• 제목/요약/키워드: Relative Bias

검색결과 268건 처리시간 0.023초

분석기법의 차이에 따른 현장시료의 VOC 분석결과 비교연구: 분석오차의 발생 양상과 원인 (A comparative analysis of volatile organic compound levels in field samples between different gas chromatographic approaches)

  • 안지원;수딜 팬디;김기현
    • 분석과학
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    • 제23권5호
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    • pp.465-476
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    • 2010
  • 본 연구에서는 대기환경시료 및 현장조건에서 채취한 현장시료들 중, 악취성분 및 주요 VOC 성분들 중에서 여러 유형의 관리대상으로 지정 중인 benzene, toluene, p-xylene, styrene, methyl ethyl ketone의 농도분석 방식들을 비교하였다. 이때, GC/FID와 튜브를 연계한 F-T 분석방식과 GC/MS와 백(bag)을 연계한 M-B방식으로 같은 시료를 각각 분석하고 이들 결과 값을 비교하였다. 상관분석결과, toluene과 pxylene에서 F-T와 M-B방법간의 결과에서 큰 상관성을 보이는 것으로 나타났다(P < 1.4E-08). 양 기기간의 오차를 percent difference (PD)와 같이 산술적으로 구하여 평가한 결과, benzene과 toluene의 농도는 상대적으로 비슷한 경향을 보였다. 그러나 분석대상 성분들 간에 양 방식의 차이는 평균적으로 35%가 넘으면서 F-T와 M-B간의 오차가 일정 수준이상으로 존재하였다. 그리고 F-T/M-B ratio가 대부분 1 이하로 나타나면서, M-B의 결과 값이 F-T에 비해 상대적으로 크게 나타나는 경향을 보였다. 양 분석기기로부터 산출한 결과 값을 통계적으로 판단하기 위해, t-test를 실시하였다. 그 결과, 95% 신뢰수준에서 toluene, pxylene, styrene, methyl ethyl ketone 성분에서는 두 시스템간의 결과 값에 차이가 유의한 것으로 나타났다(P < 0.043). 그러나 전반적으로 양 분석기법의 차이에 따른 오차는 상당 부분 선택한 표준시료의 성상 및 백내부의 시료손실 등과 같은 요인에 크게 영향을 받는 것으로 나타났다.

Electron Tunneling and Electrochemical Currents through Interfacial Water Inside an STM Junction

  • Song, Moon-Bong;Jang, Jai-Man;Lee, Chi-Woo
    • Bulletin of the Korean Chemical Society
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    • 제23권1호
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    • pp.71-74
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    • 2002
  • The apparent barrier height for charge transfer through an interfacial water layer between a Pt/Ir tip and a gold surface has been measured using STM technique. The average thickness of the interfacial water layer inside an STM junction was controlled by the amount of moisture. A thin water layer on the surface was formed when relative humidity was in the range of 10 to 80%. In such a case, electron tunneling through the thin water layer became the majority of charge transfers. The value of the barrier height for the electron tunneling was determined to be 0.95 eV from the current vs. distance curve, which was independent of the tip-sample distance. On the other hand, the apparent barrier height for charge transfer showed a dependence on tip-sample distance in the bias range of 0.1-0.5 V at a relative humidity of approximately 96%. The non-exponentiality for current decay under these conditions has been explained in terms of electron tunneling and electrochemical processes. In addition, the plateau current was observed at a large tip-sample distance, which was caused by electrochemical processes and was dependent on the applied voltage.

2차원 광화학수송모델을 이용한 포항지역의 1995-1996년 기간동안 오존의 연직 프로파일 및 전량 추정 (Estimation of Vertical Profiles and Total Amount of Ozone Using Two-Dimensional Photochemical Transfer Model During the Period of 1995-1996 at Pohang)

  • 문윤섭
    • 한국대기환경학회지
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    • 제22권3호
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    • pp.271-285
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    • 2006
  • A two-dimensional photochemical transport model (2D PTM) is simulated to describe the transport and chemical reaction of ozone related to aerosols in the troposphere and stratosphere. The vertical profiles and total amounts of ozone, which are advected by both residual Eulerian circulation and the adiabatic circulation under certain circumstance, have been compared with the observation data such as ozonesondes, Brewer spectrometer, the Upper Atmosphere Research Satellite (UARS), and the Total Ozone Mapping Spectrophotometer (TOMS). As a result, we find that the observed distribution of ozone Is adequately reproduced in the model at middle and high latitude in the Northern Hemisphere as well as at Phang ($36^{\circ}\;02'N,\;129^{\circ}\;23'E$) in South Korea. In particular, the 2D PTM is well simulated in the ozone decrease due to the Pinatubo volcanic eruption in 1991. However, ozone mixing ratio are more underestimated than those of UARS and ozonesondes, because are very sensitive to the latitude of transport across the tropopause associated with both Rummukainen errors and off-line model. Relative mean bias errors and relative root mean square errors of ozone calculations using the 2D PTM are shown within${\pm}10%$, respectively.

