• Title/Summary/Keyword: Refractory applications

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Modeling refractory concrete lining of fluid catalytic cracking units of oil refineries

  • Silva, Ana B.C.G.;Andrade, Henrique C.C.;Fairbairn, Eduardo M.R.;Telles, Jose C.F.;Ribeiro, Fernando L.B.;Toledo-Filho, Romildo D.;Medeiros, Jorivaldo
    • Computers and Concrete
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    • v.25 no.1
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    • pp.29-36
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    • 2020
  • This work presents a numerical modeling procedure to simulate the refractory concrete lining in fluid catalytic cracking units of oil refineries. The model includes the simulation of the anchors that reinforce the contact between the refractory concrete and the steel casing. For this purpose, the constitutive relations of an interface finite element are set to values that represent the homogenized behavior of the anchored interface. The parameters of this constitutive relation can be obtained by experimental tests. The model includes also multi-surface plasticity, in order to represent the behavior of the refractory concrete lining. Since the complexity of real case applications leads to high computational costs, the models presented here were implemented in a high-performance parallelized finite element platform. A case study representing a riser similar to the ones used by the refinery industry demonstrates the potential of the model.

Decomposition Behavior of Ferro-Si3N4 for High Temperature Refractory Application (고온 내화물 응용을 위한 질화규소철 (Ferro-Si3N4)의 분해거동)

  • Choi, Do-Mun;Lee, Jin-Seok;Choi, Sung-Churl
    • Journal of the Korean Ceramic Society
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    • v.43 no.9 s.292
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    • pp.582-587
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    • 2006
  • Decomposition behavior of $ferro-Si_3N_4$was investigated with varying temperature and holding time in mud components for high temperature refractory applications. Porosities gradually increased with increasing temperature and holding time due to the carbothermal reduction of $Si_3N_4\;and\;SiO_2$. Silicon monoxide (SiO) as a intermediate resulted from evaporation of $Si_3N_4\;and\;SiO_2$ reacted with C sources to generate needle-like ${\beta}-SiC$ and Fe in $Si_3N_4$ acted as a catalyst in order to enhance growth of SiC grain with the preferred orientation. SiC generation yield increased with increasing holding time, all of the $Si_3N_4\;and\;SiO_2$ affected on SiC formation up to 2h. However, SiC generation was only dependent on residual $SiO_2$ over 2h, because the carbothermal reduction reaction of $Si_3N_4$ was no longer possible at that time.

Fabrication of Pure Refractory Metals by Resistance Sintering under Ultra High Pressure

  • Zhou, Zhang-Jian;Du, Juan;Song, Shu-Xiang;Ge, Chang-Chun
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1323-1324
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    • 2006
  • Refractory materials, such as W and Mo, are very useful elements for use in high-temperature applications. But it is not easy to fabricat pure W and Mo with very high density and retaining very fine grain size because of their high melting point. In this paper, a newly developed method named as resistance sintering under ultra high pressure was use to fabricate pure fine-grained W and Mo. The microstructure was analysis by SEM. The sintering mechanism is primary analyzed. Basic physical property of these sintered pure W and Mo, such as hardness, bend strength, are tested.

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NEW PROGRESS IN TiN-BASED PROTECTIVE COATINGS DEPOSITED BY ARC ION PLATING

  • Huang, R.F.;Wen, L.S.
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.265-275
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    • 1999
  • Titanium nitride and related overlayers produced by arc ion plating (AIP) are applied as commercial coatings in world-wide scale since the middle of 80s. Due to the achievements of low temperature deposition (LTD), they begin now to be used as wear and corrosion-resistant coatings for machine parts, besides applications on cemented carbide and high speed steel cutting tools. On the other side, TiN can be now applied successfully to brass, Al-alloy, ZnAl alloy articles as decorative coating through LTD. Various nitrides, carbonitrides, borides and other refractory compounds, such as (Ti, Al)N, TiCN, CrN, are used as the coatings for special heavy-duty working conditions instead of TiN since 90s. More and more multilayer coatings are applied now substituting single layer ones. Duplex processes are under development.

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Current clinical applications of platelet-rich plasma in various gynecological disorders: An appraisal of theory and practice

  • Dawood, Ayman Shehata;Salem, Hesham Abdelaziz
    • Clinical and Experimental Reproductive Medicine
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    • v.45 no.2
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    • pp.67-74
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    • 2018
  • The purpose of this paper is to review the current clinical uses of platelet-rich plasma (PRP) in the field of gynecology. All relevant articles published from January 2000 to December 2017 were reviewed and analyzed. The articles on PRP in the field of gynecology were mainly case series, pilot studies, or case reports. PRP is currently considered a new therapeutic modality for some disorders that are refractory to conventional drugs.

Aerosol Mass Spectrometer (AMS)-Based Real-Time Physicochemical Characterization of Atmospheric Aerosols

  • Kim, Donghwi
    • Mass Spectrometry Letters
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    • v.13 no.2
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    • pp.27-34
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    • 2022
  • Atmospheric aerosols have become a major environmental concern because of their adverse effects on human health, air quality, and climate change. Over the last few decades, several mass spectrometry (MS)-based techniques have been developed and applied in the field of atmospheric aerosol research. Particularly, real-time measurement of ambient aerosols using an aerosol mass spectrometer (AMS) has become one of the most powerful tools for aerosol chemistry. This review provides a brief description of AMS and its applications for understanding the physicochemical properties of atmospheric aerosols, as well as its sources and evolution processes.

