• Title/Summary/Keyword: Relative stability

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Hydrocarbon Gas-sensing Properties of Catalytic Combustion Type Gas Sensor (접촉연소식 가스센서의 탄화수소계 가스 감응 특성)

  • Lee, Dae-Sik;Lee, Sang-Mun;Nam, Ki-Hong;Han, Sang-Do;Lee, Duk-Dong
    • Journal of Sensor Science and Technology
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    • v.8 no.4
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    • pp.327-332
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    • 1999
  • Catalytic combustion type gas sensors were fabricated by using noble metal(Pt and Pd) added ${\gamma}-Al_2O_3$ powder with specific surface area of $200\;m^2/g$. The fabricated sensor showed power consumption of 500 mW at the operating voltage of 1.75 V and high sensitivity of about 120 mV for butane, methane, or propane 100%LEL, respectively. The sensor properties also showed good linearity to hydrocarbon gas concentration variation, reproductivity and stability for relative humidity variation. And it showed high stability in butane ambient for 100 days.

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Humidity-Sensitive Characteristics and Reliabilities of Polymeric Humidity Sensor Containing Phosphonium Salts (포스포늄 염을 가진 고분자 습도센서의 감습 특성 및 신뢰성)

  • Kim, Ohyoung;Gong, Myoung-Seon
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.554-560
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    • 1998
  • Vinylbenzyl triphenyl phosphonium chloride(VTPC)/styrenes=3.7 copolymer was prepared for the moisture-absorptive polyelectrolyte dew sensor containing phosphonium salts. The humid membrane was fabricated on the gold/alumina electrode by dipping. The impedances were $11M{\Omega}$, $980k{\Omega}$, $50k{\Omega}$, and $11k{\Omega}$ at 70%RH, 80%RH, 90%RH and 95%RH, respectively, at $25^{\circ}C$ and the humidity-sensitive charactristic was suitable for the dew sensor. The temperature-dependent coefficient between $15^{\circ}C$ and $35^{\circ}C$ was found to be $-0.25%RH/^{\circ}C$ and the hysteresis falled in the ${\pm}2%RH$ range. The response time was found to be 45 sec for the relative humidity ranging from 70%RH to 98%RH at $25^{\circ}C$. The reliabilities such as temperature cycle, humidity cycle, high temperature and humidity resistance, electrical load stability, stability of long-term storage and water durability were measured and evaluated for the application as a dew sensor.

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Storage Stability and Irradiation Effect of Red Pepper Powder (고추가루의 저장성(貯藏性)과 방사선 처리효과(處理效果))

  • Lee, Chung-Hye;Choi, Eon-Ho;Kim, Hyong-Soo;Lee, Su-Rae
    • Korean Journal of Food Science and Technology
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    • v.9 no.3
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    • pp.199-204
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    • 1977
  • To improve the storage stability of Korean red pepper (Capsicum annuum), the equilibrium moisture content of the powder and effects of irradiation on the capsaicin, capsanthin and microorganisms were investigated during its storage. The equilibrium moisture contents of the powder at $25^{\circ}C$ and relative humidities of 43.7, 53.3, 64.4, 75.4 and 84.3% were 13, 18, 25, 28 and 37%, respectively, and the larger the particle size was, the lower the equilibrium moisture content was under the same storage conditions. Cobalt-60 gamma irradiation degraded partly the capsaicin in red pepper or in solution at dose levels above 500 krad, but did not affect the moisture and capsanthin contents during its storage. Total viable cell count of the powder was around $10^8$ per gram and $D_{10}$ value for the mixed organisms was 210 krad.

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Simulation on the Distribution of Vanadium- and Iron-Picolinate Complexes in the Decontamination Waste Solution (제염 폐액에서 바나듐- 및 철-피콜리네이트 착화물의 평형분배 모사)

  • Shim, Joon-Bo;Oh, Won-Zin;Kim, Jong-Duk
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.33-38
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    • 2005
  • The distribution of vanadium and iron ionic species in the presence of picolinate ligand has been simulated at various conditions with different pH values and compositions in the decontamination waste solution. In spite of variations of metal concentration in the decontamination solution, the shape of distribution diagrams were not changed greatly at both high (the molar ratio of picolinate to vanadium is 6) and low (the molar ratio is 3) LOMI decontamination conditions. However, in the solution of low-picolinate condition the shape of the distribution diagram of iron(II)-picolinate complexes was changed significantly. This phenomenon is attributed to the shortage of relative amount of picolinate ligand to iron existed in the solution, and originated from the difference in stability constants for complexes formed between vanadium(III) and iron(II) species with picolinate ligand. The distribution diagrams obtained in this study can be applied very usefully to the prediction or understanding the reaction phenomena occurred at various conditions in the course of the LOMI waste treatments such as an ion exchange operation.

