• Title/Summary/Keyword: Reduction behavior

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pH-Dependent Electrochemical Behavior of N-Monosubstituted-4,$4^{\prime}$-Bipyridinium Ions

  • Park, Joon-woo;Kim, Yuna;Lee, Chong-Mok
    • Bulletin of the Korean Chemical Society
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    • v.15 no.10
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    • pp.896-900
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    • 1994
  • The pH-dependent reduction behavior of N-monosubstituted-4,4'-bipyridinium ions ($RBPY^+: R=methyl(C_1)$; benzyl; n-octyl; n-dodecyl) has been investigated by electrochemical and spectroelectrochemical techniques. At acidic condition, $RBPY^+$ is protonated and the protonated species are reduced by two consecutive one-electron processes. The $2e^-$ reduced species undergoes a chemical reaction with $H^+$. The second-order rate constant $(k_H)$ of the homogeneous chemical process is $(3.7{\pm}0.3){\times}10^3M^{-1}s^{-1}$ for the two electron reduction product of $C_1BPY^+$. At high pH, the electrode reduction of $RBPY^+$ is one-step $2e^-$ transfer process with concomitant addition of $H^+$, which is confirmed by cyclic voltammetric study using a microdisk electrode.

Experimental and analytical investigations on seismic behavior of ductile steel knee braced frames

  • Zahrai, Seyed Mehdi;Jalali, Meysam
    • Steel and Composite Structures
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    • v.16 no.1
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    • pp.1-21
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    • 2014
  • Knee Braced Frame (KBF) is a special form of ductile eccentrically braced frame having a diagonal brace connected to a knee element, as a hysteretic damper, instead of beam-column joint. This paper first presents an experimental investigation on cyclic performance of two knee braced single span one-story frame specimens. The general test arrangement, specimen details, and most relevant results (failure modes and hysteretic curves) are explained. Some indexes to assess the seismic performance of KBFs, including ductility; response reduction factor and energy dissipation capabilities are also subsequently discussed. Experimental results indicate that the maximum equivalent damping ratios achieved by test frames are 21.8 and 23% for the specimens, prior to failure. Finally, a simplified analytical model is derived to predict the bilinear behavior of the KBFs. Acceptable conformity between analytical and experimental results proves the accuracy of the proposed model.

Inelastic Behavior of the SRC Column (SRC 합성교각의 비탄성 거동)

  • Jung, In-Keun;Min, Jin;Shim, Chang-Su;Chung, Young-Soo
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 2005.03a
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    • pp.300-307
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    • 2005
  • Steel Reinforced Concrete (SRC) composite column has several advantage such as excellent durability, rapid construction, reduction of column section. Due to these aspect, applications of SRC columns to bridge piers are continuously increasing. For the design of relatively large SRC columns for bridge piers, it is necessary to check the current design provisions which were based on small section having higher steel ratio. In this study, seven concrete encased composite columns were fabricated and static tests were performed. Embedded steel members were a H-shape rolled beam and a partially filled steel tube. Based on the test results, the ultimate strength according to section details and local behavior were estimated. For the analysis of inelastic behavior of the SRC column, the cracked section stiffness of the columns was evaluated and compared with calculations. The stiffness of the cracked section showed that 25% of the initial value and this stiffness reduction occurred at 85% of the ultimate load in the experiments.

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Initial Performance Degradation of Hydrogen-Fueled Ceramic Fuel Cell with Plasma-Enhanced Atomic Layer-Deposited Ultra-Thin Electrolyte (플라즈마 원자층증착 초박막전해질 수소 세라믹연료전지의 초기성능 저하)

  • JI, SANGHOON
    • Journal of Hydrogen and New Energy
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    • v.32 no.5
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    • pp.340-346
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    • 2021
  • The initial electrochemical performance of ceramic fuel cell with thin-film electrolyte fabricated by plasma-enhanced atomic layer deposition method was evaluated in terms of peak power density ratio, open circuit voltage ratio, and activation/ohmic resistance ratios at 500℃. Hydrogen and air were used as anode fuel and cathode fuel, respectively. The peak power density ratio reduced as ~52% for 30 min, which continually decreased as time increased but degradation rate gradually decreased. The open circuit voltage ratio decreased with respect time; however, its behavior was evidently different from the reduction behavior of the peak power density. The activation resistance ratio increased as ~127% for 30 min, which was almost similar with the reduction behavior of the peak power density ratio.

Application of Phase-Field Theory to Model Uranium Oxide Reduction Behavior in Electrolytic Reduction Process (전해환원 공정의 우라늄 산화물 환원 거동 모사를 위한 Phase-Field 이론 적용)

  • Park, Byung Heung;Jeong, Sang Mun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.3
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    • pp.291-299
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    • 2018
  • Under a pyro-processing concept, an electrolytic reduction process has been developed to reduce uranium oxide in molten salt by electrochemical means as a part of spent fuel treatment process development. Accordingly, a model based on electrochemical theory is required to design a reactor for the electrolytic reduction process. In this study, a 1D model based on the phase-field theory, which explains phase separation behaviors was developed to simulate electrolytic reduction of uranium oxide. By adopting parameters for diffusion of oxygen elements in a pellet and electrochemical reaction rate at the surface of the pellet, the model described the behavior of inward reduction well and revealed that the current depends on the internal diffusion of the oxygen element. The model for the electrolytic reduction is expected to be used to determine the optimum conditions for large scale reactor design. It is also expected that the model will be applied to simulate the integration of pyro-processing.

