• 한국농촌건축학회논문집
• /
• 제2권2호
• /
• pp.115-126
• /
• 2000

Retaining walls are used to prevent excessive movement of retained soils. Typical retaining walls include gravity, reinforced concrete, reinforced earth and tie-back. However, from a practical viewpoint there are still drawbacks among these often constructed retaining walls. New types of retaining walls constructed with precast concrete blocks are proposed. This type of retaining wall is incorporates each blocks interconnected with adjacent block by connecting unit to build up a flexible retaining-wall system. This paper focus to behavior characteristics includes deformation and distribution of lateral earth pressure by loading tests and FEM analysis. For model tests, a 1/10 scale reduce models are manufactured include unevenness part, drainage hole and connecting unit and steel wire used to connect each blocks with adjacent block. To simulate the real retaining walls closely, uneven parts are interconnected each other and the construction type of blocks and wall front inclination are varied to investigate the relative displacement of individual block and the location of maximum deformation of wall as increasing surcharging. Additionally, PENTAGON3D, which solve the geotechnical and other problem, used for verifying and comparing with model tests.

• Bulletin of the Korean Chemical Society
• /
• 제25권1호
• /
• pp.90-96
• /
• 2004

The conformations of dicyclopropyl, isopropyl cyclopropyl, and diisopropylcarbenes were optimized using density functional theory (B3LYP/6-31G(d)). We showed that the optimized geometries of carbenes with cyclopropyl groups are fully in accord with those expected for bisected W-shaped conformations, in which the effective hyperconjugation of a cyclopropyl group with singlet carbene can occur. The stabilization energies were evaluated at the B3LYP/6-311+G(3df, 2p)//B3LYP/6-31G(d) + ZPE level using an isodesmic equation. The relative stability of carbenes is in the order $(c-Pr)_2$C: > (i-Pr)(c-Pr)C: > $(i-Pr)_2$C:, and a cyclopropyl group stabilizes carbene more than an isopropyl group by nearly 9 kcal/mol. Energies for the decomposition of diazo compounds to carbenes increase in the order $(c-Pr)_2$ < (i-Pr)(c-Pr) < $(i-Pr)_2$ by ~9 kcal/mol each. From a singlettriplet energy gap ($E_{ST}$) calculation, the singlet level is lower than the triplet level and the $E_{ST}$ shows a trend similar to the stabilization energy calculations. For comparison, the optimized geometries and stabilization energies for the corresponding carbocations were also studied at the same level of calculation. The greater changes in geometries and the higher stabilization energies for carbocations compared to carbenes can explain the greater hyperconjugation effect.

• Macromolecular Research
• /
• 제14권3호
• /
• pp.359-364
• /
• 2006

Di-block copolymers composed of two biocompatible polymers, poly(ethylene glycol) and poly(D,L-lactide), were synthesized by ring-opening polymerization for preparing polymer vesicles (polymersomes). Emulsion solvent evaporation method was used to fabricate the polymersomes. Scanning electron microscope (SEM) images confirmed that polymersomes have a hollow structure inside. Confocal laser microscope and optical microscope were also used to verify the hollow structure of polymersomes. Polymersomes having various sizes from several hundred nanometers to a few micrometers were fabricated. The size of the polymersomes could be readily controlled by altering the relative hydrodynamic volume fraction ratio between hydrophilic and hydrophobic blocks in the copolymer structure, and by varying the fabrication methods. They showed greatly enhanced stability with increased molecular weight of PEG. They maintained their physical and chemical structural integrities after repeated cycles of centrifugation/re-dispersion, and even after treatment with surfactants.

• Fibers and Polymers
• /
• 제5권4호
• /
• pp.264-269
• /
• 2004

The present paper deals with improvement in disperse dyeablility as well as imparting of cationic dyeablility to difficultly dyeable polypropylene by a melt blending technique. Isotactic polypropylene (PP) was blended with fibre grade polybutylene terephthalate (PBT), cationic dyeable polyethylene terephthalate (CDPET) and polystyrene (PS), individually. The resulting binary blends were spun and drawn into fibres at draw ratio 2, 2.5, and 3. The compatibility of blends, structural changes of fibres in terms of X-ray crystallinity, relative crystallinity, sonic modulus, birefringence and thermal stability were examined. The blended fibres were found to be disperse dyeable by the conventional method of high temperature and high pressure dyeing. And this dye ability increased with increase in the level of substitution. PP/CDPET blend also exhibited dyeablility with cationic dyes in addition to that with disperse dyes. The optimum level of blending was predicted keeping in view of tenacity and thermal stability of melt blend fibres. The wash fastness properties of the dyed fibres were found to be of high rate.

