• 자원리싸이클링
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• 제30권6호
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• pp.53-60
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• 2021

현재 EAF 전기로 제강공정에서는 슬래그 중의 MgO 함량을 증가시켜 탈황능과 내화재 수명을 개선시키고자 돌로마이트(백운석) 용제(Flux)를 첨가하고 있으며, 또한 에너지효율을 증가시키기 위해 용강 중에 가탄재를 취입하고 있다. 이러한 견지에서 폐 MgO-C계 내화재를 재활용하는 연구를 진행하였다. 폐 MgO-C계 내화재는 MgO(>70%)과 탄소(>10%)를 대량 함유하고 있기 때문이다. 이런 목적으로 제강 슬래그를 대상으로 해서 폐 MgO-C계 내화재를 첨가하는 효과를 실험하였고 그 결과를 경소 돌로마이트를 첨가한 결과와 비교하여 폐 MgO-C계 내화재 재활용 효과를 평가하였다. 폐 MgO-C계 내화재를 사용해서 얻은 결과가 슬래그 염기도 측면에서 경소 돌로마이트를 사용한 결과와 유사하게 나타남으로써 기존 경소 돌로마이트 대체 가능성을 확인하였다. 특히 폐 MgO-C계 내화재를 사용한 경우에는, 폐 내화재에 다량 함유된 흑연 성분에 의한 슬래그 중의 철산화물과의 환원반응으로 CO가스가 발생하여 생긴 크고 작은 기포들이 관찰되었으며 이로써 슬래그 Foaming 효과를 기대할 수 있는 것으로 확인하였다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 추계학술대회논문집A
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• pp.310-315
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• 2000

We analyzed thermal stress of the STS VOD ladle by the variation of material property of refractory, and determined the location of back filler using FE analysis. Thermal distribution of refractory of ladle between hot face and back face were decreased by the increasing the thermal conductivity, and thermal stress of refractory were decreased about 2 to 4 times with the decreasing the young's modulus coefficients. Back filler, which is constructed to absorb the thermal expansion of dolomite refractory, has relatively low thermal conductivity. Inner side of refractory of ladle maintained high temperature, but temperature of outer side of ladle decreased low. Consequently, inner expansion and outer contraction were appeared. and thermal stress were increased, so thermal stress by the construction of back filler were increased.

• 대한기계학회논문집A
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• 제26권3호
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• pp.445-451
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• 2002

The refractory-lined pipe is used to protect the system from high-temperature of the internal flow. The property of the refractory has an effect upon the stress analysis for fluid catalytic cracking(FCC) unit piping design. The equivalent elastic modulus and density considering steel and refractory must be applied in the stress analysis of the system. In the research, the theoretical method to obtain the value of the equivalent property is introduced and then the parametric analysis is carried out to understand the characteristic of the material properties, and the stress analysis is performed with reactor, the part of FCC unit.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집A
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• pp.964-968
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• 2001

The refractory-lined pipe is used to protect the system from high-temperature of the internal flow. The property of the refractory has an effect upon the stress analysis for fluid catalyst cracking(FCC) unit piping design. The equivalent elastic modulus and density considering steel and refractory must be applied in the stress analysis of the system. In the research, the theoretical method to obtain the value of the equivalent property is introduced and then the parametric analysis is carried out to understand the characteristic of the material properties.