Research of Dry Reduction Process of Waste Tin Oxide using Methane (메탄가스를 이용한 폐주석산화물의 건식환원시스템)

  • Hyun-Chul Jung;Se-Kwon Kim;Sang-Yeol Kim
    • Resources Recycling
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    • v.31 no.6
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    • pp.18-24
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    • 2022
  • Dry reduction using natural gas was proposed to recover tin from waste tin oxide generated in a tin bath that was used for controlling the smoothness of architectural glass during production, and the reduction behavior was investigated. The utilized vertical natural gas dry reduction system is capable to process 4 L or 20 kg depending on input raw materials. The system was established by applying the upper intake and lower discharge method. The recovery rate was 97.2% at 800 ℃ and 4 sccm flow rate and increased with the amount of input gas. Hydrogen accounted for 23% of the discharge gas, showing a 16.6% hydrogen conversion rate. The reaction behavior of tin recovered via natural gas reduction provides basic data on the new waste resource reduction/recovery technology.

Study on Consumer's Complaints Behavior and Information Search Behavior According to Return Factors of the Internet Fashion Mall (인터넷 패션쇼핑몰의 반품요인에 따른 소비자 불평행동과 정보탐색행동에 관한 연구)

  • Kim, Ju-Hee
    • Fashion & Textile Research Journal
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    • v.12 no.6
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    • pp.745-754
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    • 2010
  • This study is to find return factors when modern consumers purchase goods from an internet shopping mall and then to analyze the characteristics of complaints act and information search behavior. Subjects of research are 245 men and women, who have experience with more than one return in internet fashion shopping mall, in their twenties. The data were analyzed by using Factor analysis, Cronbach's analysis, one-way ANOVA, Duncan test as a post identification, Pearson's correlation analysis and multiple regression analysis. The results of this study are that male and female consumers in their 20s are mainly aware of the return factors: impulse buying, product status, deliver service, service after purchase, hype and comfortableness. And complains behavior often conduct public action, private action, nonaction. Information search behaviors for risk reduction when they purchase are product comparison, oral information search, neutral marketing information search, and service information search. The return factor from the internet fashion shopping had the greatest impact on public action and deliver services factor was a big complaint. In addition, impulse buying & Hype affect private action and non-action is influenced by impulse purchase. The consumer types by the return factors in internet fashion shopping mall are classified into the return group by deliver service, the return group by complex factors, and the return group by product status. Furthermore, there are significant differences in complaining behavior among these groups. In the information search behavior for reduction of risk factors, the return group by complex factors did more active information search behavior than the other groups. The return group by deliver service searched oral information and the return group by product status explored the neutral marketing information.

The Optimization of Hydrogen Reduction Process for Mass Production of Fe-8wt%Ni Nanoalloy Powder

  • Jung, Sung-Soo;Kang, Yun-Sung;Lee, Jai-Sung
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1331-1332
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    • 2006
  • The present investigation has attemped to optimize hydrogen reduction process for the mass production of Fe-8wt%Ni nanoalloy powder from ball milled $Fe_2O_3-NiO$ powder. In-situ hygrometry study was performed to monitor the reduction behavior in real time through measurement of water vapor outflowing rate. It was found that the reduction process can be optimized by taking into account the apparent influence of water vapor trap in the reactor on reduction kinetics which strongly depends on gas flow rate, reactor volume and reduction.

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Hollow Reinforced Concrete Bridge Column Systems with Reinforcement Details for Material Quantity Reduction: II. Experiments and Analyses (물량저감 철근상세를 갖는 중공 철근콘크리트 교각 시스템: II. 실험 및 해석)

  • Kim, Tae-Hoon;Kim, Ho-Young;Lee, Jae-Hoon;Shin, Hyun-Mock
    • Journal of the Earthquake Engineering Society of Korea
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    • v.18 no.1
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    • pp.9-18
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    • 2014
  • The purpose of this study is to investigate the seismic behavior of hollow reinforced concrete bridge column systems with reinforcement details for material quantity reduction and to provide the details and reference data. Five hollow reinforced concrete bridge columns were tested under a constant axial load and a cyclically reversed horizontal load. The accuracy and objectivity of the assessment process can be enhanced by using a sophisticated nonlinear finite element analysis program. The adopted numerical method gives a realistic prediction of seismic performance throughout the loading cycles for several the investigated test specimens. This study documents the testing of hollow reinforced concrete bridge column systems with reinforcement details for material quantity reduction and presents conclusions based on the experimental and analytical findings.

The Impact of Diagnostic Imaging Fee Changes to Medical Provider Behavior: Focused on the Number of Exams of Computed Tomograph (영상진단 수가 변화가 의료공급자 진료행태에 미치는 영향: 전산화단층영상진단 검사건수를 중심으로)

  • Cho, Su-Jin;Kim, Donghwan;Yun, Eun-Ji
    • Health Policy and Management
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    • v.28 no.2
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    • pp.138-144
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    • 2018
  • Background: Diagnostic imaging fee had been reduced in May 2011, but it was recovered after 6 months because of strong opposition of medical providers. This study aimed to analyze the behavior of medical providers according to fee changes. Methods: The National Health Insurance claims data between November 2010 and December 2012 were used. The number of exams per computed tomography was analyzed to verify that the fee changes increased or decreased the number of exams. Multivariate regression model were applied. Results: The monthly number of exams increased by 92.5% after fee reduction, so the diagnostic imaging spending were remained before it. But medical provider decreased the number of exams after fee return. After adjusting characteristic of hospitals, fee reduction increased the monthly number of exams by 48.0% in a regression model. Regardless type of hospitals and severity of disease, the monthly number of exams increased during period of fee reduction. The number of exams in large-scaled hospitals (tertiary and general hospital) were increased more than those of small-scaled hospitals. Conclusion: Fee-reduction increased unnecessary diagnostic exams under the fee-for-service system. It is needed to define appropriate exam and change reimbursement system on the basis of guideline.