• Title/Summary/Keyword: Research Program

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High Alloying Degree of Carbon Supported Pt-Ru Alloy Nanoparticles Applying Anhydrous Ethanol as a Solvent

  • Choi, Kwang-Hyun;Lee, Kug-Seung;Jeon, Tae-Yeol;Park, Hee-Young;Jung, Nam-Gee;Chung, Young-Hoon;Sung, Yung-Eun
    • Journal of Electrochemical Science and Technology
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    • v.1 no.1
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    • pp.19-24
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    • 2010
  • Alloying degree is an important structural factor of PtRu catalysts for direct methanol fuel cells (DMFC). In this work, carbon supported PtRu catalysts were synthesized by reduction method using anhydrous ethanol as a solvent and $NaBH_4$ as a reducing agent. Using anhydrous ethanol as a solvent resulted in high alloying degree and good dispersion. The morphological structure and crystallanity of synthesized catalysts were characterized by X-ray diffraction (XRD), high resolution transmission electron microscope (HR-TEM). CO stripping and methanol oxidation reaction were measured. Due to high alloying degree catalyst prepared in anhydrous ethanol, exhibited low onset potential for methanol oxidation and negative peak shift of CO oxidation than commercial sample. Consequently, samples, applying ethanol as a solvent, exhibited not only enhanced CO oxidation, but also increased methanol oxidation reaction (MOR) activity compared with commercial PtRu/C (40 wt%, E-tek) and 40 wt% PtRu/C prepared in water solution.

Controll over the Au@Ag Core-shell Nanoparticle 2D Patterns via Diblock Copolymer Inverse Micelle Templates and Investigation of the Surface Plasmon Based Optical Property (이중블록공중합체 역마이셀 주형을 이용한 Au@Ag 코어-쉘 나노입자 2차원 패턴 제어 및 표면 플라즈몬 기반 광학적 특성 연구)

  • Yoon, Min Ji;Kim, Jihyeon;Jang, Yoon Hee;Lee, Ji-Eun;Chung, Kyungwha;Quan, Li Na;Kim, Dong Ha
    • Journal of the Korean Chemical Society
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    • v.57 no.5
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    • pp.618-624
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    • 2013
  • We demonstrated unique inter- and intra-plasmonic coupling effects in bimetallic Au@Ag core-shell NP arrays which are regularly or randomly arranged on self-assembled block copolymer (BCP) inverse micelle monolayers. Polyvinylpyrrolidone (PVP)-stabilized Au@Ag core-shell NP arrays in regular or disordered configuration were incorporated and assembled on reconstructed PS-b-P4VP inverse micelle templates through two types of processes. The intensively enhanced LSPR coupling properties of individual and assembled Au@Ag NPs were evaluated by UV-visible spectroscopy in terms of the type of ligand stabilizer, coupling between Au and Ag, thickness of Ag shell, and type of array configuration. Finally, Au@Ag core-shell NP arrays were employed as active substrates for surface enhanced Raman spectroscopy (SERS) and a significantly enhanced signal enhancement was observed in accordance with the coupling intensity of Au@Ag NPs patterns.

Falcon 9 Type Korean RLV and GTO-LV Mission Design (Falcon 9 방식의 한국형 재사용 발사체 및 정지궤도 발사체 임무설계)

  • Lee, Keum-Oh;Seo, Daeban;Lim, Byoungjik;Lee, Junseong;Park, Jaesung;Choi, Sujin;Lee, Keejoo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.26 no.3
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    • pp.32-42
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    • 2022
  • The strategy to develop a launch vehicle family by bundling multiple rocket engines of a single type has been proven by SpaceX and their reusable fleet comprised of Falcon 9 and Falcon Heavy. In this study, we revisit a potential launch vehicle family out of a 35 tonf-class methalox staged combustion cycle engine and evaluate their utility and performance in various space missions. For example, a Korean version of Falcon 9 can deliver 4.7 tons of payload into 500 km SSO in an expendable mode while the payload is reduced to 2.16 tons in a sea-landing reusable mode. A Korean version of Falcon Heavy can deliver 4.4 tons into GTO when launched from the Naro Space Center, indicating that this common booster core configuration can handle Cheollian 2 albeit the high inclination. Once developed, the same methaloax engine can power the first-stage of smallsat launch vehicles and air launch vehicles.

WRF Physics Models Using GP-GPUs with CUDA Fortran (WRF 물리 과정의 GP-GPU 계산을 위한 CUDA Fortran 프로그램 구현)

  • Kim, Youngtae;Lee, Yong Hee;Chung, Kwan-Young
    • Atmosphere
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    • v.23 no.2
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    • pp.231-235
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    • 2013
  • We parallelized WRF major physics routines for Nvidia GP-GPUs with CUDA Fortran. GP-GPUs are originally designed for graphic processing, but show high performance with low electricity for calculating numerical models. In the CUDA environment, a data domain is allocated into thread blocks and threads in each thread block are computing in parallel. We parallelized the WRF program to use of thread blocks efficiently. We validated the GP-GPU program with the original CPU program, and the WRF model using GP-GPUs shows efficient speedup.