The Coupling Effects of Excitatory and Inhibitory Connections Between Chaotic Neurons Having Gaussian-shaped Refractory Function With Hysteresis

  • Park, Changkyu;Lee, Ju-Jang
    • 제어로봇시스템학회:학술대회논문집
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    • 1998.10a
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    • pp.356-361
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    • 1998
  • Neural Networks, modeled succinctly from the real nervous system of a living body, can be categorized into two folds; artificial neural network(ANN) and biological neural network(BNN). While the former has been developed to solve practical problems using function approximation capability, pattern classification) clustering algorithm, etc, the latter has been focused on verifying the information processing capability to which brain research gives an impetus, by mimicking real biological systems. However, BNN suffers Iron severe nonlinearities dealt with. A bridge between two neural networks is chaotic neural network(CNN), which simply delineate the real nor-vous system and comprises almost all the ANN structures by selecting parameters. Main research theme of this area is to develop an explanation tool to clarify the information processing mechanism in biological systems and its extension to engineering applications. The CNN has a Gaussian-shaped refractory function with hysteresis effect and the chaotic responses of it have been observed fur a wide range of parameter space. Through the examination of the coupling effects of excitatory and inhibitory connections, the secrets of information processing and memory structure will appear.

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The applications of ozone-based advanced oxidation processes for wastewater treatment: A review

  • Hussain, Mujtaba;Mahtab, Mohd Salim;Farooqi, Izharul Haq
    • Advances in environmental research
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    • v.9 no.3
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    • pp.191-214
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    • 2020
  • The rise in population and industrialization accounts for the generation of a huge amount of wastewaters. The treatment of this wastewater is obligatory to safeguard the environment and various life forms. Conventional methods for high strength wastewater treatment coming out to be ineffective. Advanced oxidation processes (AOPs) for such wastewater treatment proved to be very effective particularly for the removal of various refractory compounds present in the wastewater. Ozone based AOPs with its high oxidizing power and excellent disinfectant properties is considered to be an attractive choice for the elimination of a large spectrum of refractory compounds. Furthermore, it enhances the biodegradability of wastewaters after treatment which favors subsequent biological treatments. In this review, a detailed overview of the AOPs (like the Fenton process, photocatalysis, Electrochemical oxidation, wet air oxidation, and Supercritical water oxidation process) has been discussed explicitly focusing on ozone-based AOPs (like O3, O3/H2O2, O3/UV, Ozone/Activated carbon process, Ozone/Ultrasound process, O3/UV/H2O2 process). This review also comprises the involved mechanisms and applications of various ozone-based AOPs for effective municipal/industrial wastewaters and landfill leachate treatment. Process limitations and rough economical analysis were also introduced. The conclusive remarks with future research directions also underlined. It was found that ozonation in combination with other effective AOPs and biological methods enhances treatment efficacies. This review will serve as a reference document for the researchers working in the AOPs field particularly focusing on ozone-based AOPs for wastewater treatment and management systems.

Carbon Fiber Reinforced Ceramics based on Reactive Melt Infiltration Processes

  • Lenz, Franziska;Krenkel, Walter
    • Journal of the Korean Ceramic Society
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    • v.49 no.4
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    • pp.287-294
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    • 2012
  • Ceramic Matrix Composites (CMCs) represent a class of non-brittle refractory materials for harsh and extreme environments in aerospace and other applications. The quasi-ductility of these structural materials depends on the quality of the interface between the matrix and the fiber surface. In this study, a manufacture route is described where in contrast to most other processes no additional fiber coating is used to adjust the fiber/matrix interfaces in order to obtain damage tolerance and fracture toughness. Adapted microstructures of uncoated carbon fiber preforms were developed to permit the rapid infiltration of molten alloys and the subsequent reaction with the carbon matrix. Furthermore, any direct reaction between the melt and fibers was minimized. Using pure silicon as the reactive melt, C/SiC composites were manufactured with an aim of employing the resulting composite for friction applications. This paper describes the formation of the microstructure inside the C/C preform and resulting C/C-SiC composite, in addition to the MAX phases.

Ionio conductivity of solid solution ceramics in the system of $CaO-Y_{2}O_{3}-ZrO_{2}$ Prepared by SHS

  • Soh, Deawha;Korobova, N.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.211-214
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    • 2001
  • The undesirable phase transformation of zirconium dioxide at high temperatures can be eliminated by stabilization of the cubic phase with an addition of a selected alkaline earth or rare-earth oxide. In this paper the ionic conductivity of cubic solid solutions in the stabilized ZrO$_2$ by CaO-Y$_2$O$_3$ system was examined. The higher ionic conductivity appears to be related to lower activation energy rather than to the number of oxygen vacancies dictated by composition. Those compositions of highest conductivity lie close to the cubic-monoclinic solid-solution phase boundary. Conductivity temperature data are presented that indicate a reversible order-disorder transition for Zr$_2$2-Y$_2$O$_3$cubic solid solutions containing 20 and 25 mole % $Y_2$O$_3$.

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