만성피로증후군에 대한 보중익기탕과 그 변방의 효과 : 체계적인 문헌고찰 (The Effectiveness of Bojungikgi-tang and its modifications on Chronic Fatigue Syndrome: A Systematic Review And Meta-analysis)

  • 남동현
    • 대한한의학회지
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    • 제41권1호
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    • pp.93-106
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    • 2020
  • Objectives: The aim of this review is to ascertain whether Bojungikgi-tang and its modifications is more effective than non-specific management in chronic fatigue syndrome (CFS). Methods: We collected clinical trials to investigate the effects of Bojungikgi-tang and non-specific management on general symptoms, fatigue, and sleep quality in CFS patients. The databases used for data retrieval were Pubmed, Central Cochrane, CNKI, VIP, CiNii, OASIS, RISS, and Koreamed. We performed selection/exclusion process from the found records according to prespecified criteria, and assessed the final included trials according to the Cochrane risk of bias tool. The included studies were classified on the basis of interventions in experimental group. Results: Seven randomized controlled trials (476 participants) were eligible and their results were synthesized in the meta-analysis. The synthesis showed a substantial effect of Bojungikgi-tang (relative risk 0.20 [95% CI 0.13 to 0.31], Z=7.44, P<0.00001; I2=0%) and combination of Bojungikgi-tang and Sosiho-tang (relative risk 0.15 [95% CI 0.08 to 0.28], Z=5.85, P<0.00001; I2=0%) compared with non-specific management on improvement of general symptoms. However, we could not find sufficient clinical research records to determine their effects of improvement on fatigue and sleep quality. Conclusions: Bojungikgi-tang and its modifications are more effective than non-specific management for improvement of general symptoms in CFS post-treatment.

한반도 연근해 저층 트롤 조사 자료에 표본론을 적용한 개체군의 상대적 크기 추정 (Application of Sampling Theories to Data from Bottom Trawl Surveys Along the Korean Coastal Areas for Inferring the Relative Size of a Fish Population)

  • 이효태;현상윤
    • 한국수산과학회지
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    • 제50권5호
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    • pp.594-604
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    • 2017
  • The Korean National Institute of Fisheries Science (NIFS) has biannually (spring and fall, respectively) deployed a bottom trawl survey along the coastal areas for last decade, taking samples on a regular basis (i.e., a systematic sampling). Despite the availability of the survey data, NIFS has not yet officially reported the estimates of the groundfish population sizes as well as has not evaluated uncertainty of the estimates. The objectives of our study were to infer the relative size of a fish population, applying two different sampling techniques (namely simple and stratified sampling) with different observation units to the NIFS survey data, and to compare those two techniques in bias and precision. For demonstration purposes, we used data on Pacific cod (Gadus macrocephalus) collected by the 2011-2015 surveys, and the results of simple and stratified sampling showed that the point estimates and precision varied by observation unit as well as the sampling technique.

Studies on Synonymous Codon and Amino Acid Usage Biases in the Broad-Host Range Bacteriophage KVP40

  • Sau Keya;Gupta Sanjib Kumar;Sau Subrata;Mandal Subhas Chandra;Ghosh Tapash Chandra
    • Journal of Microbiology
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    • 제45권1호
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    • pp.58-63
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    • 2007
  • In this study, the relative synonymous codon and amino acid usage biases of the broad-host range phage, KVP40, were investigated in an attempt to understand the structure and function of its proteins/protein-coding genes, as well as the role of its tRNAs. Synonymous codons in KVP40 were determined to be AT-rich at the third codon positions, and their variations are dictated principally by both mutational bias and translational selection. Further analysis revealed that the RSCU of KVP40 is distinct from that of its Vibrio hosts, V. cholerae and V. parahaemolyticus. Interestingly, the expression of the putative highly expressed genes of KVP40 appear to be preferentially influenced by the abundant host tRNA species, whereas the tRNAs expressed by KVP40 may be required for the efficient synthesis of all its proteins in a diverse array of hosts. The data generated in this study also revealed that KVP40 proteins are rich in low molecular weight amino acid residues, and that these variations are influenced primarily by hydropathy, mean molecular weight, aromaticity, and cysteine content.

A Study on the Impact Analysis of Security Flaws between Security Controls: An Empirical Analysis of K-ISMS using Case-Control Study

  • Kim, Hwankuk;Lee, Kyungho;Lim, Jongin
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제11권9호
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    • pp.4588-4608
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    • 2017
  • The measurement of information security levels is a very important but difficult task. So far, various measurement methods have studied the development of new indices. Note, however, that researches have focused on the problem of attaining a certain level but largely neglecting research focused on the issue of how different types of possible flaws in security controls affect each other and which flaws are more critical because of these effects. Furthermore, applying the same weight across the board to these flaws has made it difficult to identify the relative importance. In this paper, the interrelationships among security flaws that occurred in the security controls of K-ISMS were analyzed, and the relative impact of each security control was measured. Additionally, a case-control study was applied using empirical data to eliminate subjective bias as a shortcoming of expert surveys and comparative studies. The security controls were divided into 2 groups depending on whether or not a security flaw occurs. The experimental results show the impact relationship and the severity among security flaws. We expect these results to be applied as good reference indices when making decisions on the removal of security flaws in an enterprise.

