• Title/Summary/Keyword: Residual Chloride

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Studies on the Residual Bending Strength of burned Douglas-fir and Western Hemlock soaked with Fire Retardant Chemicals (내화처리(耐火處理) 미송(美松) 및 미삼재(美杉材)의 연소후(燃燒後) 잔유(殘留)휨강도(强度)에 관한 연구(硏究))

  • Lee, Phil-Woo;Park, Heon
    • Journal of the Korean Wood Science and Technology
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    • v.12 no.3
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    • pp.15-24
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    • 1984
  • The $3{\times}3{\times}30\;cm^3$ sized specimens of Douglas-fir(Pseudotsuga menziesii) and western hemlock(Tsuga heterophylla) in this study were soaked in four fire-retardant solutions of ammonium sulfate, monoammonium phosphate, diammonium phosphate, and aluminium chloride for 1, 24, 72, 168, and 336 hours. Subsequently they were air-dried and burned at high temperature of ca. $1,800^{\circ}C$ and for short time of 5 minutes. This study estimated the relationship between the adsorbed chemicals and the residual weight ratio or residual bending strength of these partly burned lumbers. The results were as follows; 1) In average amount of chemical adsorption, diammonium phosphate showed the largest and aluminium chloride the smallest regardless of species but monoammonium phosphate was larger in Douglas-fir than that of western hemlock. 2) The amount of chemical adsorption was larger in western hemlock than Douglas-fir on the whole. 3) The amount of chemical adsorption was increased with the increase of soaking time but the rate of increase began to decrease at 200hrs. 4) Residual weight ratios showed no difference between species but showed differences among the chemicals treated i.e. monoammonium phosphate, diammonium phosphate, ammonium sulfate and aluminium chloride in turn from the largest to the smallest. 5) MOR values showed linear increase with the increase of residual weight ratios but showed no difference in species and chemicals respectively. 6) In the relationship between amount of chemical adsorption and MOR, only diammonium phosphate showed the curve of secondary degree with significance in Douglas-fir. 7) The MOE value of burned Douglas-fir lumber increased and showed significance of 99% as the adsorbed chemical amount increased, but among the chemicals only monoammonium phosphate showed significance. The MOE value of burned western hemlock lumber didn't show significance. 8) In only Douglas-fir, the correlation between adsorbed chemical amount and work to proportional limit showed significance in only monoammonium phosphate. And in both Douglas-fir and western hemlock, the correlation between adsorbed chemicals and work to maximum load showed significance in monoammonium phosphate.

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Characteristics of Adsorption on the RO Membrane Surface by Coagulants Types (응집제 종류에 따른 RO막 표면 흡착 특성)

  • Jeong, Youngmi;Park, Chanhyuk;Lee, Sanghyup;Kweon, Jihyang
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.4
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    • pp.477-483
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    • 2007
  • A coagulation process for RO (reverse osmosis) membrane pretreatment system was an effective technology to remove colloidal and particulate matters. However, coagulant residuals from the pretreatment process may negatively affect RO membrane performance. The bench-scale coagulant exposure study was performed to investigate the effect of their residual on adsorbed mass which related to the membrane performance. Coagulant addition in this study ranged from 0 to 5mg/L ferric chloride, alum, and 2mg/L cationic polymer(poly-di-methyldiallyl ammonium chloride) as coagulant aids. This results showed that adsorbed mass is not significantly increased during short-time period, however, accumulated mass of coagulants on the membrane surface is significantly increased during long-time experimental period. The effect of pH on coagulants adsorption characteristics was significantly differed due to the electrostatic repulsive interactions between soluble coagulants and membrane surface charge. This data suggest that the RO membrane performance of drinking water treatment plant could be decreased by adsorption of residual coagulants when applied for the coagulant pretreatment process.

Strength deterioration of reinforced concrete column sections subject to pitting

  • Greco, Rita;Marano, Giuseppe Carlo
    • Computers and Concrete
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    • v.15 no.4
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    • pp.643-671
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    • 2015
  • Chloride induced reinforcement corrosion is widely accepted to be the most frequent mechanism causing premature degradation of reinforced concrete members, whose economic and social consequences are growing up continuously. Prevention of these phenomena has a great importance in structural design, and modern Codes and Standards impose prescriptions concerning design details and concrete mix proportion for structures exposed to different external aggressive conditions, grouped in environmental classes. This paper focuses on reinforced concrete column section load carrying capacity degradation over time due to chloride induced steel pitting corrosion. The structural element is considered to be exposed to marine environment and the effects of corrosion are described by the time degradation of the axial-bending interaction diagram. Because chlorides ingress and consequent pitting corrosion propagation are both time-dependent mechanisms, the study adopts a time-variant predictive approach to evaluate residual strength of corroded reinforced concrete columns at different lifetimes. Corrosion initiation and propagation process is modelled by taking into account all the parameters, such as external environmental conditions, concrete mix proportion, concrete cover and so on, which influence the time evolution of the corrosion phenomenon and its effects on the residual strength of reinforced concrete columns sections.

