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Preparation of Silicone Polymeric Membrane and Removal of Chlorinated Organic Compounds by Pervaporation (실리콘계 고분자막의 제조와 투과증발법에 의한 유기염소계 화합물 제거)

  • 백귀찬;이용택;김용옥
    • Membrane Journal
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    • v.9 no.2
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    • pp.114-125
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    • 1999
  • Dense polymer membranes were made from vanous silicone polymers such as poly(1-trimethylsilyl-1-propyneHPTMSP), poly(dimethylsiloxaneHPDMS), PTMSP- g-PDMS. These membranes were evaluated in terms of the removal of chlorinated organic hydrocarbons such as chloroform, trichloroethylene(TCE), perchloroethylene(PCE) from water by pervaporation. It was possible for membranes used in this study to remove PCE selectively which is dissolved small quantity in water among other separable solutes. PTMSP membranes exhibited a remarkable decay in permeability with time because of the free volume decreases. However, PTMSP-g-PDMS membrane underwent no physical aging and showed the stable flux behavior. From the results of the contact angle measurement, polymeric membranes used in this study showed affinity with solutes for separation and no affinity with water. The relative swelling degree was directly related to the selectivity, while it has no influence on the flux.

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Fabrication of Molybdenum Silicide-based Composites with Uniformly Dispersed Silicon Carbide (탄화 규소가 균일 분산된 규화 몰리브데넘계 복합재의 제조)

  • Choi, Won June;Park, Chun Woong;Kim, Young Do;Byun, Jong Min
    • Journal of Powder Materials
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    • v.25 no.5
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    • pp.402-407
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    • 2018
  • Molybdenum silicide has gained interest for high temperature structural applications. However, poor fracture toughness at room temperatures and low creep resistance at elevated temperatures have hindered its practical applications. This study uses a novel powder metallurgical approach applied to uniformly mixed molybdenum silicide-based composites with silicon carbide. The degree of powder mixing with different ball milling time is also demonstrated by Voronoi diagrams. Core-shell composite powder with Mo nanoparticles as the shell and ${\beta}-SiC$ as the core is prepared via chemical vapor transport. Using this prepared core-shell composite powder, the molybdenum silicide-based composites with uniformly dispersed ${\beta}-SiC$ are fabricated using pressureless sintering. The relative density of the specimens sintered at $1500^{\circ}C$ for 10 h is 97.1%, which is similar to pressure sintering owing to improved sinterability using Mo nanoparticles.

Does Correction Factor Vary with Solar Cycle?

  • Chang, Heon-Young;Oh, Sung-Jin
    • Journal of Astronomy and Space Sciences
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    • v.29 no.2
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    • pp.97-101
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    • 2012
  • Monitoring sunspots consistently is the most basic step required to study various aspects of solar activity. To achieve this goal, the observers must regularly calculate their own correction factor $k$ and keep it stable. Relatively recently, two observing teams in South Korea have presented interesting papers which claim that revisions that take the yearly-basis $k$ into account lead to a better agreement with the international relative sunspot number $R_i$, and that yearly $k$ apparently varies with the solar cycle. In this paper, using artificial data sets we have modeled the sunspot numbers as a superposition of random noise and a slowly varying background function, and attempted to investigate whether the variation in the correction factor is coupled with the solar cycle. Regardless of the statistical distributions of the random noise, we have found the correction factor increases as sunspot numbers increase, as claimed in the reports mentioned above. The degree of dependence of correction factor $k$ on the sunspot number is subject to the signal-to-noise ratio. Therefore, we conclude that apparent dependence of the value of the correction factor $k$ on the phase of the solar cycle is not due to a physical property, but a statistical property of the data.