Characterization of Physicochemical Properties of Ferulic Acid

  • Sohn, Young-Taek;Oh, Jin-Hee
    • Archives of Pharmacal Research
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    • v.26 no.12
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    • pp.1002-1008
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    • 2003
  • Ferulic acid (3-methoxy, 4-hydroxy cinnamic acid) is a flavoid component possessing antioxidant property. The compound is currently under development as a new drug candidate for the treatment of the dementia. The objective of this preformulation study was to determine the physicochemical properties of ferulic acid. The n-octanol to water partition coefficients of ferulic acid were 0.375 and 0.489 at the pHs of 3 and 10, respectively. Accelerated stability study for ferulic acid indicated that the t 90 value for the drug was estimated to be 459 days at $25^{\circ}C$. Ferulic acid was also found to be unstable under the relative humidity of more than 76%, probably because of the hygroscopic nature of the drug. In order to study compatibility of ferulic acid with typical excipients, potential change in differential scanning calorimetry spectrum was studied in 1: 1 binary mixtures of ferulic acid and typical pharmaceutical excipients (e.g., Aerosil, Avicel, CMC, Eudragit, lactose, PEG, PVP, starch and talc). Avicel, CMC, PVP and starch were found to be incompatible with ferulic acid, indicating the addition of these excipients may complicate the manufacturing of the formulation for the drug. Particle size distribution of ferulic acid powder was in the size range of 10-190 $\mu$m with the mean particle size of 61 $\mu$m. The flowability of ferulic acid was apparently inadequate, indicating the granulation may be necessary for the processing of the drug to solid dosage forms. Two polymorphic forms were obtained by recrystallization from various solvents used in formulation. New polymorphic form of ferulic acid, Form II, was obtained by recrystallization from 1,4-dioxane. The equilibrium solubility for Form I was approximately twice of that for Form II. The dissolution rate of Form II was higher than that of Form I in the early phase (<6 min). Therefore, these physicochemical information has to be taken in the consideration for the formulation of ferulic acid.

On the Pyrolysis of Polymers I. Thermogravimetric Analysis of Polymers (高分子物質의 熱分解에 關한 硏究 (第1報) 熱天秤에 依한 硏究)

  • Chwa-Kyung Sung
    • Journal of the Korean Chemical Society
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    • v.7 no.2
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    • pp.96-105
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    • 1963
  • The weight decrease curves of 18 kinds of polymers have been measured by thermobalance at the same condition where temperature is increased $1^{\circ}C$ per minutes under nitrogen or air atmosphere. The curves are further differentiated to obtain rate curve of weight decrease. Those curve offer a method to compare relative thermal stability, effects of oxygen or modes of thermal degradation of polymers qualitatively. The curves could be classified into following four types: Polystyrene, polymethylmethacrylate and acetal polymer belong to the first type. Those polymers depolymerize mainly into corresponding monomers, weight decrease curves are steepy up to perfect vaporization of polymers and rate curves show a relatively sharp peak. (Type I) Polyvinyl chloride represents the second type. This polymer decomposes with splitting off of hydrogen chloride. The thermogravimetric curve rises rapidly at first, then level off at the moderate weight decrease and gradually rises. Polyvinyl acetate also belongs to this class. (Type II) The modification of the second type is represented by polyester. The curve at the early stage is less steep, the leveling off at the next stage is less clear and the final rising of the curve is steeper than the normal second type. Polyamide, polyurethane, and polycarbonate belong to this type. (Type II') The thermal decomposition of the third type polymers is more complex than that of others. Various irregular chain scissions including side chain splitting and depolymerization to monomers occur simultaneously. The weight of the polymer decreases gradually and the rate curve does not show sharp peaks. Polyvinyl alcohol and diene polymers belong to this type. (Type III) Generally, polycondensation polymers are more stable toward heat than addition polymers and polymers having aromatic nucleus show good thermal stability. Polymers having tertiary carbon atoms such as polystyrene or polypropylene and acetal resin start decomposition under airatmosphere at the temprature below $50^{\circ}C$ or more of the temperature where the polymers start decomposition under nitrogen atmosphere.

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The Efficacy of Active Exercise Programs for Work-Related Chronic Low Back Pain (직업성 만성요통에 대한 능동적 운동프로그램의 효과)

  • Hur, Jin-Gang
    • Journal of Korean Physical Therapy Science
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    • v.11 no.3
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    • pp.38-48
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    • 2004
  • The purpose of present study is to examine the relative efficacy of active exercise programs for work-related chronic low back pain and to figure out how much they affect mechanical stability of lumbar. Subjects are 43 employees with work-related chronic low hack pain, and they were randomly divided into two groups with general physiotherapy groups and thoracic exercise groups for increasing thoracic mobility. Active exercise programs were done 3 times a week, for 6 months, and the subjects were tested for Pain intensity(VAS), the Oswestry Disability Index, Maximal stretching with both hands in the overhead direction and the lumbar region angle of inclination. All subjects were reassessed with same measurement with Pre-study and 6 months after study After applying active exercise programs, pain intensity didn't show any significant difference between two groups. The Oswestry Disability Index showed significant difference between two groups and thoracic exercise groups decreased significantly compare to general physiotherapy group(p<0.05). Maximal stretching with both hands in the overhead direction showed significant difference between two groups and thoracic exercise group increased significantly more than general physiotherapy groups(p<0.05). The lumbar region angle of inclination showed significant difference between two groups and thoracic exercise group decreased significantly more than general physiotherapy groups (p<0.05). According to the results above, exercise for increasing thoracic mobility has an effect on lumbar stability. For the work-related chronic lower hack pain workers, it is far more effective for lumbar stabilization than general physiotherapy.