• 한국표면공학회지
• /
• 제49권1호
• /
• pp.87-91
• /
• 2016

The development of high performance transparent electrode with flexibility have been required for flexible electronics. Here, we demonstrate the silver nanowire and reduced graphene oxide hybrid transparent electrode for replacing brittle indium-tin-oxide electrode by spray coating technique and plasma reduction. The spray coating system is applied to deposit silver nanowire and over coated graphene oxide films and it has a great potential to scale-up. The resistance of silver nanowire transparent electrode is reduced by 10% and the surface roughness is decreased after graphene oxide coating. The over-coated graphene oxide is successfully reduced by $H_2$ plasma treatment and it is effective in increasing the environmental stability of electrode. The lifetime of silver nanowire and reduced graphene oxide hybrid electrode at $85^{\circ}C$ of Celsius degree of temperature and 85% of relative humidity has much increased.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2007년도 제38회 하계학술대회
• /
• pp.1534-1535
• /
• 2007

This paper describes a novel microfluidic device with a microfabricated electrospray source for a sheathless electrospray ionization interface to a mass spectrometer. This electrospray ionization-mass spectrometry (ESI-MS) device consists of a triangular-shaped metal emitter, allowing the generation of an efficient electrospray for peptide detection, and microfluidic channels monolithically in a glass microchip. The performance of the proposed interface was evaluated by opimizing its experimental condition and spraying standard peptides. The spraying has high signal strength and stability, with a relative standard deviation of 2.9% and singly-charged and doubly-charged peaks of the peptides were successfully detected. The metal emitter source showed a good performance to be comparable to commercially available emitters in signal strength and stability.

• 한국정밀공학회지
• /
• 제18권12호
• /
• pp.54-59
• /
• 2001

The stability of a thin plate structure is very crucial problem which results buckling. Because the buckling strength of thin plates is lower than the yield strength of the material, reinforcement plate must be used to increase the buckling strength. And, in this case, spot welding is commonly used, however, the spot welded joints are practically designed by experimental decisions, so it is Inefficient and has the risks of buckling demolition. In this study, two parameters, such as the area ratio and the distance ratio of spot welding which have influence on the buckling strength, should be chosen. Under compressive and shearing load, the effect of two parameters on the critical stress is discussed.

• Bulletin of the Korean Chemical Society
• /
• 제13권3호
• /
• pp.306-311
• /
• 1992

The stable structures of pure ethylene and mixed ethylene-ammonia cluster ions are studied using an electron impact ionization time-of-flight mass spectrometer. Investigations on the relative cluster ion distributions of $(C_2H_4)_n(NH_3)_m^+$ under various experimental conditions suggest that $(C_2H_4)_2(NH_3)_3^+$ and $(C_2H_4)_3(NH_3)_2^+$ ions have the enhanced structural stabilities, which give insight into the feasible structure of solvated ions. For the stable configurations of these ionic species, we report an experimental evidence that both $(C_2H4)_2^+(C_2H_4)_3^+$ clusters as the central cations provide three and two hydrogen-bonding sites, respectively, for the surrounding $NH_3$ molecules. This interpretation is based on the structural stability for ethylene clusters and the intracluster ion-molecular rearrangement of the complex ion under the presence of ammonia solvent molecules.

• Geomechanics and Engineering
• /
• 제30권2호
• /
• pp.107-121
• /
• 2022

Coal pillar assessment is of broad importance to underground engineering structure, as the pillar failure can lead to enormous disasters. Because of the highly non-linear correlation between the pillar failure and its influential attributes, conventional forecasting techniques cannot generate accurate outcomes. To approximate the complex behavior of coal pillar, this paper elucidates a new idea to forecast the underground coal pillar stability using combined unsupervised-supervised learning. In order to build a database of the study, a total of 90 patterns of pillar cases were collected from authentic engineering structures. A state-of-the art feature depletion method, t-distribution symmetric neighbor embedding (t-SNE) has been employed to reduce significance of actual data features. Consequently, an unsupervised machine learning technique K-mean clustering was followed to reassign the t-SNE dimensionality reduced data in order to compute the relative class of coal pillar cases. Following that, the reassign dataset was divided into two parts: 70 percent for training dataset and 30 percent for testing dataset, respectively. The accuracy of the predicted data was then examined using support vector classifier (SVC) model performance measures such as precision, recall, and f₁-score. As a result, the proposed model can be employed for properly predicting the pillar failure class in a variety of underground rock engineering projects.

• 한국정밀공학회지
• /
• 제11권5호
• /
• pp.33-41
• /
• 1994

For the establishment of large force standard and the accurate measurement of large force, 2MN hydraulic force standard machine which consists of loading frame, deadweight machine, two ram/cylinder systems and hydraulic control system was designed and fabricated. Measurement results of shapes for tow ram/cylinders reveal that the ratio of effective area is 200.094. The relative deviation of force stability for the machine is about .+-. 0.01% at 2MN and is less than .+-. 0.005% below 2MN. This machine may be widely used to calibrate the force measuring devices in industry and to test the force sensors.