Influence of Mother and Peer Attachment on Conflict Resolution Strategies of Children (모애착과 또래애착이 아동의 친구간 갈등해결전략에 미치는 영향)

  • Jung, Sun-Hyun;Lee, Hee-Yeong
    • Journal of Fisheries and Marine Sciences Education
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    • v.24 no.6
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    • pp.793-805
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    • 2012
  • This study investigated the influence of mother and peer attachment on conflict resolution strategies of children. Following research questions were established. First, what is the influence of mother and peer attachment on conflict resolution strategies of children? Second, does the influence of mother and peer attachment on conflict resolution strategies of children differ according to sex? Third, what is the relative influence of mother and peer attachment on conflict resolution strategies of children? 485 fifth graders(male, 184; female, 163) from elementary schools located in Busan participated in this study and completed Inventory of Parent and Peer Attachment and Conflict Resolution Strategies Scale. Collected data were analyzed using t-test, Pearson Correlation Coefficient, Simple Regression and Multiple Regression Analysis. Major findings of this study were summarized as follows: First, both mother and peer attachment influenced on compromising and integration, avoiding and obliging strategies although the degree of influence were different. Second, the influence of mother and peer attachment on conflict resolution strategies differ according to gender. Third, the influence of peer attachment on conflict resolution strategies were greater than the one of mother attachment. Finally the significance of this study were presented with comments on limitations of this study.

Uncertainty Evaluation of the Analysis of Methamphetamine and Amphetamine in Human Hair by GC/MS (GC/MS를 이용한 모발 중 메스암페타민 및 암페타민 분석의 측정불확도 평가)

  • Kim, Jin-Young;Kim, Jong-Sang;Kim, Min-Kyoung;Lee, Jae-Il;Suh, Yong-Jun;In, Moon-kyo
    • YAKHAK HOEJI
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    • v.51 no.3
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    • pp.206-213
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    • 2007
  • Recently estimating the uncertainty of an analytical result has become an essential part of quantitative analysis. This study describes the uncertainty of the measurement for the determination of methamphetamine and its major metabolite amphetamine in human hair, The method consists of washing, drying, weighing, incubation and extraction with methanolic HCI solution, clean-up, trifluoroacetyl derivatization, and qualification/quantification of residues by gas chromatography/mass spectrometry (GC/MS). Traceability of measurement was established through traceable standards and calibrated volumetric equipment and measuring instruments. Measurement uncertainty associated with each analyte in real samples was estimated using quality control (QC) data. The main source of combined standard uncertainty comprised two components, which are uncertainties associated with calibration linearity and variations in QC, while those associated with preparation of analytical standards and sample weighing were not so important considering the degree of contribution. Relative combined standard uncertainties associated with the described method ranged for individual analytes from 4.99 to5.03%.

Fuzzy Inference-based Quantitative Estimation of Environmental Affecting Factor For Performance-based Durability Design of RC Structure Exposed to Salt Attack Environment (염해 환경에 노출된 RC 구조물의 내구성능설계를 위한 퍼지 추론 기반 환경영향지수의 산정)

  • Do Jeong Yun;Song Hun;Soh Seung Young;Soh Yang Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.237-240
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    • 2005
  • As a part of the effort for improving the durability design based on a set of the deem-to-satisfy specifications, it is important and primary to quantitatively identify the environmental impact to a target reinforced concrete structure. In this work, an effort is made to quantitatively calculate the environmental affecting factor with using a fuzzy inference that it indicates the severity of environmental impact to the exposed reinforced concrete structure or member. This system is composed of input region, output region and rule base. For developing the fuzzy inference system surface chloride concentration{chloride), cyclic degree of wet and dry(CWD), relative humidity(RH) and temperature (TEMP) were selected as the input parameter to environmental affecting factor(EAF) of output parameter. The Rules in inference engine are generated from the engineering knowledge and intuition based on some international code of practises as well as various researcher's experimental data. The devised fuzzy inference system was verified comparing the inferred value with the investigation data, and proved to be validated. Thus it is anticipated that this system for quantifying EAF is certain to be considered into the starting point to develop the performance-based durability design considering the service life of structure.

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Output-Feedback Input-Output Linearizing Controller for Nonlinear System Using Backward-Difference State Estimator (후방차분 상태 추정기를 이용한 비선형 계통의 입출력 궤환 선형화 제어기)

  • Kim, Seong-Hwan;Park, Jang-Hyun
    • Journal of IKEEE
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    • v.9 no.1 s.16
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    • pp.72-78
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    • 2005
  • This paper describes the design of a robust output-feedback controller for a single-input single-output nonlinear dynamical system with a full relative degree. While all the previous research works on the output-feedback control are based on dynamic observers, a new state estimator which uses the past values of the measurable system output is proposed. We name it backward-difference state estimator since the derivatives of the output are estimated simply by backward difference of the present and past values of the output. The disturbance generated due to the error between the estimated and real state variables is compensated using an additional robustifying control law whose gain is tuned adaptively. Overall control system guarantees that the tracking error is asymptotically convergent and that all signals involved are uniformly bounded. Theoretical results are illustrated through a simulation example of inverted pendulum.