The Structure of Americanin A

  • Lin, Lee-Juian;Meksuriyen, Duangdeun;Cordell, Geoffrey A.;Woo, Won-Sick;Lee, Chung-Kyu
    • Korean Journal of Pharmacognosy
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    • v.18 no.2
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    • pp.94-98
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    • 1987
  • The structure of the neolignan americanin A was confirmed to be 2, through the application of the Selective INEPT NMR technique. Complete and unambiguous proton and $^{13}C-NMR$ assignments are provided.

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Comparative Analysis on the Evaluation Systems of the Public R&D Programs in the Developed Countries (선진국공공연구개발프로그램 평가시스템의 비교분석)

  • 홍형득
    • Journal of Korea Technology Innovation Society
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    • v.4 no.3
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    • pp.275-290
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    • 2001
  • The frameworks for evaluation of national R&D programs reflect their various political and administrative cultures(Gibbons & Georghiou, 1987), and the structure of national R&D system. In this research the core research questions are : what is god evaluation\ulcorner What is being evaluated, by whom, by which criteria, for whom and what purpose\ulcorner In order to examine these general aims and answer these questions, in detail several objectives can be proposed on the process of this research. In this research, the national R&D programs will be considered in terms of the interface between evaluation and the wider policy-making process. The programs for case study are the Alvey program(UK), the Advanced Technology Program (US) and the Framework program(EU) . One of the characteristics of these programs is the well established evaluation systems they have. From the comparative analysis, we can withdraw some useful implication for Korean evaluation practice for national R&D programs. Evaluation system is social process and the way in which it is organized is critical to its outcome.

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How a Convergence Product Affects Related Markets: The Case of the Mobile Phone

  • Lee, Mi-Suk;Lee, Jong-Su;Cho, Young-Sang
    • ETRI Journal
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    • v.31 no.2
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    • pp.215-224
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    • 2009
  • Analyzing the diffusion of a convergence product is a new and challenging research field. It is very difficult to find research dealing with this issue due to the inherent complexity and lack of data. In analyzing the diffusion of a convergence product, we should simultaneously take into account its relationship with related single-function products because of their similarities in terms of technology and functionality. In this study, we empirically analyze the diffusion of the convergence mobile phones in South Korea and find that the convergence products can affect the diffusion of MP3 players and digital cameras positively or negatively. This research may be significant for business strategies in technology management and product development.

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Design Study for KSLV Integrated Power Plant Test Facility

  • Kang, Sun-Il;Lee, Jung-Ho;Kim, Young-Han;Oh, Seung-Hyup
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.573-576
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    • 2004
  • KARI is achieving the KSLV program according to National Space Technology Development Program. In this paper, the authors are intended to introduce the Integrated Power Plant (abb. IPP) test facility which will be constructed for the variety of tests on KSLV program. IPP test facility refers to comprehensive testing equipment for liquid rocket launch vehicle. Using this facility, KARl can verify the adaptiveness of parts and subsystems for launch vehicle and finally can qualify the system characteristics of launch vehicle doing kinds of test including hot firing test. Using this facility, KARI can simulate the vehicle launching circumstances and it make to predict the performance of launch vehicle when its flight test.

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Gamma Ray Shielding Study of Barium-Bismuth-Borosilicate Glasses as Transparent Shielding Materials using MCNP-4C Code, XCOM Program, and Available Experimental Data

  • Bagheri, Reza;Moghaddam, Alireza Khorrami;Yousefnia, Hassan
    • Nuclear Engineering and Technology
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    • v.49 no.1
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    • pp.216-223
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    • 2017
  • In this work, linear and mass attenuation coefficients, effective atomic number and electron density, mean free paths, and half value layer and $10^{th}$ value layer values of barium-bismuth-borosilicate glasses were obtained for 662 keV, 1,173 keV, and 1,332 keV gamma ray energies using MCNP-4C code and XCOM program. Then obtained data were compared with available experimental data. The MCNP-4C code and XCOM program results were in good agreement with the experimental data. Barium-bismuth-borosilicate glasses have good gamma ray shielding properties from the shielding point of view.

Thio and Nitrogen Analogues of Acronycine

  • Geewananda, Y.A.;Gunawardana, P.;Cordell, Geoffrey A.
    • Archives of Pharmacal Research
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    • v.18 no.3
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    • pp.195-202
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    • 1995
  • The thio, thio acetyl, oxime, and several hydrazone and azine derivatives of the antitumor alkaloid acronycine (1) were prepared. NMR spectroscopy was used to study the configurations around the C=N double bond in these acronycine derivatives. In the hydrazones and azines of acronycine the N-N bond assumes a syn configuration to the $C_6-OCH_3$ group, while the NO bond in the oxime and the N-N bond in noracronycine hydrazone and azines assumes an anti configuration.

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