• New & Renewable Energy
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• v.3 no.1 s.9
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• pp.54-59
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• 2007

A sintering aid, $B_{2}O_{3}$ have been included into a $LiAlO_{2}$ electrolyte support by a tape casting method in order to reinforce mechanical strength of the support for molten carbonate fuel cells [MCFCs). Starting idea originates from the low melting point of $B_{2}O_{3}$ ($450^{\circ}C$), which can provide the low temperature consolidation of ceramic materials. The mechanical properties and the microstructure changes of the $B_{2}O_{3}$-included electrolyte support were examined by scanning electron microscope, mercury porosimetry, X-ray powder diffraction [XRD], high temperature differential scanning calorimeter and three-point bending strength measurement. The mechanical strength was clearly improved by addition of $B_{2}O_{3}$. The increase of mechanical strength results from the neck growth of a new $LiAlO_{2}$ phase between $LiAlO_{2}$ particles by the liquid phase sintering. Average pore size and porosity of the electrolyte support reinforced by addition of the sintering aid, $B_{2}O_{3}$, was $0.24{\mu}m$ and 59%, respectively which were suitable microstructure of a matrix for an application of MCFCs.

• Journal of Powder Materials
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• v.11 no.6 s.47
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• pp.462-466
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• 2004

The bi-materials composed of $Al-5wt{\%}Mg$ and its composite reinforced with SiC particles were prepared by ball-milling and subsequent sintering process. The size of powder in Al-Mg/SiCp mixture decreased with increasing ball-milling time, it was saturated above 30 h when the ball and powder was in the ratio of 30 to 1. Both $Al-5wt{\%}Mg$ powders mixture and $Al-5wt{\%}Mg/SiCp$ mixture were compacted under a pressure of 350MPa and were bonded by sintering at temperatures ranging from 873K to 1173K for 1-5h. At 873k, the sound bi-mate-rials could not be obtained. In contrast, the bi-materials with the macroscopically well-bonded interface were obtained at higher temperatures than 873K. The length of well-bonded interface became longer with increasing temperature and time, indicating the improved contact in the interface between unreinforced Al-Mg part and Al-Mg/SiCp composite part. The relative density in the bi-materials increased as the sintering temperature and time increased, and the bi-materials sintered at 1173K for 5h showed the highest density.

• Journal of The Korean Society of Agricultural Engineers
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• v.47 no.5
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• pp.27-39
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• 2005

In the recent design of high ductile fiber-reinforced ECC (engineered cementitious composite), optimizing both processing and mechanical properties for specific applications is critical. This study presents an innovative method to develop new class ECCs, which possess the different fluid properties to facilitate diverse types of processing (i.e., self-consolidating or shotcrete processing) while maintaining ductile hardened properties. In the material design concept, we employ a parallel control of fresh and hardened properties by using micromechanics and cement rheology. Control of colloidal interaction between the particles is regarded as a key factor to allow the performance of the specific processing. To determine how to control the particle interactions and the viscosity of cement suspension, we first introduce two chemical admixtures including a highly charged polyelectrolyte and a non-ionic polymer. Optimized mixing steps and dosages we, then, obtained within the solid concentration predetermined based on micromechanical principle. Test results indicate that the rheological properties altered by this approach were revealed to be highly effective in obtaining the desired function of the fresh ECC, allowing us to readily achieve hardened properties, represented by pseudo strain-hardening behavior in uniaxial tension.

• Journal of Powder Materials
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• v.10 no.1
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• pp.15-20
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• 2003

Hybrid $A1_2O_3-TiC$ ceramic particle reinforced 6061 and 5083 Al composite powders were prepared by the combination of twin rolling and stone mill crushing process, followed by consolidating processes of cold compaction, degassing and hot extrusion. The composite bar consists of lamellar structure of ceramic particle rich area and matrix area, in which the hybrid was decomposed into each TiC of about $3-4\mutextrm{m}$ and $AI_2O_3$ particles of about $1-2\mutextrm{m}$ in diameter. It also found that fine $Mg_2Si$ precipitates of about 30 nm were embedded in the matrix, which have grains of about 3 $\mutextrm{m}$. Higher UTS was measured at the 5083 composite bar compared to the conventionally fabricated composite, due to again refinement effect by the rapid solidification. No particle was shown to form in the interface between the matrix and reinforcement, whereas carbon was diffused into the matrix.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2003.10a
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• pp.54-54
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• 2003

We have developed a Cu-based bulk amorphous composite reinforced with a micron-sized crystalline phase, the (Cu60Zr30Ti10)95Ta5 amorphous matrix composite. The composite demonstrates the ultimate strength of 2332 MPa with a dramatically enhanced fracture strain of 15.3 %. Macroscopic observation of the fractured (Cu60Zr30Ti10)95Ta5 amorphous matrix composite showed the development of multiple shear bands along with numerous branching and deflection of shear bands. Microscopic observation on the amorphous matrix of the composite showed that cracks propagate through the residual amorphous matrix located between nanocrystallites, which had formed during deformation. Simulations based on finite element method were conducted to understand the formation mechanisms of multiple shear bands, the initiation site of shear bands, and interaction of shear bands with crystalline particles. Other microscopic fracture mechanism responsible for the enhanced plasticity was discussed.

