VAP 공정에 의한 충진시간이 VaRTM 대비 약 67% 단축되었으며, VAP공정이 VaRTM 공정에 비해 복합재 평판의 두께조절능력과 균일도가 우수함을 확인하였다.