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The development of a back analysis program for subsea tunnel stability under operation: transversal tunnel section (운영 중 해저 터널의 안정성 평가를 위한 역해석 프로그램 개발: 횡단방향)

  • An, Joon-Sang;Kim, Byung-Chan;Lee, Sang-Hyun;Song, Ki-Il
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.19 no.2
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    • pp.195-212
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    • 2017
  • When back analysis is used for the assessment of an operating subsea tunnel safety in various measurement information such as stress, water pressure and tunnel lining and ground stiffness degradation, the reliable results within tolerable error rate can be obtained. By utilizing a commercial geotechnical analysis program FLAC3D, back analysis can be performed with a DEA which has already been successfully validated in previous studies. However, relative more time-consumption is the drawback of this approach. For this reason, this study introduced beam-spring model-based on FEM solver which uses less analysis time relatively. Beam-spring program capable of structural analysis of a circular tunnel section was developed by using Python language and combined with the built-DEA. From the measurement datum, expected to estimate the stability of an operation tunnel close to real-time.

The Preparation for Sintered Body of $CeO_2$ Based Complex Oxide in Low Temperature Solid Oxide Fuel Cells Using Colloidal Surface Chemistry (콜로이드 계면화학을 이용한 저온형 고체전해질용 $CeO_2$계 복합 산화물의 소결체 제조)

  • 황용신;최성철
    • Journal of the Korean Ceramic Society
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    • v.37 no.7
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    • pp.705-712
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    • 2000
  • In this study, the dispersion stability of CeO2 based complex oxide was studied, and density, porosity, and microstructure of green body were investigated using colloid surface chemistry to manufacture the Gd2O3 doped CeO2 solid electrolyte in an aqueous system. To prepare the stable slurry for slip casting, the dispersion stability was examined as a function of pH using ESA(electrokinetic sonic anplitude) analysis. The dynamic mobility of particles was enhanced with anionic and cationic dispersant were added the amount of 0.5wt% respectively, but pH value in slurries didn't move to below 6.0 because of the influence of dopants. This phenomenon also appeared in the CeO2-Y2O3 and CeO2-Sm2O3 systems, so it could be inferred that rare earth dopants such as Gd2O3, Sm2O3 and Y2O3 not only have the similar motion with changing pH in an aqueous system but also can be dissolved in the range of pH 6.0∼6.5. In CeO2-Gd2O3 system, when the anionic dispersant was added the amount of 0.5wt% and pH value in slurries was fixed at 9.5, the green body density was 4.07g/㎤, and the relative density of sintered body was 95.2%. It could be inferred from XRD analysis that Gd3+ substituted into Ce4+ site because there was no free Gd2O3 peak.

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Physicochemical and Microbiological Characterization of Protected Designation of Origin Ezine Cheese: Assessment of Non-starter Lactic Acid Bacterial Diversity with Antimicrobial Activity

  • Uymaz, Basar;Akcelik, Nefise;Yuksel, Zerrin
    • Food Science of Animal Resources
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    • v.39 no.5
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    • pp.804-819
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    • 2019
  • Ezine cheese is a non-starter and long-ripened cheese produced in the Mount of Ida region of Canakkale, Turkey, with a protected designation of origin status. Non-starter lactic acid bacteria (NSLAB) have a substantial effect on the quality and final sensorial characteristics of long-ripened cheeses. The dominance of NSLAB can be attributed to their high tolerance to the hostile environment in cheese during ripening relative to many other microbial groups and to its ability to inhibit undesired microorganisms. These qualities promote the microbiological stability of long-ripened cheeses. In this study, 144 samples were collected from three dairies during the ripening period of Ezine cheese. Physicochemical composition and NSLAB identification analyses were performed using both conventional and molecular methods. According to the results of a 16S rRNA gene sequence analysis, 13 different species belonging to seven genera were identified. Enterococcus faecium (38.42%) and E. faecalis (18.94%) were dominant species during the cheese manufacturing process, surviving 12 months of ripening together with Lactobacillus paracasei (13.68%) and Lb. plantarum (11.05%). The results indicate that NSLAB contributes to the microbiological stability of Ezine cheese over 12 months of ripening. The isolation of NSLAB with antimicrobial activity, potential bacteriocin producers, yielded defined collections of natural NSLAB isolates from Ezine cheese that can be used to generate specific starter cultures for the production of Ezine cheese (PDO).