Event-specific Detection Methods for Genetically Modified Maize MIR604 Using Real-time PCR

  • Kim, Jae-Hwan;Kim, Hae-Yeong
    • Food Science and Biotechnology
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    • 제18권5호
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    • pp.1118-1123
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    • 2009
  • Event-specific real-time polymerase chain reaction (PCR) detection method for genetically modified (GM) maize MIR604 was developed based on integration junction sequences between the host plant genome and the integrated transgene. In this study, 2 primer pairs and probes were designed for specific amplification of 100 and 111 bp DNA fragments from the zSSIIb gene (the maize endogenous reference gene) and MIR604. The quantitative method was validated using 3 certified reference materials (CRMs) with levels of 0.1, 1, and 10% MIR604. The method was also assayed with 14 different plants and other GM maize. No amplification signal was observed in real-time PCR assays with any of the species tested other than MIR604 maize. As a result, the bias from the true value and the relative deviation for MIR604 was within the range from 0 to 9%. Precision, expressed as relative standard deviation (RSD), varied from 2.7 to 10% for MIR604. Limits of detections (LODs) of qualitative and quantitative methods were all 0.1%. These results indicated that the event-specific quantitative PCR detection system for MIR604 is accurate and useful.

국지예보모델에서 고해상도 마이크로파 위성자료(MHS) 동화에 관한 연구 (A Study on the Assimilation of High-Resolution Microwave Humidity Sounder Data for Convective Scale Model at KMA)

  • 김혜영;이은희;이승우;이용희
    • 대기
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    • 제28권2호
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    • pp.163-174
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    • 2018
  • In order to assimilate MHS satellite data into the convective scale model at KMA, ATOVS data are reprocessed to utilize the original high-resolution data. And then to improve the preprocessing experiments for cloud detection were performed and optimized to convective-scale model. The experiment which is land scattering index technique added to Observational Processing System to remove contaminated data showed the best result. The analysis fields with assimilation of MHS are verified against with ECMWF analysis fields and fit to other observations including Sonde, which shows improved results on relative humidity fields at sensitive level (850-300 hPa). As the relative humidity of upper troposphere increases, the bias and RMSE of geopotential height are decreased. This improved initial field has a very positive effect on the forecast performance of the model. According to improvement of model field, the Equitable Threat Score (ETS) of precipitation prediction of $1{\sim}20mm\;hr^{-1}$ was increased and this impact was maintained for 27 hours during experiment periods.

확률 분포형의 극치 수문량 예측 능력 평가에 관한 연구 (A Study on the Estimation of Extreme Quantile of Probability Distribution)

  • 정진석;신홍준;안현준;허준행
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2017년도 학술발표회
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    • pp.399-400
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    • 2017
  • 홍수나 가뭄 등 극치 현상의 통계분석 및 빈도해석에 있어 극치분포형이 널리 사용되고 있으며, 이러한 극치분포형의 특성을 이해하기 위해서는 분포형의 오른쪽 꼬리(right tail) 부분 특성을 자세히 분석할 필요가 있다. 이에 따라 본 연구에서는 Monte Carlo 모의를 통하여 다양한 극치분포형의 오른쪽 꼬리 부분의 통계적 특성 및 그 예측 능력을 연구하였다. 극치분포형으로는 우리나라 확률수문량 산정에 널리 활용되고 있는 generalized extreme value (GEV), Gumbel, generalized logistic 분포를 사용하였으며, 매개변수 산정 방법으로는 확률가중모멘트법을 사용하였다. 모의실험의 모분포로는 수문빈도해석에서 많이 사용되는 GEV 분포를 사용하였고, 30년 이상 자료를 보유한 기상청 지점 자료의 왜곡도를 조사하여 모의실험에 사용되는 모집단의 왜곡도로 가정하여 표본 자료를 발생시켰다. 예측 능력의 평가는 재현기간 10~1000년의 확률수문량을 왜곡도계수를 고려한 GEV 도시위치공식을 이용하여 GEV 확률지에 도시하고, 평균제곱근오차(root mean square error), 편의(bias), 평균상대오차(mean relative difference), 평균절대상대오차(mean absolute relative difference)를 이용하여 최적 분포형을 선정함으로써 이루어진다. 또한 예측 능력 평가결과의 타당성 확인을 위해 극치분포형의 적합정도를 잘 나타낸다고 알려진 modified Anderson-Darling 방법의 검정결과와 비교하여 적절성을 확인하였다.

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