• 제목/요약/키워드: Reduction mechanism

검색결과 1,747건 처리시간 0.023초

Electrochemical Behavior for a Reduction of Uranium Oxide in a $LiCl-Li_{2}O$ Molten Salt with an Integrated Cathode assembly

  • Park, Sung-Bin;Park, Byung-Heung;Seo, Chung-Seok;Jung, Ki-Jung;Park, Seong-Won
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2005년도 Proceedings of The 6th korea-china joint workshop on nuclear waste management
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    • pp.39-50
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    • 2005
  • Electrolytic reduction of uranium oxide to uranium metal was studied in a $LiCl-Li_{2}O$ molten salt system. The reduction mechanism of the uranium oxide to a uranium metal has been studied by means of a cyclic voltammetry. Effects of the layer thickness of the uranium oxide and the thickness of the MgO on the overpotential of the cathode and the anode were investigated by means of a chronopotentiometry. From the cyclic voltamograms, the decomposition potentials of the metal oxides are the determining factors for the mechanism of the reduction of the uranium oxide in a $LiCl-3\;wt{\%} Li_{2}O$ molten salt and the two mechanisms of the electrolytic reduction were considered with regards to the applied cathode potential. In the chronopotentiograms, the exchange current and the transfer coefficient based on the Tafel behavior were obtained with regard to the layer thickness of the uranium oxide which is loaded into the porous MgO membrane and the thickness of the porous MgO membrane. The maximum allowable currents for the changes of the layer thickness of the uranium oxide and the thickness of the MgO membrane were also obtained from the limiting potential which is the decomposition potential of LiCl.

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Study the Electrochemical Reduction of Some Triazines in N,N-Dimethylformamide at Glassy Carbon Electrode

  • Fotouhi, L.;Farzinnegad, N.;Heravi, M.M.;Khaleghi, Sh.
    • Bulletin of the Korean Chemical Society
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    • 제24권12호
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    • pp.1751-1756
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    • 2003
  • An electrochemical study related to the electroreduction of 4-amino-6-methyl-3-thio-1,2,4-triazin-5-one(I), 6-methyl-3-thio-1,2,4-triazin-5-one(II), and 2,4-dimetoxy-6-methyl-1,3,5-triazine(III) in dimethylformamide at glassy carbon electrode has been performed. A variety of electrochemical techniques, such as differential pulse voltammetry (DPV), cyclic voltammetry (CV), chronoamperometry, and coulometry were employed to clarify the mechanism of the electrode process. The compounds I and II with thiol group exhibited similar redox behavior. Both displayed two cathodic peaks, whereas the third compound, III, without thiol group showed only one cathodic peak in the same potential range of the second peak of I and II. The results of this study suggest that in the first step the one electron reduction of thiol produced a disulfide derivative and in the second reduction step the azomethane in the triazine ring was reduced in two electron processes. A reduction mechanism for all three compounds is proposed on this basis. In addition, some numerical constants, such as diffusion constant, transfer coefficient, and rate constant of coupled chemical reaction in the first reduction peak were also reported.

A Robust Control Approach for Maneuvering a Flexible Spacecraft

  • Sung, Yoon-Gyeoung;Lee, Jea-Won;Kim, Hunmo
    • Journal of Mechanical Science and Technology
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    • 제15권2호
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    • pp.143-151
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    • 2001
  • In the paper, a robust control mechanism is presented to maneuver a flexible spacecraft with the deflection reduction during large slewing operation at the same time. For deflection reduction and maneuvering of the flexible spacecraft, a control mechanism is developed with the application of stochastic optimal sliding-mode control, a linear tracking model and input shaping technique. A start-coast-stop maneuver is employed as a slewing strategy. It is shown that the control mechanism with he strategic maneuver results in better performance and is more efficient than rigid-body-like maneuver, by applying to the Spacecraft Control Laboratory Experiment (SCOLE) system in a space environment.

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미소경 드릴링 머신의 시작과 감시에 관한 연구 (A Study on the Development and the Monitoring of Micro Hole Drilling Machine)

  • 백인환;정우섭
    • Journal of Advanced Marine Engineering and Technology
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    • 제18권4호
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    • pp.62-68
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    • 1994
  • Recently, the trends toward reduction in size and weight of industrial products increased the application of micro hole for manufacturing gadgets of high precision and gave rise to a great deal of interest for micro hole drilling M/C. Quite a few research work is performed on micro drilling on domestic basis compared with the tendency of analyzing cutting mechanism, adaptive control, monitoring of generally available drills of diameter greater than 1mm. This study adresses the design, manufacturing and controlling a micro hole drilling M/C with the overload detection instrument and the step feed mechanism. Controlling and monitoring of the drilling process are acomplished on PC basis for more user interfaces and effectiveness. The test machine of the results of this research shows a good foundation for extending further micro hole machining technique.

