• Title/Summary/Keyword: Removal of impurities

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Recent Trend of Ultra-Pure Water Producing Equipment

  • Motomura, Yoshito
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.06a
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    • pp.121-147
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    • 1996
  • Since 1980, the water quality of ultra-pure water has been rapidly improved, and presently ultra-pore water producing equipment for 64Mbit is in operation. Table 1 shows the degree of integration of DRM and required water quality exlmple. The requirements of the ultra-pure water for 64Mbit are resistivity: 18.2 MQ/cm or higher, number of particulates: 1 pc/ml or less (0.05 $\mu$m or larger). bacteria count: 0.1 pc/l or less. TOC (Total Organic Carbon, index of organic snbstance) : 1ppb or less, dissolved oxygen: 5ppb or less, silica: 0.5ppb or less, heavy metal ions: 5ppb or less. The effect of metals on the silicon wafer has been well known, and recently it has been reported that the existence of organic substance in ultra-pure water is closely related to the device defect, drawing attention. It is reported that if organic substance sticks to the natural oxidation film, the oxide film remaims on the organic substance attachment in the hydrofluoric acid treatment (removal of natural oxidation film). The organic substance forms film on the silicon wafer, and harmful elements such as metals and N.P.S., components contained in the organic substance and the bad effect due to the generatinn of silicon carbide cannot be forgotten. In order to remove various impurities in raw water, many technological develoments (membrane, ion exchange, TOC removal, piping material, microanalysis, etc.) have been made with ultra-pure water producing equipment and put to practical use. In this paper, technologies put to practical use in recent ultra-pure vater producing equimeut are introduced.

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Pretreatment Process for Performance Improvement of SIES at Kori Unit 2 in Korea

  • Lee, Sang-Jin;Yang, Ho-Yeon;Shin, Sang-Woon;Song, Myung-Jae
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.02a
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    • pp.12-27
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    • 2004
  • Pretreatment process consisted of submerged hollow-fiber microfiltration(HMF) membrane and spiral-wound nanofiltration(SNF) membrane has been developed by NETEC, KHNP for the purpose of improving the impurities of liquid radioactive waste before entering Selective Ion Exchange System(SIES). The lab-scale combined system was installed at Kori NPP #2 nuclear power plant and demonstration tests using actual liquid radioactive waste were carried out to verify the performance of the combined system. The submerged HMF membrane was adopted for removal of suspended solid in liquid radioactive waste and the SNF membrane was used for removal of particulate radioisotope such as, Ag-l10m and oily waste because ion exchange resin can not remove particulate radioisotopes. The liquid waste in Waste Holdup Tank (WHT) was processed with HMF and SNF membrane, and SIES. The initial SS concentration and total activity of actual waste were 38,000ppb and $1.534{\times}10_{-3}{\mu}Ci/cc$, respectively. The SS concentration and total activity of permeate were 30ppb and lower than LLD(Lower Limit of Detection), respectively.

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Evaluation of SMUT Properties according to Nb Content in the Pickling Process of Nuclear Fuel Cladding Tube (핵연료 피복관의 산세 공정 시 Nb 함량에 따른 SMUT 특성)

  • Moon, Jong Han;Lee, Young Jun;Lee, Jin Hang;Hong, Jong Won;Lee, Jong Hyeon
    • Korean Journal of Materials Research
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    • v.29 no.8
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    • pp.483-490
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    • 2019
  • Currently, the Korean nuclear industry uses ZIRLO as material for nuclear fuel cladding(zirconium alloy). KEPCO Nuclear Fuel is in the process of developing a HANA alloy to enable domestic production of cladding. Cladding manufacture involves multistage heat treatments and pickling processes, the latter of which is vital for the removal of defects and impurities on the cladding surface. SMUT that forms on the cladding surface during such pickling process is a source of surface defects during heat treatment and post-treatment processes if not removed. This study analyzes ZIRLO, HANA-4, and HANA-6 alloy claddings to extensively study the SEM/EDS, XRD, and particle size characteristics of SMUT, which are second phase particles that are formed on the cladding surface during pickling processes. Using the analysis results, this study observes SMUT formation characteristics according to Nb concentration in Zr alloys during the washing process following the pickling process. In addition, this study observes SMUT removal characteristics on cladding surfaces according to concentrations of nitric acid and hydrofluoric acid in the acid solution.