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A study on the Stability Analysis of Slope in Unsaturated Soil Based on the Soil-Water characteristic curve (함수특성곡선을 고려한 불포화토 사면의 안정성 연구)

  • Yoon, Min-Ki;Kim, Jong-Sung;Kim, Hyo-Jung;Lee, Yeong-Saeng
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.10a
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    • pp.1029-1037
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    • 2008
  • The finite element analysis of transient water flow through unsaturated soils was used to investigate effects of hydraulic characteristics, initial relative degree of saturation, methods to consider boundary condition, and rainfall intensity and duration on water pressure in slopes. The finite element method with shear strength reduction technique was used to evaluate the stability of slopes under rainfall. The slope-related disasters in Korea usually occur between July and September during the typhoon and localized heavy rain. This means that the rainfall is the most important factor that leads to the slope-related disasters. The slope-related disasters can happen at very short time and lead to big damage. To forecast the change of the heave of the groundwater in slope the Seep/w program was used.

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A Hybrid Approach Based on Multi-Criteria Satisfaction Analysis (MUSA) and a Network Data Envelopment Analysis (NDEA) to Evaluate Efficiency of Customer Services in Bank Branches

  • Khalili-Damghani, Kaveh;Taghavi-Fard, Mohammad;Karbaschi, Kiaras
    • Industrial Engineering and Management Systems
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    • v.14 no.4
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    • pp.347-371
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    • 2015
  • A hybrid procedure based on multi-Criteria Satisfaction Analysis (MUSA) and a Network Data Envelopment Analysis (NDEA) is proposed to evaluate the relative efficiency of customer services in bank branches. First, a three-stage process including sub-processes such as customer expectations, customer satisfaction, and customer loyalty, is defined to model the banking customer services. Then, fulfillment of customer expectations, customer loyalty level, and the customer satisfaction degree are measured and quantified through a multi-dimensional questionnaire based on customers' perceptions analysis and MUSA method, respectively. The customer services scores and the other criteria such as mean of employee evaluation score, operation costs, assets, deposits, loans, number of accounts are considered in network three-stage DEA model. The proposed NDEA model is formed based on multipliers perspective, output-oriented, and constant return to scale assumptions. The proposed NDEA model quantifies and assesses the total efficiency of main process and assigns the efficiency to customer expectations, customer satisfactions, and customer loyalties sub-processes in bank branches. The whole procedure is applied on 30 bank branches in IRAN. The proposed approach can be used in other organizations such as airports, airline agencies, urban transportation systems, railway organizations, chain stores, chain restaurants, public libraries, and entertainment centers.

3D numerical model for wave-induced seabed response around breakwater heads

  • Zhao, H.Y.;Jeng, D.S.;Zhang, Y.;Zhang, J.S.;Zhang, H.J.;Zhang, C.
    • Geomechanics and Engineering
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    • v.5 no.6
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    • pp.595-611
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    • 2013
  • This paper presents a three-dimensional (3D) integrated numerical model where the wave-induced pore pressures in a porous seabed around breakwater heads were investigated. Unlike previous research, the Navier-Stokes equation is solved with internal wave generation for the flow model, while Biot's dynamic seabed behaviour is considered in the seabed model. With the present model, a parametric study was conducted to examine the effects of wave and soil characteristics and breakwater configuration on the wave-induced pore pressure around breakwater heads. Based on numerical examples, it was found that the wave-induced pore pressures at breakwater heads are greater than that beneath a breakwater. The wave-induced seabed response around breakwater heads become more important with: (i) a longer wave period; (ii) a seabed with higher permeability and degree of saturation; and (iii) larger angle between the incident waves and breakwater. Furthermore, the relative difference of wave-induced pore pressure between fully-dynamic and quasi-static solutions are larger at breakwater heads than that beneath a breakwater.