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네일의 토압분담 효과를 고려한 Green Wall 시스템의 설계 (Design of the Green Wall System considering Distribution Effect of Earth Pressure by Soil Nail)

  • 박시삼;조성한;유찬호;김홍택;김용언
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2006년도 춘계 학술발표회 논문집
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    • pp.1038-1045
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    • 2006
  • The Green Wall is highest eco-system among a segmental retaining wall systems. Recently, the demand of high segmental retaining wall (SRW) is increased in domestic. The soil nailing system is applied in order to maintain the high SRW stability for steeper slope. However, the proper design approach that can consider the earth pressure reduction effects in soil nailing system has not been proposed. This study was performed to introduce the design case by 'Two-Body Translation mechanism' to be able to consider distribution of earth pressure in the soil nailing when designing the green wall using soil nailing system. Also, this study attempts to evaluate the earth pressure change when advanced soil nailing system is constructed using $FLAC^{2D}$ ver. 3.30 program and 'Two-Body Translation mechanism'. Also in this study, various parametric studies using numerical methods as shear strength reduction (SSR) technique and limit equilibrium technique were carried out. In the parametric study, the length ratio and the bond ratio of the soil nailing were changed to identify the earth pressure reduction effect of the retaining wall reinforced by soil nailing.

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POD 기법을 이용한 경계층 외부 수직날의 마찰저항 저감 기구에 관한 관측 (Investigation of Skin Friction Reduction Mechanism of Outer-Layer Vertical Blades Using POD Analysis)

  • 안남현;박성현;전호환;이인원
    • 대한기계학회논문집B
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    • 제37권6호
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    • pp.567-575
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    • 2013
  • 외부경계층 수직 날의 마찰저항 저감 기구를 규명하기 위하여 회류수조에서 시간분해 입자영상유속계로 측정된 비정상 유동장에 POD 분석을 실시하였다. 최근의 PIV 결과에서는 수직날 평면 및 수직날 사이 평면에서 각각 2.73%, 7.95%의 마찰저항 저감효과가 발견되었다. 본 연구에서는 수직날 배열이 난류조직구조에 미치는 영향을 POD 방법을 통하여 분석하였다. 난류유동의 조직적인 와구조가 수직날에 의하여 절단, 변형되고 비정상 거동이 난류경계층에서의 마찰저항 저감 기구와 밀접하게 관련된 것으로 관찰되었다.

Aerodynamic stabilization of central stabilizers for box girder suspension bridges

  • Ge, Yaojun;Zou, Xiaojie;Yang, Yongxin
    • Wind and Structures
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    • 제12권4호
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    • pp.285-298
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    • 2009
  • For long-span suspension bridges with their intrinsic limit in flutter, some counter measures, for example, central stabilizers, should be adopted to improve aerodynamic stability to meet with the appropriate wind resistance requirements. The present paper introduces aerodynamic stabilization for long-span suspension bridges with box girders by using central stabilizers based on Xihoumen Bridge with the main span of 1650 m. The aerodynamic stabilization study covers experimental investigation of sectional model testing, comprehensive evaluation of three central stabilizers and theoretical analysis of stabilizing mechanism related to flutter derivatives, aerodynamic damping and degree participation.

Balanced Buck-Boost Switching Converter to Reduce Common-Mode Conducted Noise

  • Shoyama Masahito;Ohba Masashi;Ninomiya Tamotsu
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2001년도 Proceedings ICPE 01 2001 International Conference on Power Electronics
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    • pp.212-216
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    • 2001
  • Because conventional switching converters have been usually using unbalanced circuit topologies, parasitic capacitance between the drain/collector of an active switch and the frame ground through its heat sink may generate the common-mode conducted noise. We have proposed a balanced switching converter circuit, which is an effective way to reduce the common-mode conducted noise. As an example, a boost converter version of the balanced switching converter was presented and the mechanism of the common-mode noise reduction was explained using equivalent circuits. This paper extends the concept of the balanced switching converter circuit and presents a buck-boost converter version of the balanced switching converter. The feature of common-mode noise reduction is confirmed by experimental results and the mechanism of the common-mode noise reduction is explained using equivalent circuits.

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차동유성형 마찰드라이브의 개발 (Developement of planetary differential type traction drive)

  • 이종원;오세훈;최동엽;이대길;전한수
    • 한국정밀공학회지
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    • 제14권3호
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    • pp.35-40
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    • 1997
  • The traction drive has advantages of having high efficiency and transmitting the power without blacklash. However, when high ratio of speed reduction is desired, excessively large size is required. In this study, a new type of traction drive is invented, designed and manufactured so that stable speed reduction mech- anisms are available by adopting a cross roller type drive. It has a simple structure, but produces high speed reduction ratio. Power loss is observed, and also, driving torque and torque transfer efficiency are calculated. Pre-loads are needed in order that the traction drive transfers power without slipping, and the spacer is enlarged due to the pre-loading. After all, the key point of pre-load mechanism is that the spacer's diameter becomes larger as pre-loads are applied.

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On the mechanism of vertical stabilizer plates for improving aerodynamic stability of bridges

  • Chen, Airong;Zhou, Zhiyong;Xiang, Haifan
    • Wind and Structures
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    • 제9권1호
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    • pp.59-74
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    • 2006
  • Vertical stabilizer plates have been found to be an effective aerodynamic measure to improve the aerodynamic stability of bridges either with an open cross section or with a streamlined box cross section in wind tunnel testings and have been adopted in some long span bridges. By taking an open deck II-shaped section and a closed box section as examples, the mechanism of vertical stabilizer plates for improving aerodynamic stability are investigated by using numerical simulation based on Random Vortex Method. It is found that vertical stabilizer plates can increase the amplitude of the heaving motion, and decrease that of the rotational motion of the bridge decks.