• International Journal of CAD/CAM
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• v.12 no.1
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• pp.20-28
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• 2012

Finite Element Analysis (FEA) is often used to identify local stress/strain concentrations where a component is likely to fail. In order to reduce the degree of strain concentration, component thickness can be increased in those regions, or a stronger material can be used. In short fiber reinforced composite materials, strength and stiffness can be increased through proper fiber alignment. The field-aided microtailoring (FAiMTa) process is one promising method for doing this. FAiMTa uses principles of dielectrophoresis to preferentially align particles or fibers within a matrix. To achieve the preferred fiber orientation, an interdigitated electrode network must be integrated into the mold halves which can be fabricated by additive manufacturing (AM) processes. However, the process of determining the preferred fiber arrangements and electrode locations can be very challenging. This paper presents algorithms to semi-automate the interdigitated electrode design process. The algorithm has been implemented in the Solidworks CAD system and is demonstrated in this paper.

• Elastomers and Composites
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• v.29 no.1
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• pp.18-29
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• 1994

The purpose of this study is to investigate reinforced effect between silica treated by coupling agents and rubber matrix under the configuration chemical bonds, and the effect of silica particles coated by organic polymers using aluminum chloride as the catalyst. In vulcanization characteristies were tested by Curastometer. The M-series vulcanizates were reached to the fastest optimum cure $time(t_{90})$ and R-series vulcanizates with the same formula had the shorted optimum cure times. Tensile characteristics measuring with a tensile tester revealed that the M-series vulcanizate was the best in the physical properties, such as tensile strength. In 100% modulus, however, the S-series vulcanizates appeared to be better than the other vulcanizates. Also, hardness showed the following order : S-series>R-series>M-series with the order of elongation R-series>M-series>S-series. In SEM test, shapes of chemical treated silicas were observed. The dispersion of filler in the SBR composite appeard uniformly. In RDS test for the dynamic characteristics, G' indicates that S-3 shows the highest value with the next order M-3>R-3, and the order of damping values are as followe: M-3>M-3>R-3.

• Journal of the Korean Wood Science and Technology
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• v.18 no.4
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• pp.9-17
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• 1990

When manufacturing beam by laminating particleboards, the mechanical properties of particleboad-laminated beam would be also improved if the properties, especially mechanical properties of particleboad be reinforced. In this study, steel wires were used to reinforce particleboard. This study was carried out to obtain the basic mechanical properties of the board composed of wood particle and steel wires, focusing on bending strength which is the important factors in laminated beam and it was tried to estimate the relationship between the properties of the particleboard-laminated beam. and the proportion of steel wires to wood particles in particleboards. The result obtained can be summarized as follows: 1. The more steel wires used in boards, the higher value of modulus of rupture in bending was obtained, For example. the density 5 board composed of 14 numbers of steel wires showing 55% improved value than control board. 2. The board with lower density was also made better in higher value of elasticity, the density 0.5 board with 14 numbers of steel wires improved by 170%, the density 0.6 board by 86%, the 0.7 board by 37% and the 0.8 board by 26%. 3. The work to maximum load was improved with more steel wires. for example, the density 0.8 board with 14 numbers of steel wires improved by 31%.

• Journal of Powder Materials
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• v.27 no.5
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• pp.365-372
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• 2020

Predicting the quality of materials after they are subjected to plasma sintering is a challenging task because of the non-linear relationships between the process variables and mechanical properties. Furthermore, the variables governing the sintering process affect the microstructure and the mechanical properties of the final product. Therefore, an artificial neural network modeling was carried out to correlate the parameters of the spark plasma sintering process with the densification and hardness values of Ti-6Al-4V alloys dispersed with nano-sized TiN particles. The relative density (%), effective density (g/㎤), and hardness (HV) were estimated as functions of sintering temperature (℃), time (min), and composition (change in % TiN). A total of 20 datasets were collected from the open literature to develop the model. The high-level accuracy in model predictions (>80%) discloses the complex relationships among the sintering process variables, product quality, and mechanical performance. Further, the effect of sintering temperature, time, and TiN percentage on the density and hardness values were quantitatively estimated with the help of the developed model.

• Journal of Korea Foundry Society
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• v.13 no.4
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• pp.350-358
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• 1993

Aluminum base composites reinforced with various amount of SiC particles and Mg contents have been investigated by different fabrication method for twenty-years. In this paper, how the decomposition and dissolution behaviors of $SiCp(20{\mu}m)$ in the melt of Al composites arised was studied. As the results, the decomposition and dissolution of SiCp into the melt of Al composites increased with increase of the temperature above $720^{\circ}C$, and holding time at a given melting temperature. Because SiC is thermodynamically unstable in this Al-SiCp composite at temperature above the liquidus, SiCp dissolves and reacts with Al in matrix to form $Al_4C_3$ according to following chemical equation $4Al+3SiC{\rightarrow}Al_4C_3+3Si$, Si decomposed and dissolved from SiCp increases Si content of matrix, while liquidus temperature of matrix decrease with increase of SiC content in matrix. The hardness of SiCp decreased with increase of the melting temperature, the hardness of the matrix /particle interface increased with increase of the melting temperature due to increase of the $Mg_2Si$ and $Al_4C_3$ intermetallic compounds, etc.