Effect of Residual Chloride Ion on Thermal Decomposition Behaviour os Stannic Acid and Physical Properties of $SnO_2$ Powder Fabricated for Gas Sensor (가스센서용 $SnO_2$분말 제조시 잔류 염소이온이 Sn수화물의 열분해거동 및 분말물성에 미치는 영향)

  • Song, Guk-Hyeon;Choe, Byeong-U;Park, Jae-Hwan;Park, Sun-Ja
    • Korean Journal of Materials Research
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    • v.4 no.8
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    • pp.934-944
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    • 1994
  • Effects of residual chloride on thermal decomposition behaviour of a-stannic acid and physical properties of $SnO_{2}$ powder were observed. The powder was fabricated by hydroxide method; $\alpha$-stannic acid was precipitated by mixing acqueous solutions of $SnCl_{4}$ and $NH_{4}$OH . The precipitate was washed with $NH_{4}NO_{3}$ solution while washing was controlled to be of three grades to modify its residual chloride content. The precipitate was dried at $1100^{\circ}C$ ~ 24h and calcined in air at $500^{\circ}C$ ~ $1100^{\circ}C$ for one hour. Thermal decomposition behaviour of $\alpha$-stannic acid was examined by a DT-TGA and a FTIR. Chemical composition and physical properties of $SnO_{2}$ powder were observed by an AES, a BET and a TEM, respectively. With a reduction in chloride content, the relative crystallite size of $SnO_{2}$ powder slightly increased by a low-temperature-calcining. However, at a high calcining temperature(T), the reverse relation occured. It was suggested that chloride ion replaces part of lattice oxygen site of a-stannic acid. Also, chloride ion on the site was suggested to retard de-hydration as well as crystalization at a low T while to promote crystal growth of $SnO_{2}$ by forming oxygen vacancy at a high T.

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Change of Lipoxygenase Activity in Chinese Cabbages Submerged in Brines (배추의 절임 중 Lipoxygenase의 활성변화)

  • Kim, Dong-Kyoung;Han, Kee-Young;Noh, Bong-Soo
    • Korean Journal of Food Science and Technology
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    • v.29 no.3
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    • pp.576-580
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    • 1997
  • Lipoxygenase activity in Chinese cabbage was measured at various concentrations of brines. Lipoxygenase activity on linoleic acid substrate was determined by changing the rate of dissolved oxygen consumption. The inactivation of lipoxygenase by salting was increased when concentration of sodium chloride and soaking time were increased. About 60% of enzyme activity was reduced after submerging in 13% brine solution for 5 hr. The addition of calcium chloride (0.7%) reduced about $10{\sim}15%$ of lipoxygenase activity rather than without. Residual activity of lipoxygenase in Chinese cabbage submerged in 13% brine was 20% and about 60% of lipoxygenase was also inhibited by addition of garlic extract.

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A study on performance analysis and merging techniques of sensors in water quality measurement (수질계측센서의 성능분석 및 센서 융합기술에 관한 연구)

  • Yang Keun-Ho;Yoo Byung-Kook
    • Journal of the Institute of Convergence Signal Processing
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    • v.7 no.3
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    • pp.143-148
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    • 2006
  • There are need to manage the water quality to supply an safety to consumer through pipe and reservoir the drinking water that produced in a clean water reservoir. However, a management of water quality and monitoring in reservoir have never been performed. Recently, the government has enforced standards of water quality. However, we have a inferior technology of water quality as compared with one in USA, Japan, Germany, etc. In case of water quality inspection and analysis equipments, sensor technology is very important to improve the water quality inspection and to develop the analysis equipments. In this paper, we analyze a law and a regulation for management of drinking water quality, and propose the measurement standards of drinking water quality in pH, conductivity, residual chloride, turbidity and water temperature. Then, we analyze electrode sensors that interference within pH, conductivity, residual chloride in interference experiment.