• 한국음향학회지
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• 제36권4호
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• pp.247-253
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• 2017

일반적으로 내화물의 진동특성은 등방성 재료로 가정한 후 확인한다. 하지만 실제로 내화물은 특정 방향으로 가압 성형하여 제조되기 때문에 이방성 재료특성을 보인다. 따라서 본 연구에서는 내화물을 정방정계 대칭성으로 가정하고, 유한요소프로그램을 이용해 너비, 길이, 높이 방향에 대한 주파수 응답을 얻었다. 해석결과의 타당성은 실제 측정결과의 비교를 통해 검증하였다. 주파수 응답을 기반으로, 충격방향기법을 이용하여 내화벽돌의 세 방향의 두께를 추정하였다. 실험을 통해 찾은 두께와 실제 두께와의 최대 오차율은 5 % 미만으로 확인되었다. 이를 통해 내화물과 같은 이방성 재료 두께 측정 시 충격반향기법의 효용성을 확인하였다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2017년도 춘계 학술논문 발표대회
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• pp.131-132
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• 2017

As the building is becomes bigger and larger, it can lead to big damage in case of fire. Also, tunnel, machine room and underground joint are spaces that can cause high temperature fire above 1,350℃ in case of fire. Therefore, a refractory material is need that can be withstand in high temperatures for long time. One side, the composition of oyster shell is CaCO₃ of 90% or more. It is expected that it will be possible to use it as a high calcium natural material which is the material of the refractory board. According to, Study on bending, compressive strength of mortar according to temperature and heating time change using oyster shell as aggregate the most commonly occurring particle sizes form 2.5mm to 5mm.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2017년도 추계 학술논문 발표대회
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• pp.122-123
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• 2017

As the building is becomes bigger and larger, it can lead to big damage in case of fire. Also, tunnel, machine room and underground joint are spaces that can cause high temperature fire above 1,350℃ in case of fire. Therefore, a refractory material is need that can be withstand in high temperatures for long time. One side, the composition of oyster shell is CaCO₃ of 90% or more. It is expected that it will be possible to use it as a high calcium natural material which is the material of the refractory board. According to, Study on bending, compressive strength of mortar according to temperature and heating time change using classified oyster shell as aggregate.

• 한국세라믹학회지
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• 제37권6호
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• pp.583-588
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• 2000

Antioxidation characteristics of carbon at high temperature with the co-addition of Al and Si powder in Al2O3-C system refractory were analyzed. The use of surface-modified phosphate carbon as a starting material was found to be very effective in improving the mixing effect of raw materials and antioxidation behavior of carbon. In particular, this effect was dominant at higher temperatures than 130$0^{\circ}C$.

• 한국재료학회지
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• 제19권9호
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• pp.473-480
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• 2009

In order to provide the mechanism of nozzle clogging, recovered nozzles for high strength steel grade were examined carefully after continuous casting. The thickness of clogged material in SEN is increased in the following order: from the bottom to the top of the nozzle, upper part of slag line, and the pouring hole. Nozzle clogging material begins to form due the adhesion of metal to nozzle wall, the decarburization, and reduction of oxide in the refractory by Al and Ti in the melt. The reduction of oxide in the refractory by Al and Ti improves the wettability of the melt on the refractory and forms a thin Al-Ti-O layer. Metal containing micro alumina inclusions is solidified on the Al-Ti-O layer, and the solid layer grows due to the heat evolution through the nozzle wall. Thermodynamic calculation has been made for the related reactions. The effect of superheat to the nozzle clogging is discussed on ultra low carbon steel and low carbon steel.

• 한국주조공학회지
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• 제30권3호
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• pp.115-120
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• 2010

Recently, an advanced raw material supplying system in diecasting industry that molten metal produced by the raw material supplier can be directly delivered to the diecasting shops was proposed. It was known to have advantages of reducing melting process cost and improving working environment. However, for its successful mass production, the development of high insulation ladle is inevitable. In this study, the optimal mixing ratio of $SiO_2-Al_2O_3$ was investigated and the high insulation ladle with computer simulation result was built in a prototype and evaluated. The prototype which has refractory wall of $SiO_233%-Al_2O_3$ 35%-CaO 33% showed high insulation sufficient for carrying the Al molten metal for 138 minutes. Gas quantity result and SEM-EDS analysis on the melt poured in the ladle also showed extremely low level of 0.028 cc / 100 g and no penetration of Al molten metal into the refractory wall, satisfying the requirements for mass production.