• 제목/요약/키워드: Reflection Spectra

검색결과 134건 처리시간 0.03초

폴리이미드 전구체 초박막의 분자배향과 표면상태에 관한 연구 (A Study on the Molecular Orientation and the Surface Mophology of polyimide precursor ultrathin film)

  • 정순욱
    • 한국응용과학기술학회지
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    • 제22권3호
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    • pp.228-233
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    • 2005
  • Langmuir-Blodgett(LB) technique can speak the best candidate of the future molecular electronic devices. But, precursor as molecular ultrathin film devices require the bulk property that are influenced by the molecular orientation. So, this device is one of current interest in molecular electronic device development of new materials. In this study, quantitative evaluation of molecular orientation in LB films of polyamic acid alkylamine salt was performed analysis experiment comparing the absorption or transmission intensity of the FT-IR spectrometer and reflection or absorption spectra with UV-visible absorption spectra. It could find that the polar angle(${\theta}$) of the dipole moment appears in about $68^{\circ}$ and the tilting angle of the alkyl chain is about $11.5^{\circ}$.

Polyamic Acid 알킬아민 염 랭뮤어-블로젯막의 분자 배향에 관한 연구 (A Study on the Molecular Orientation of Po1yamic Acid Alkylamine Salt Langmuir-Blodgett Films)

  • 정순욱;임현성
    • 한국항해항만학회:학술대회논문집
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    • 한국항해항만학회 2000년도 추계학술대회논문집
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    • pp.53.1-56
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    • 2000
  • Langmuir-Blodgett(LB) technique is the best candidate for the future molecular electronic devices. But, these molecular thin film devices require the bulk properties that are influenced by the molecular orientations. So, this is of current interest in molecular electronic device fabrications of new materials. In this study, quantitative evaluation of molecular orientation in LB films of PAAS was performed by comparing the absorption intensities of the FT-IR transmission and reflection-absorption spectra and the polarized UV/visible absorption spectra. It was found that the polar angle($\theta$) of the dipole moment is about 68$^{\circ}$and the tilting angle of the alkyl chain is about $11.5^{\circ}$ .

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Analysis of Magnetic Permeability Spectra of Metamaterials Composed of Cut Wire Pairs by Circuit Theory

  • Lim, Jun-Hee;Kim, Sung-Soo
    • Journal of Magnetics
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    • 제21권2호
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    • pp.187-191
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    • 2016
  • Retrieving the equivalent electromagnetic parameters (permittivity and permeability) plays an important role in the research and application of metamaterials. Frequency dispersion of magnetic permeability has been theoretically predicted in a metamaterial composed of cut wire pairs (CWP) separated by dielectric substrate on the basis of circuit theory. Magnetic resonance resulting from antiparallel currents between the CWP is observed at the frequency of minimum reflection loss (corresponding to absorption peak) and effective resonator size can be determined. Having calculated the circuit parameters (inductance L, capacitance C) and resonance frequency from CWP dimension, the frequency dispersion of permeability of Lorentz like magnetic response can be predicted. The simulated resonance frequency and permeability spectra can be explained well on the basis of the circuit theory of an RLC resonator.

Polyamic Acid 알킬아민 염 랭뮤어-블로젯막의 분자 배향에 관한 연구 (A Study on the Molecular Orientation of Polyamic Acid Alkylamine Salt Langmuir-Blodgett Films)

  • 정순욱;임현성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
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    • pp.53-56
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    • 2000
  • Langmuir-Blodgett(LB) technique is the best candidate for the future molecular electronic devices. But, these molecular thin film devices require the bulk properties that are influenced by the molecular orientations. So, this is of current interest in molecular electronic device fabrications of new materials. In this study, quantitative evaluation of molecular orientation in LB films of PAAS was performed by comparing the absorption intensities of the FT-IR transmission and reflection-absorption spectra and the polarized UV/visible absorption spectra. It was found that the polar angle( $\theta$ ) of the dipole moment is about 68$^{\circ}$ and the tilting angle of the alkyl chain is about 11.5$^{\circ}$

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습식 표면개질 처리된 폴리이미드 필름 표면의 특성에 관한 연구 (A Study on Characteristics of Surface Modified Polyimide Film by Wet Process)

  • 구석본;이홍기
    • 한국표면공학회지
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    • 제39권4호
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    • pp.166-172
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    • 2006
  • Metallized Polyimide films are extensively used as base materials in microelectronics, optical and automotive applications. However it is difficult to deposit metals on those because of their structural stabilities. In this work, polyimide films are modified by a wet process with alkalinemetalhydroxide and additives to introduce functional groups. The surface molecular structures of polyimide are investigated using X-ray photoelectron spectroscopy(XPS), fourier transform infrared reflection spectroscopy(FTIR-ATR), atomic force micro-scopic(AFM). XPS spectra and FTIR spectra show that the surface structure of polyimide is converted into potassium polyamate. AFM image and AFM cross-sectional analyses reveal the increased roughness on the modified surface of polyimide films. As a result, it is shown that the adhesion strength between polyimide surface and electroless nickel layer is increased by the nano-anchoring effect.