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Estimation of Diffusion Coefficient and Mass Transfer Coefficient in Microwave-Assisted Drying of Paclitaxel for Removal of Residual Methylene Chloride (잔류 메틸렌 클로라이드 제거를 위한 마이크로웨이브를 이용한 파클리탁셀건조에서 확산계수 및 물질전달계수 추정)

  • Kim, Jin-Hyun
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.430-434
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    • 2018
  • In this study, an effective diffusion coefficient and mass transfer coefficient were investigated in microwave-assisted drying of paclitaxel for removal of residual methylene chloride. At all the temperatures (35, 45, and $55^{\circ}C$), a large amount of the residual methylene chloride was initially removed during the drying, and the drying efficiency increased when increasing the drying temperature. The effective diffusion coefficient ($1.299{\times}10^{-13}{\sim}2.571{\times}10^{-13}m^2/s$) and mass transfer coefficient ($1.625{\times}10^{-11}{\sim}4.857{\times}10^{-11}m/s$) increased with increasing drying temperature. The small Biot number (0.0100~0.0151) indicated that the process of mass transfer was externally controlled.

Changes of Chemical Components During the Storage of Fresh Red Pepper Homogenates (파쇄(破碎) 생(生)고추의 밀봉(密封) 저장중(貯藏中) 품질(品質) 성분(成分)의 변화(變化))

  • Lee, Gye Hee;Oh, Man Jin
    • Korean Journal of Agricultural Science
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    • v.13 no.1
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    • pp.130-138
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    • 1986
  • In order to obtain the basic data for development of raw pepper homogenates as instant spice, effects of preservatives, packaging materials, storage temperature and period on chemical components of raw pepper homogenates were investigated during storage after sealing up. The results are as follows: 1. Raw pepper homogenates added 15% sodium chloride was effective prominently than raw pepper homogenates on residual contents of acidity, capsanthin and capsaicin. 2. P. V. D. C film was effective than P. E film in sealing of raw pepper homogenates. 3. Decomposition of capsanthin was exceeded at high temperature during the sealed storage of raw pepper homogenates and decomposition of capsaicin was accelerated at initial stage of storage and also it was decreased prominently by adding of sodium chloride. 4. Decomposition of vitamin C during the storage was exceeded at high temperature and it was prominently suppressed by adding of sodium chloride. 5. Increase of total viable cell count and lactic acid bacteia count was prominently suppressed by adding of sodium chloride and its difference for storage temperature was disregarded.

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ADVANCES IN DESIGN AND RESIDUAL LIFE CALCULATION WITH REGARD TO REBAR CORROSION OF REINFORCED CONCRETE

  • C. Andrade;D. Izquierdo;J. Rodriguez;L Ortega
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05a
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    • pp.15-30
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    • 2005
  • The increasing amount of structures presenting distress due to reinforcement corrosion is urging the establishment of more accurate calculation methods for the service life of concrete structures. In the present paper, a summary of the different approaches is presented that are able to calculate the expected life of new structures, in certain aggressive environments or the residual life of already corroding structures. The methods for the initiation period are based on the proper calculation of the carbonation front or chloride penetration and on the steel corrosion rate. The methods for the residual load-bearing capacity calculations are based in the use of ' indicators ' or in the evaluation of the reduced section and a structural recalculation.

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Effects of the Changes of Current Density and Additive Concentration on Ni Thin Films in Ni Sulfamate-chloride Electrodeposition Baths (Ni Sulfamate-chloride 전기도금 용액에서 전류밀도와 첨가제의 농도 변화가 Ni 박막에 미치는 영향)

  • Yoon, Pilgeun;Park, Deok-Yong
    • Journal of the Korean institute of surface engineering
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    • v.51 no.1
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    • pp.62-70
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    • 2018
  • Sulfamate plating solution containing a small amount of chloride bath was fabricated to study the properties of the electrodeposited Ni thin films. Effects of the changes of current density and additive concentration on current efficiency, residual stress, surface morphology and microstructure of Ni thin films electrodeposited from Ni sulfamate-chloride baths were investigated. The current efficiency was measured to be more than about 95%, independent of the changes of current density and saccharin concentration in the baths. Residual stress of Ni thin film was appeared to be the compressive stress modes in the range of $5{\sim}30mA/cm^2$ current density. Maximum compressive stress was observed at the current density of $10mA/cm^2$. Compressive stress values of Ni thin/thick films were increased to be about -85~-100 MPa with increasing saccharin concentration from 0 to 0.0195 M(4 g/L). Surface morphology was changed from smooth to nodule surface appearance with increasing the current density. Smooth surface morphology of Ni thin films electrodeposited from the baths containing saccharin was observed, independent of the saccharin concentration. Ni thin/thick films consist of FCC(111), FCC(200), FCC(220), FCC(311) and FCC(222) peaks. It was revealed that the FCC(200) peak of Ni thin films is the preferred orientation in the range of $5{\sim}30mA/cm^2$ current density. The intensity of FCC(200) peak was gradually decreased and the intensity of FCC(111) peak was increased with increasing saccharin concentration in the baths.