Molecular Dynamics Study on Evaporation Process of Adherent Molecules on Surface by High Temperature Gas

  • Yang, Young-Joon;Osamu Kadosaka;Masahiko Shibahara;Masashi Katsuki;Kim, Si-Pom
    • Journal of Mechanical Science and Technology
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    • v.18 no.12
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    • pp.2104-2113
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    • 2004
  • Surface degreasing method with premixed flame is proposed as the removal method of adherent impurities on materials. Effects of adherent molecular thickness and surface potential energy on evaporation rate of adherent molecules and molecular evaporation mechanism were investigated and discussed in the present study. Evaporation processes of adherent molecules on surface molecules were simulated by the molecular dynamics method to understand thermal phenomena on evaporation processes of adherent molecules by using high temperature gas like burnt gas. The calculation system was composed of a high temperature gas region, an adherent molecular region and a surface molecular region. Both the thickness of adherent molecules and potential parameters affceted the evaporation rate of adherent molecules and evaporation mechanism in molecular scale.

A UNANI PERSPECTIVE OF MASSAGE: DALAK

  • Abbasi, Hana;Kabir, Hifzul
    • CELLMED
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    • v.9 no.3
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    • pp.6.1-6.5
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    • 2019
  • Unani system of medicine provides comprehension about the state of human body while in health and during turn down of health. Unani system strives to find the best methods to leads a healthy life with minimal or zero risk of any sickness additionally, the treatment is not only done through unani formulations but also by the regimenal therapies (Tadabeer) like Cupping (Hijamah), Leeching (Taleeq), Venesection (Fasd), Massage (Dalak), Exercise (Riyazat) etc. Massage (Dalak) is widely practiced regimens, which are used for restrorative, preventive as well as for therapeutic purposes. Almost all the civilizations having evidences about the use of massage in their manuscripts to improve impure blood or impurities from the body. Massage (Dalak) found to be effective in treatment of neurological and musculoskeletal disorders. Ibn Rushd stated that Massage (Dalak) is a type of exercise used for the removal of toxins or waste metabolites from the body. According to the disease, Massage (dalak) should be done in different parts of body and with different types of oils (roganiyat) and single drugs (mufrid advia).

A Study on the Extraction and Purification of Glutathione from Yeast

  • Kim, Seong-Ung;Yang, Choong-Ik;Min, Shin-Hong;Rhee, Sang-Hi;Kim, Yong-Bae
    • Journal of Pharmaceutical Investigation
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    • v.8 no.2
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    • pp.1-10
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    • 1978
  • During the course of studies on the production of glutathione from yeast, process development and optimization was carried out. The optimal pH for the extraction of glutathione was found to be 2.5 to 4.0 and the maximum yield for glutathione was obtained when the extraction temperature was 25 to $45^{\circ}C$. The cuprous salt of glutathione was recovered maximally at the range of 2 to 4g of cuprous oxide per 10 Kg of compressed yeast. Further purification was needed for the removal of impurities from glutathione. Cation exchange resin, anion exchange resin and Sephadex G-25 were employed for this purpose. 13 to 15 g of glutathione was obtained from 10 Kg of compressed yeast and the purity was above 99.3%.

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Iron hydrolysis and lithium uptake on mixed-bed ion exchange resin at alkaline pH

  • Olga Y. Palazhchenko;Jane P. Ferguson;William G. Cook
    • Nuclear Engineering and Technology
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    • v.55 no.10
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    • pp.3665-3676
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    • 2023
  • The use of ion exchange resins to remove ionic impurities from solution is prevalent in industrial process systems, including in the primary heat transport system (PHTS) purification circuit of nuclear power plants. Despite its extensive use in the nuclear industry, our general understanding of ion exchange cannot fully explain the complex chemistry in ion exchange beds, particularly when operated at or near their saturation limit. This work investigates the behaviour of mixed-bed ion exchange resin, saturated with species representative of corrosion products in a CANDU (Canadian Deuterium Uranium) reactor PHTS, particularly with respect to iron chemistry in the resin bed and the removal of lithium ions from solution. Experiments were performed under deaerated conditions, analogous to normal PHTS operation. The results show interesting iron chemistry, suggesting the hydrolysis of cation resin bound ferrous species and the subsequent formation of either a solid hydrolysis product or the soluble, anionic Fe(OH)3-.