다양한 흡착자에 대한Si(113) $\times$2 표면의 상변화 연구 (Adsorbate-induced reconstructions of $\times$2 surface)

  • 김학수;황찬국;김용기;김정선;박죵윤;김기정;강태희;김봉수
    • 한국진공학회지
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    • 제8권3B호
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    • pp.269-275
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    • 1999
  • 전자회절법을 이용하여 K및 다양한 흡착자에 의한 Si(113)3 $\times$ 2 표면의 상변화를 관찰하였으며 광전자분광법을 이용하여 산소 노출량에 따른 가전자대 및 내각준위스펙트럼을 관찰하였다. 산소 흡착에 의해 가전자대의 표면상태가 내각준위에서 관찰되는 두 피크(S1, S2)와 동시에 사라지면서 3$\times$1 주기성을 보였다. 특히 이러한 변화가 동종물질인 실리콘 증착에서도 관찰되었으며 후열처리에 의해 3$\times$2 주기성으로 환원되는 것으로 미루어 Si(113)3$\times$2 표면의 3$\times$1으로의 초기 상전이가 실리콘 표면의 흡착자에 의해서 형성된 것이 아니며 기판 자체의 재배열과 관련되어 있음을 확인하였다.

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투과 및 반사 스펙트럼을 이용한 콜레스테릭 액정 필름의 광학 상수 결정 (Determination of optical constants for cholesteric liquid crystal films by using transmittance and reflectance spectra)

  • 박종락;류기한
    • 한국광학회지
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    • 제15권1호
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    • pp.63-67
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    • 2004
  • 이론적으로 계산된 투과 및 반사 스펙트럼을 실험적으로 측정된 결과에 대해 곡선 맞춤(curve fitting)을 수행하여 콜레스테릭 액정 필름(CLC, cholesteric liquid crystal)의 광학 상수를 결정하였다. 이론적인 투과 및 반사 스펙트럼 계산을 위해 Bewemn의 4${\times}$4행렬법이 사용되었다. 서로 다른 반사밴드를 갖고 있는 세 종류의 샘플에 대해 이 방법을 적용하였다 CLC샘플에 대한 곡선 맞춤 결과로부터 얻은 굴절률 값을 수평 배향된 LC샘플에 대해 측정된 값과 비교하였는데, 두 결과는 세 CLC 샘플에 대한 곡선 맞춤 결과 오차 범위 내에서 일치하였다.

Disk-averaged Spectra Simulation of Earth-like Exoplanets with Ray-tracing Method

  • 류동옥;김석환
    • 천문학회보
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    • 제37권1호
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    • pp.76.2-76.2
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    • 2012
  • The understanding spectral characterization of possible earth-like extra solar planets has generated wide interested in astronomy and space science. The technical central issue in observation of exoplanet is deconvolution of the temporally and disk-averaged spectra of the exoplanets. The earth model based on atmospheric radiative transfer method has been studied in recent years for solutions of characterization of earthlike exoplanet. In this study, we report on the current progress of the new method of 3D earth model as a habitable exoplanet. The computational model has 3 components 1) the sun model, 2) an integrated earth BRDF (Bi-directional Reflectance Distribution Function) model (Atmosphere, Land and Ocean) and 3) instrument model combined in ray tracing computation. The ray characteristics such as radiative power and direction are altered as they experience reflection, refraction, transmission, absorption and scattering from encountering with each all of optical surfaces. The Land BRDF characteristics are defined by the semi-empirical "parametric-kernel-method" from POLDER missions from CNES. The ocean BRDF is defined for sea-ice cap structure and for the sea water optical model, considering sun-glint scattering. The input cloud-free atmosphere model consists of 1 layers with vertical profiles of absorption and aerosol scattering combined Rayleigh scattering and its input characteristics using the NEWS product in NASA data and spectral SMARTS from NREL and 6SV from Vermote E. The trial simulation runs result in phase dependent disk-averaged spectra and light-curves of a virtual exoplanet using 3D earth model.

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FT-IR을 이용한 중요 광물의 적외 방출도 스펙트럼 측정 (Infrared Emissivity of Major Minerals Measured by FT-IR)

  • 이유정;박중현;이광목
    • 대기
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    • 제25권4호
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    • pp.601-610
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    • 2015
  • This study measured the emissivity spectra of 5 major rock-forming minerals using a Fourier Transform Infrared (FT-IR) spectrometer in the spectral region of $650{\sim}1400cm^{-1}$. The mineral samples are quartz, albite, bytownite, anorthite, and sandstone. We compared emissivity spectra measured in this study with spectra provided by Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) and Arizona State University (ASU). The spectral features of emissivity such as Reststrahlen Band (RB) and Christiansen Feature (CF) locations were compared. Results showed that both CF and RB locations of emissivity spectra measured in this study were similar to those from ASTER and ASU. In the case of quartz, the RB was occurred in the region of $700{\sim}850cm^{-1}$ and $1050{\sim}1250cm^{-1}$. The spectral position of emissivity peak was in good agreement with the location of ASTER and ASU. For plagioclase (albite, bytownite, and anorthite), the spectral location of CF was shifted toward larger wavenumber and the emissivity value was increased in the region of $870{\sim}1200cm^{-1}$ with Ca percentage. The CF of anorthite and bytownite was occurred at $1245.79cm^{-1}$, and that of albite was occurred at $1283.79cm^{-1}$. We also confirmed that emissivity feature of sandstone includes both emissivity features of quartz and calcite. However, there were some differences in the magnitude of emissivity and locations of RB and CF. These were due to the differences in measurement methods, and differences in particle size and temperature of samples.

광섬유 격자소자를 이용한 협대역 투과 필터의 설계 (Design of narrow band-pass filter using two fiber bragg gratings)

  • 임종훈;이경식
    • 전자공학회논문지D
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    • 제35D권8호
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    • pp.82-88
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    • 1998
  • We propose and design a new type of anrrow band-pass optical filter based on two fiber gratings with different reflection wavelength. The ripples occur in the spectra of the filter with two uniform fiber gratings. Our simulation results also show that the ripples disappear with the fiber gratings apodized to both gaussian and hyperbolic tangent function. The hyperbolic tangent function seems to be a better apodization function for improving the filter's performance in terms of narrow pass bandwidth and high transmission.

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