Water Treatment Using DAF(Disssolved Air Flotation) (용존공기 부상법(Disssolved Air Flotation)을 이용한 정수처리)

  • Lee, Byoung-Ho;Kim, Jae Hoon
    • Journal of Korean Society of Water and Wastewater
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    • v.10 no.2
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    • pp.80-87
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    • 1996
  • Treatment efficiencies of water quality parameters such as $KMnO_4$ Demand, $UV_{254}$, Turbidity, and LAS(Linear Alkyl Sulfonate) were compared between DAF(Dissolved Air Flotation) and CGS(Conventional Gravitational Sedimentation). The experimental results showed that DAF is much more efficient in treatment of water quality parameters than CGS. The optimum pH was about 7, and optimum alum($Al_2(SO_4)_3$) dose was about 30 ppm for DAF treatment. Economic aspects were also analyzed for bath systems. Even though production cost per ton of drinking water is slightly higher in DAF than in CGS, it turned out that construction cost and land value of CGS far surpass the production cost. DAF system is superior in removal efficiency of impurities and in production cost as a whole to CGS system.

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Removal of Iron Bearing Minerals from Illite (일라이트에 함유된 Fe 불순물 제거)

  • Kim, Yun-Jong;Cho, Sung-Baek;Park, Hyun-Hae;Kim, Sang-Bae
    • Korean Journal of Materials Research
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    • v.16 no.8
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    • pp.497-502
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    • 2006
  • Recently, many attention have been focused on illite as a material for the well-being industry. Illite contains various kinds of iron bearing materials and they restrict their usage. In this study, Fe impurities in the illite produced in Yeongdong-gun, Chungcheongbuk-do were characterized and their removal experiments were performed. According to the characterization of illite raw ore, it contained 1.54 wt.%$Fe_2O_3$ due to the existence of iron oxide($Fe_2O_3$) and pyrite($FeS_2$). The raw ore was crushed into 3 mm or less using cone crusher and then ground by rod mill for the liberation of impurity mineral. For the removal of iron bearing minerals, an acid treatment, a flotation, a magnetic separation, and a flotation combined with magnetic separator were performed respectively. When the illite raw ore was treated with magnetic separation and various kinds of acid, 1.54wt.%. $Fe_2O_3$ content was reduced to 0.78 and 1.0 wt.%, respectively. On the other hand $Fe_2O_3$ content was reduced to be 0.52 wt.% after flotation. These results indicate that iron bearing minerals cannot be reduced below 0.3wt.%$Fe_2O_3$. However, combination of magnetic separation and flotation enable us to get 0.24wt.% of illite concentrate. It is concluded that, for the refinement of illite from Yeongdong-gun, the flotation combined with magnetic separation is good for high purity illite.

Hydrogen Sulfide Removal of Biogas from Sewage Treatment Plant with Micro-bubble Generation System (마이크로버블 장치를 이용한 하수처리장 바이오가스의 황화수소 제거)

  • Jung, Jae-Ouk;Jung, Yong-Jun
    • Journal of Wetlands Research
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    • v.22 no.4
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    • pp.239-244
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    • 2020
  • Prior to utilization of energy and power generation, the biogas from anaerobic digestion of sewage treatment plant(46,000㎡/d) should be purified particularly hydrogen sulfide among the various kinds of impurities. This study has focused on the methane decreasing rate and the removal of both hydrogen sulfide and carbon dioxide. In the case of partial circulation, 59.7% of methane gas was decreased to 57.4% in spite of oxidation process with micro-bubble. Carbon dioxide was removed from 38% to 32% and 76.1% of hydrogen sulfide was removed where 1,400ppm was introduced to the DIWS system, which indicated that DIWS system can be of use for the hydrogen sulfide removal of biogas from sewage treatment plant.